Barium nitrate
Barium nitrate with chemical formula Ba(NO3)2 is a salt composed of barium and the nitrate ion.
Barium nitrate exists as a white solid at room temperature. It is soluble in water, and like other soluble barium compounds, is toxic. It occurs naturally as the rare mineral nitrobarite. Barium nitrate's properties make it suitable for use in various military applications, including thermite grenades and incendiary ammunition.
Manufacture
Barium nitrate is manufactured by one of two processes. The first involves dissolving small chunks of barium carbonate in nitric acid, allowing any iron impurities to precipitate, then filtered, evaporated, and crystallized. The second requires combining barium chloride with a heated solution of sodium nitrate, causing barium nitrate crystals to separate from the mixture.
Reactions
At elevated temperatures, barium nitrate decomposes to barium oxide, nitrogen dioxide, and oxygen:
In an atmosphere of nitric oxide, thermal decomposition produces barium nitrite (Ba(NO2)2). Reactions with soluble metal sulfates or sulfuric acid yield
barium sulfate. Many insoluble barium salts, such as the carbonate, oxalate and phosphate of the metal, are precipitated by similar double decomposition
reactions. Barium nitrate is an oxidizer and reacts vigorously with common reducing agents. The solid powder, when mixed with many other metals such as aluminium or zinc in their finely divided form, or combined with alloys such as aluminium-magnesium, ignites and explodes on impact.