- published: 18 Mar 2016
- views: 477867
In chemistry, vinyl or ethenyl is the functional group −CH=CH2, namely the ethylene molecule (H2C=CH2) minus one hydrogen atom. The name is also used for any compound containing that group, namely R−CH=CH2 where R is any other group of atoms.
An industrially important example is vinyl chloride, precursor to PVC, a plastic commonly known as vinyl.
Vinyl is one of the alkenyl functional groups. On a carbon skeleton, sp2-hybridized carbons or positions are often called vinylic. Allyls, acrylates and styrenics contain vinyl groups. (A styrenic crosslinker with two vinyl groups is called divinyl benzene.)
The etymology of vinyl is the Latin vinum = "wine", because of its relationship with alcohol (in its original sense of ethyl alcohol). The term "vinyl" was coined by the German chemist Hermann Kolbe in 1851.
Vinyl groups can polymerize with the aid of a radical initiator or a catalyst, forming vinyl polymers. In these polymers, the double bonds of the vinyl monomers turn into single bonds and the different monomers are joined by single bonds. Vinyl groups do not exist in vinyl polymer; the term refers to the precursor. It is sometimes important to ascertain the absence of unreacted vinyl monomer in the final product when the monomer is toxic or reduces the performance of the plastic. The following table gives some examples of vinyl polymers.
A gramophone record (phonograph record in American English) or vinyl record, commonly known as a "record", is an analog sound storage medium in the form of a flat polyvinyl chloride (previously shellac) disc with an inscribed, modulated spiral groove. The groove usually starts near the periphery and ends near the center of the disc. Phonograph records are generally described by their diameter in inches (12", 10", 7"), the rotational speed in rpm at which they are played (16 2⁄3, 33 1⁄3, 45, 78), and their time capacity resulting from a combination of those parameters (LP – long playing 33 1⁄3 rpm, SP – 78 rpm single, EP – 12-inch single or extended play, 33 or 45 rpm); their reproductive quality or level of fidelity (high-fidelity, orthophonic, full-range, etc.), and the number of audio channels provided (mono, stereo, quad, etc.).
The phonograph disc record was the primary medium used for music reproduction until late in the 20th century, replacing the phonograph cylinder record, with which it had co-existed, by the 1920s. By the late 1980s, digital media, in the form of the compact disc, had gained a larger market share, and the vinyl record left the mainstream in 1991. After its fall, records continued to be manufactured and sold, and have been especially used by disc jockeys and many audiophiles for various types of music. The phonograph record has made a niche resurgence in the early 21st century – 9.2 million records were sold in the U.S. in 2014, a 260% increase since 2009. Likewise, in the UK sales have increased five-fold from 2009 to 2014.
Actors: Walter Marsh (actor), Tom McBeath (actor), Grace MacLeod (miscellaneous crew), Dean Stockwell (actor), Peter Locke (producer), John Savage (actor), Donald Kushner (producer), Andrew Wheeler (actor), Don Munro (miscellaneous crew), Craig March (actor), Dean Wray (actor), Judith Maxie (actress), Kristen Dalton (actress), Nicholas Podbrey (miscellaneous crew), Kelly Moon (miscellaneous crew),
Plot: Dr. Ben Cahill, a fine city doctor, gets so stressed by marital problems and alcohol that he freezes up under pressure in the emergency room. To get his act back together, he decides to unwind a few months in the house he and his ex bought on Orr island, an insignificant (former) fishermen place off the coast of Maine. He almost immediately becomes the butt of spite from a gang of local nobodies. After the doctor started examining, at the request of the reasonable sheriff Hobbs who leans to his side, some animal and human corpses with strange internal as well as external injuries, one of the brutes, not so handy handyman Jack Wald, has a fatal nocturnal accident crashing into Dr. Cahill's car. The doc observes one of the red cockroaches which recently infest the island has pincers, most unusual, reads up and contacts the university entomology department, where this African species isn't too well-known either. Jack's even dumber brother Eamon Wald uses violence which ends up causing the sheriff's death, so the doc has no other help then the enterprising local store clerk Nell Bartle, who takes a liking to the only educated men around, to continue investigating fighting off Eamon's gang and as they find out how bad the danger is, try to evacuate...
Keywords: atlantic-ocean, ballpoint-pen, bar, barn, bathtub, boat, boston-massachusetts, child-in-peril, cockroach, coffeeGet William Michael Morgan's New EP today! http://smarturl.it/wmmep http://williammichaelmorgan.com http://facebook.com/WilliamMichaelMorgan http://twitter.com/wmmorganmusic http://instagram.com/wmmorganmusic
Electron Microscope video from Applied Science - https://www.youtube.com/watch?v=GuCdsyCWmt8 Record storage options: Pricier (woodier) option - http://amzn.to/1MqYf97 Cheaper (cardboardier) option - http://amzn.to/1faWQoz IKEA Drona ($6) is a ripoff on Amazon - Go to store Inner Sleeves: MFSL Master sleeves - http://amzn.to/1WnIWkO Diskeeper Audiophile sleeves - http://amzn.to/1h8lhEM Outer sleeves (protect cover art) - http://amzn.to/1KkpZp Record brushes: Cheap brush (I like it best) - http://amzn.to/1DOqYlw Pricier brush (overrated) - http://amzn.to/1KkqGiU Stylus tools: Stylus brush - http://amzn.to/1KkqO26 ONZOW Zerodust (worth the $) - http://amzn.to/1h8ms7p Static tools: Zerostat (if you can stomach price) - http://amzn.to/1MqZNQz Wet cleaning: Spin Clean (cheap but I hated it...
Telekom Electronic Beats TV investigates the current resurgence in popularity of the most iconic and recognisable symbol of the electronic music scene - the vinyl record. What fuels this fascination? Why is the relationship between this medium and DJs, producers, artists, label managers, distributors and collectors such a personal one? Hear the thoughts of Claas Brieler (Jazzanova), Steffi (Ostgut Ton, Klakson), Finn Johannsen (Hardwax, Macro), Cinthie (Beste Modus), Marc Schneider (Word & Sound) and more for an insight into this world. Subscribe to our channel: http://bit.ly/1BwzEZM http://www.electronicbeats.net
Subscribe to the HBO YouTube: http://itsh.bo/10qIqsj Vinyl, a new drama series from Martin Scorsese, Mick Jagger and Terence Winter, debuts February 14 at 9PM on HBO. Soundtrack available from Atlantic Records February 2016, featuring “No Good” by Kaleo. Connect with HBO Online Follow @vinyl on Instagram: https://instagram.com/vinyl/ Like Vinyl on Facebook: https://www.facebook.com/VinylHBO HBO on Facebook: http://Facebook.com/HBO Follow @HBO on Twitter: http://Twitter.com/HBO Find HBO Official Site: http://HBO.com Find HBO Connect: http://Connect.hbo.com Find HBO GO: http://HBOGO.com Find HBO on Instagram: http://Instagram.com/hbo Check out other HBO Channels HBO: http://www.youtube.com/hbo Game of Thrones: http://www.youtube.com/GameofThrones Last Week Tonight: http://www.youtube.com...
There's no question the Internet opened up a whole new world of music consumption - first there were mp3 downloads, now there's a multitude of streaming music services like Spotify, Pandora, and Tidal. Digital distribution is now a dominating force in the industry. Yet something unexpected has been happening with vinyl records over the past decade - they've actually been on the rise. Nielson says vinyl record sales have steadily grown over the past ten years. And according to the RIAA, 2015 vinyl sales reached their highest level since 1988. Conventional wisdom says nostalgic baby boomers and Gen Xers are keeping this outdated format alive, but a growing number of younger fans are buying records now, too. In fact, MusicWatch reported that half of all record buyers in 2015 were under 25 yea...
Last week more vinyl records were sold than digital music downloads: 2.4 million pounds worth of physical album, double the amount last year, whereas only 2.1 million pounds worth of downloads. So is vinyl winning? We asked DJ and broadcaster Goldierocks (AKA Sam Hall), the music journalist Johnny Sharp and the lead singer in the band Hot Chip, Alexis Taylor. Newsnight is the BBC's flagship news and current affairs TV programme - with analysis, debate, exclusives, and robust interviews. Website: www.bbc.co.uk/newsnight YouTube: https://www.youtube.com/user/BBCNewsnight Twitter: https://twitter.com/BBCNewsnight Facebook: https://www.facebook.com/bbcnewsnight Snapchat: https://www.snapchat.com/add/bbcnewsnight
Buy Jarrett a Cup of Coffee! http://www.vinyleyezz.com/donate/ Subscribe to Vinyl Eyezz: https://www.youtube.com/channel/UC2oq8RM-S7dBk_cwF-Vvv5g?sub_confirmation=1 Visit our Website: www.vinyleyezz.com With the increase in record sales since 2010, You may be asking your self "Why Buy Vinyl"? In this video I discuss my top 5 reasons to own vinyl records. Send us Records! Jarrett New P.O. Box 2331 Toluca Lake, CA 91610 Like Vinyl Eyezz on Facebook: https://www.facebook.com/VinylEyezz Follow Vinyl Eyezz on Twitter: https://twitter.com/VinylEyezz Follow Vinyl Eyezz on Instagram: https://instagram.com/VinylEyezz Follow Vinyl Eyezz on Tumblr: https://www.tumblr.com/blog/vinyleyezz Follow Vinyl Eyezz on Pinterest: https://www.pinterest.com/vinyleyezz/ Vinyl Eyezz on 8tracks: https://...
GET VINYL HERE https://qrates.com/artists/12174/items/12895 Check out more at https://qrates.com GET MY FIRE MIXTAPE AT https://frankjavcee.bandcamp.com/ SPOTIFY LINK https://play.spotify.com/artist/3nHKeOa45XrUplL3NiGy7E SOCIAL MEDIAS FACEBOOK: http://Facebook.com/FrankJavCee TWITTER: http://Twitter.com/FrankJavCee INSTAGRAM: http://instagram.com/frankjavcee TUMBLR: https://FrankJAvCee.Tumblr.com YOUTUBE: https://www.youtube.com/user/FrankJavCee SNAPCHAT: FRANKJAVCEE SECOND CHANNEL https://www.youtube.com/channel/UCAaPISH4OqYrsuJYkJ9Y7Iw
Over 100 years after the technology's invention some people still consider vinyl as the only proper way to listen to music but how does vinyl work? Greg Foot explains the science behind a record. Footnotes 1: http://www.museumoftechnology.org.uk/stories/grams.html 2: http://www.bbc.co.uk/education/guides/z8d2mp3/revision 3: http://www.nytimes.com/2008/03/27/arts/27soun.html?_r=0 4: http://standardvinyl.com/vinyl-pressing/lacquers-masters/ and http://electronics.howstuffworks.com/record-player3.htm 5: http://www.wired.com/2015/03/hot-stampers/ 6: http://electronics.howstuffworks.com/record-player4.htm 7: https://youtu.be/GuCdsyCWmt8?t=4m25s 8: http://electronicdesign.com/site-files/electronicdesign.com/files/archive/electronicdesign.com/content/content/73698/73698-fig5.gif 9: http://www.b...
[Snoop Dogg]
Greetings loved ones
Let's take a journey
[Katy Perry]
I know a place
Where the grass is really greener
Warm, wet and wild
There must be something in the water
Sippin' gin and juice
Laying underneath the palm trees
(Undone)
The boys break their necks
Tryin' to creep a little sneak peek
Let's runaway
And don't ever look back
Don't ever look back
My heart stops
When you look at me
Just one touch
Now baby I believe
This is real
So take a chance
And don't ever look back
Don't ever look back
We drove to Cali
And got drunk on the beach
Got a motel and
Built a fort out of sheets
I finally found you
My missing puzzle piece
Baby, baby, baby ohh
Like baby, baby, baby noo
Like baby, baby, baby ohh
I thought youd always be mine,mine (oh oh)
For you, I would have done whatever
And I just can't believe, we ain't together
And I wanna play it cool, But I'm losin' you
I'll buy you anything, I'll buy you any ring
And im in pieces, Baby fix me
And just shake me til' you wake me from this bad dream
Chorus:
One love
My one heart
My one life for sure
Lemme tell you one time
(girl I love, girl I love you)
I'ma tell you one time
(girl I love, girl I love you)
And I'ma be your one guy
You'll be my number one girl
Always makin time for you
I'ma tell you one time
(girl I love, girl I love you)
I'ma tell you one time
(girl I love, girl I love you)
You look so deep
You know that it humbles me,
Your by my side and troubles them don't trouble me
Many have called but the chosen Is you
Whatever you want shawty I'll give it to you
Your world is my world (Your world)
And my fight is your fight (My fight)
My breath is your breath
And your heart (and now I've got my)
Chorus:
One love (Yeah yeah yeah)
My one heart
My one life for sure
Lemme tell you one time
(girl I love, girl I love you)
I'ma tell you one time (Hey)
(girl I love, girl I love you)
And I'ma be your one guy (one guy)
You'll be my number one girl
Always makin time for you
I'ma tell you one time
(girl I love, girl I love you)
I'ma tell you one time
(girl I love, girl I love you)
Looking for your hot stuff
Baby, I need it
Looking for your hot stuff
Baby, tonight
I want your hot stuff
I got to feel it
Got to have your hot stuff
Got to have your love tonight
Ooh yeah
I want you back
Ooh yeah
I want you back
I remember the love in your eye
When you took my hand and said goodbye
I don't know where the river flows
"Flirt"
Flirt, flirt!
You wanna chill in my Lamborghini,
You wanna look but you don't wanna see
So what you think of that look in my eyes?
You think it's for you?
You think you read minds?
You better watch where you're putting those hands,
You better stop if you're making more plans
'Coz everything you do makes you look like a fool
[Chorus]
You're looking for some dirt,
I'm lifting up my skirt
I'm searching for a light under me in my purse
You always think the worst,
I just wanna flirt
You found me on my knees,
Next thing you're saying "tease"
I'm trying to find my phone and my keys, not your sleaze
My spell is like a curse,
I just wanna flirt
What part of "No" don't you really understand?
One-syllable word, old man?
You got a problem with my space?
Get your look out of my face
'Coz I've had it with your lies
You're pretty damn close to being unfine
'Cuz everything you do makes you look like a fool
[Chorus]
I'm just so lucky to be walking on a wire,
I'm up so high that I can barely feel your fire
You can't touch me, no,
That's just a dream
Fill up my cup, mozoltov
Look at her dancing, just take it off
Let's paint the town, we'll shut it down
Let's burn the roof, and then we'll do it again
Let's do it, let's do it, let's do it, let's do it
And do it and do it, let's live it up
And do it and do it and do it, do it, do it
Let's do it, let's do it, let's do it
'Cause I gotta feeling, woohoo, that tonight's gonna be a good night
That tonight's gonna be a good night
That tonight's gonna be a good, good night
A feeling, woohoo, that tonight's gonna be a good night
That tonight's gonna be a good night
That tonight's gonna be a good, good night
I'm a be, I'm a be I'm a I'm a I'm a be.
I'm a be, I'm a be I'm a I'm a I'm a be.
I'm a be, I'm a be I'm a I'm a I'm a be.
I'm a be be be be I'm a I'm a be.
I'm a be be be be I'm a I'm a be.
I'm a be be be be I'm a I'm a be.
[Fergie:]
I'm a be on the next level
I'm a be rockin' over that bass treble
I'm a be chillin' with my muthafuckin' crew
I'm a be makin' all them deals you wanna do
I'm a be up in that maylist flicks
Doin' 100 flips, and I'm a be
Sippin' on drinks cause
I'm a be shakin' my hips
You gon' be lickin' your lips
I'm a be takin' them pics
Lookin' all fly and shit
They told him don't you ever come around here
Don't wanna see your face, you better disappear
The fire's in their eyes and their words are really clear
So beat it, just beat it
You better run, you better do what you can
Don't wanna see no blood, don't be a macho man
You wanna be tough, better do what you can
So beat it, but you wanna be bad
Just beat it, beat it, beat it, beat it
No one wants to be defeated
Showin' how funky and strong is your fight
It doesn't matter who's wrong or right
Just beat it, beat it
Just beat it, beat it
Just beat it, beat it
Just beat it, beat it
They're out to get you, better leave while you can
Don't wanna be a boy, you wanna be a man
You wanna stay alive, better do what you can
So beat it, just beat it
You have to show them that you're really not scared
You're playin' with your life, this ain't no truth or dare
They'll kick you, then they beat you,
Then they'll tell you it's fair
So beat it, but you wanna be bad
She was more like beauty queen from a movie scene
I said don't mind, but what do you mean I am the one
Who will dance on the floor in the round
She said I am the one who will dance on the floor in the round
[2nd verse]
She told me her name was Billie Jean, as she caused a scene
Then every head turned with eyes that dreamed of being the one
Who will dance on the floor in the round
[Bridge]
People always told me be careful what you do
Don't go around breaking young girls' hearts
And mother always told me be careful who you love
Be careful what you do 'cause the lie becomes the truth
[Chorus]
Billie Jean is not my lover
She's just a girl who claims that I am the one
But the kid is not my son
She says I am the one, but the kid is not my son
[3rd verse]
For forty days and forty nights
The law was on her side
But who can stand when she's in demand
Her schemes and plans
'Cause we danced on the floor in the round
So take my strong advice, just remember to always think twice
(Do think twice)
[4th verse]
She told my baby we'd danced 'till three
Then she looked at me
Then showed a photo of a baby cryin'
His eyes were like mine
Come on dance on the floor in the round, baby
[Bridge]
People always told me be careful what you do
Don't go around breaking young girls' hearts
She came and stood right by me
The smell of sweet perfume
This happened much too soon