DD

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Burning Bridges

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Combustion

Combustion /kəmˈbʌs.tʃən/ or burning is a high-temperature exothermic redox chemical reaction between a fuel and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion in a fire produces a flame, and the heat produced can make combustion self-sustaining. Combustion is often a complicated sequence of elementary radical reactions. Solid fuels, such as wood, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot enough that light in the form of either glowing or a flame is produced. A simple example can be seen in the combustion of hydrogen and oxygen into water vapor, a reaction commonly used to fuel rocket engines. This reaction releases 242 kJ/mol of heat and reduces the enthalpy accordingly (at constant temperature and pressure):

Combustion of an organic fuel in air is always exothermic because the double bond in O₂ is much weaker than other double bonds or pairs of single bonds, and therefore the formation of the stronger bonds in the combustion products CO₂ and H₂O results in the release of energy. The bond energies in the fuel play only a minor role, since they are similar to those in the combustion products; e.g., the sum of the bond energies of CH₄ is nearly the same as that of CO₂. The heat of combustion is approximately -418 kJ per mole of O₂ used up in the combustion reaction, and can be estimated from the elemental composition of the fuel.

Bridge

A bridge is a structure built to span physical obstacles without closing the way underneath such as a body of water, valley, or road, for the purpose of providing passage over the obstacle. There are many different designs that each serve a particular purpose and apply to different situations. Designs of bridges vary depending on the function of the bridge, the nature of the terrain where the bridge is constructed and anchored, the material used to make it, and the funds available to build it.

Etymology

The Oxford English Dictionary traces the origin of the word bridge to an Old English word brycg, of the same meaning. The word can be traced directly back to Proto-Indo-European *bʰrēw-. The word for the card game of the same name has a different origin.

History

The first bridges made by humans were probably spans of cut wooden logs or planks and eventually stones, using a simple support and crossbeam arrangement. Some early Americans used trees or bamboo poles to cross small caverns or wells to get from one place to another. A common form of lashing sticks, logs, and deciduous branches together involved the use of long reeds or other harvested fibers woven together to form a connective rope capable of binding and holding together the materials used in early bridges.