- published: 15 May 2013
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In quantum mechanics, a stationary state is an eigenvector of the Hamiltonian, implying the probability density associated with the wavefunction is independent of time. This corresponds to a quantum state with a single definite energy (instead of a probability distribution of different energies). It is also called energy eigenvector, energy eigenstate, energy eigenfunction, or energy eigenket. It is very similar to the concept of atomic orbital and molecular orbital in chemistry, with some slight differences explained below.
A stationary state is called stationary because a particle remains in the same state as time elapses, in every observable way. It has a constant probability distribution for its position, its velocity, its spin, etc. (This is true assuming the rest of the system is also static, i.e. the Hamiltonian is unchanging in time.) The wavefunction itself is not stationary: It continually changes its overall complex phase factor, so as to form a standing wave. The oscillation frequency of the standing wave, times Planck's constant, is the energy of the state according to the de Broglie relation.
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