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For a given parcel air at a known pressure and dry-bulb temperature, the thermodynamic wet-bulb temperature corresponds to unique values of relative humidity, dew point temperature, and other properties. The relationships between these values are illustrated in a psychrometric chart.
For "dry" air, air that is less than saturated (i. e. air with less than 100 percent relative humidity), the wet-bulb temperature is lower than the dry-bulb temperature due to evaporative cooling. The greater the difference between the wet and dry bulb temperatures, the drier the air and lower the relative humidity. The dew point temperature is the temperature at which the ambient air must cool to reach 100% relative humidity where condensate and rain form; and conversely, the wet bulb temperature rises to converge on the dry bulb temperature.
Cooling of the human body through perspiration is inhibited as the wet-bulb temperature (and relative humidity) of the surrounding air increases in summer. Other mechanisms may be at work in winter if there is validity to the notion of a "humid" or "damp cold."
Lower wet-bulb temperatures that correspond with drier air in summer can translate to energy savings in air-conditioned buildings due to: #Reduced dehumidification load for ventilation air #Increased efficiency of cooling towers
The temperature of an air sample that has passed over a large surface of liquid water in an insulated channel is the thermodynamic wet-bulb temperature – it has become saturated by passing through a constant-pressure, ideal, adiabatic saturation chamber.
Meteorologists and others may use the term "isobaric wet-bulb temperature" to refer to the "thermodynamic wet-bulb temperature". It is also called the "adiabatic saturation temperature".
It is the thermodynamic wet-bulb temperature that is plotted on a psychrometric chart.
The thermodynamic wet-bulb temperature is a thermodynamic property of a mixture of air and water vapor. The value indicated by a simple wet-bulb thermometer often provides an adequate approximation of the thermodynamic wet-bulb temperature.
For an accurate wet-bulb thermometer, "the wet-bulb temperature and the adiabatic saturation temperature are approximately equal for air-water vapor mixtures at atmospheric temperature and pressure. This is not necessarily true at temperatures and pressures that deviate significantly from ordinary atmospheric conditions, of for other gas-vapor mixtures."
An actual wet-bulb thermometer reads a slightly different temperature than the thermodynamic wet-bulb temperature, but they are very close in value. This is due to a coincidence: for a water-air system the psychrometric ratio happens to be ~1,although for systems other than air and water they might not be close.
To understand why this is, first consider the calculation of the thermodynamic wet-bulb temperature: in this case, a stream of air with less than 100% relative humidity is cooled. The heat from cooling that air is used to evaporate some water which increases the humidity of the air. At some point the air reaches 100% saturation (and has cooled to the thermodynamic wet-bulb temperature). In this case we can write the following:
where is the initial water content of the air on a mass basis, is the saturated water content of the air, is the latent heat of water, is the initial air temperature, is the saturated air temperature and is the heat capacity of the air.
For the case of the wet-bulb thermometer, imagine a drop of water with air of less than 100% relative humidity blowing over it. As long as the vapor pressure of water in the drop is more than the partial pressure of water in the air stream, evaporation will take place. Initially the heat required for the evaporation will come from the drop itself since the fastest moving water molecules are most likely to escape the surface of drop, so the remaining water molecules will have a lower average speed and therefore a lower temperature. If this were the only thing that happened, then the drop would cool until the following was true:
where is the saturation pressure of the water in the drop and is a function of the drop temperature and is the partial pressure of water in the vapor phase. If the air started bone dry and was blowing sufficiently fast then would be 0 and the drop could get infinitely cold. Clearly this doesn't happen. It turns out that as the drop cools, convective heat transfer begins to occur between the warmer air and the colder water. In addition, the evaporation does not occur instantly, but instead depends on the rate of convective mass transfer between the water and the air. At a certain point the water cools to a point where the heat carried away in evaporation is equal to the heat gain through convective heat transfer. At this point the following is true:
where is now the driving force for mass transfer, k' is the mass transfer coefficient (with english units of lb/(h⋅ft2)), is the heat transfer coefficient and is the temperature driving force.
Now if this equation is compared to the thermodynamic wet-bulb equation, we can see that if the quantity (known as the psychrometric ratio) then
Due to a coincidence, for air this is the case and the ratio is very close to 1.
Experimentally, the wet-bulb thermometer reads closest to the thermodynamic wet-bulb temperature if:
In practice the value reported by a wet-bulb thermometer differs slightly from the thermodynamic wet-bulb temperature because:
At relative humidities below 100 percent, water evaporates from the bulb which cools the bulb below ambient temperature. To determine relative humidity, ambient temperature is measured using an ordinary thermometer, better known in this context as a dry-bulb thermometer. At any given ambient temperature, less relative humidity results in a greater difference between the dry-bulb and wet-bulb temperatures; the wet bulb is colder. The precise relative humidity is determined by reading from a psychrometric chart of wet-bulb versus dry-bulb temperatures, or by calculation.
Psychrometers are instruments with both a wet-bulb and a dry-bulb thermometer.
A wet-bulb thermometer can also be used in combination with a globe thermometer (which is affected by the radiant temperature of the surroundings) in the calculation of the wet bulb globe temperature.
This term, as defined in this article, may be most prevalent in meteorology.
As the value referred to as "thermodynamic wet-bulb temperature" is also achieved via an adiabatic process, some engineers and others may use the term "adiabatic wet-bulb temperature" to refer to the "thermodynamic wet-bulb temperature". As stated in another section, meteorologists and others may use the term "isobaric wet-bulb temperature" to refer to the "thermodynamic wet-bulb temperature".
"The relationship between the isobaric and adiabatic processes is quite obscure. Comparisons indicate, however, that the two temperatures are rarely different by more than a few tenths of a degree Celsius, and the adiabatic version is always the smaller of the two for unsaturated air. Since the difference is so small, it is usually neglected in practice."
The WBGT is a mathematically derived value produced by an equation involving
Since a person's tolerance of a given index value varies significantly according to clothing, activity, and acclimatization
To date there have only been rare meteorological measurements of wet bulb temperature approaching 35C for brief periods of time. The researchers projected that if average global temperatures rise by 7°C (12.6°F) some areas of the world would start to surpass their criterion for a lethal wet-bulb temperature limit.
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