- published: 08 Sep 2009
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A conjugate acid, within the Brønsted–Lowry acid–base theory, is a species formed by the reception of a proton (H+), by a base—in other words, the base with a hydrogen ion added to it. On the other hand, a conjugate base is merely what is left after an acid has donated a proton in a chemical reaction. Hence, a conjugate base is a species formed by the removal of a proton from an acid.
In summary, this can be represented as the following chemical reaction:
Johannes Nicolaus Brønsted and Martin Lowry introduced the Brønsted–Lowry theory, which proposed that any compound that can transfer a proton to any other compound is an acid, and the compound that accepts the proton is a base. A proton is a nuclear particle with a unit positive electrical charge; it is represented by the symbol H+ because it constitutes the nucleus of a hydrogen atom, that is, a hydrogen cation.
A cation can be a conjugate acid, and an anion can be a conjugate base, depending on which substance is involved and which acid–base theory is the viewpoint.
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The Brønsted–Lowry theory is an acid–base reaction theory which was proposed independently by Johannes Nicolaus Brønsted and Thomas Martin Lowry in 1923. The fundamental concept of this theory is that when an acid and a base react with each other, the acid forms its conjugate base, and the base forms its conjugate acid by exchange of a proton (the hydrogen cation, or H+). This theory is a generalization of the Arrhenius theory.
In the Arrhenius theory acids are defined as substances which dissociate in aqueous solution to give H+ (hydrogen ions). Bases are defined as substances which dissociate in aqueous solution to give OH− (hydroxide ions).
In 1923 physical chemists Johannes Nicolaus Brønsted in Denmark and Thomas Martin Lowry in England independently proposed the theory that carries their names. In the Brønsted–Lowry theory acids and bases are defined by the way they react with each other, which allows for greater generality. The definition is expressed in terms of an equilibrium expression
An acid–base reaction is a chemical reaction that occurs between an acid and a base. Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their application in solving related problems; these are called acid–base theories, for example, Brønsted–Lowry acid–base theory. Their importance becomes apparent in analyzing acid–base reactions for gaseous or liquid species, or when acid or base character may be somewhat less apparent. The first of these concepts was provided by the French chemist Antoine Lavoisier, around 1776.
The first scientific concept of acids and bases was provided by Lavoisier in around 1776. Since Lavoisier's knowledge of strong acids was mainly restricted to oxoacids, such as HNO
3 (nitric acid) and H
2SO
4 (sulfuric acid), which tend to contain central atoms in high oxidation states surrounded by oxygen, and since he was not aware of the true composition of the hydrohalic acids (HF, HCl, HBr, and HI), he defined acids in terms of their containing oxygen, which in fact he named from Greek words meaning "acid-former" (from the Greek οξυς (oxys) meaning "acid" or "sharp" and γεινομαι (geinomai) meaning "engender"). The Lavoisier definition was held as absolute truth for over 30 years, until the 1810 article and subsequent lectures by Sir Humphry Davy in which he proved the lack of oxygen in H2S, H2Te, and the hydrohalic acids. However, Davy failed to develop a new theory, concluding that "acidity does not depend upon any particular elementary substance, but upon peculiar arrangement of various substances". One notable modification of oxygen theory was provided by Berzelius, who stated that acids are oxides of nonmetals while bases are oxides of metals.
Conjugation or conjugate may refer to:
Introduction to conjugate acids and bases. Created by Sal Khan. Chemistry on Khan Academy: Did you know that everything is made out of chemicals? Chemistry is the study of matter: its composition, properties, and reactivity. This material roughly covers a first-year high school or college course, and a good understanding of algebra is helpful. About Khan Academy: Khan Academy offers practice exercises, instructional videos, and a personalized learning dashboard that empower learners to study at their own pace in and outside of the classroom. We tackle math, science, computer programming, history, art history, economics, and more. Our math missions guide learners from kindergarten to calculus using state-of-the-art, adaptive technology that identifies strengths and learning gaps. We've al...
Use Bronsted Lowry Acid/Base Theory to identify conjugate acid base pairs. More free chemistry help at www.chemistnate.com
This video discusses how to find the conjugate acid of a compound. To write the formula of the conjugate acid, simply add a hydrogen and add 1 to the charge of the original compound.
Introduction to conjugate acid-base pairs. Definition and examples of conjugate acid-base pairs. Chemistry on Khan Academy: Did you know that everything is made out of chemicals? Chemistry is the study of matter: its composition, properties, and reactivity. This material roughly covers a first-year high school or college course, and a good understanding of algebra is helpful. About Khan Academy: Khan Academy offers practice exercises, instructional videos, and a personalized learning dashboard that empower learners to study at their own pace in and outside of the classroom. We tackle math, science, computer programming, history, art history, economics, and more. Our math missions guide learners from kindergarten to calculus using state-of-the-art, adaptive technology that identifies str...
Learn everything about Conjugate Acids and Bases. We explain this with the real world example of vinegar. At Fuse School, teachers and animators come together to make fun & easy-to-understand videos in Chemistry, Biology, Physics, Maths & ICT. Our OER are available free of charge to anyone. Make sure to subscribe - we are going to create 3000 more! The Fuse School is currently running the Chemistry Journey project - a Chemistry Education project by The Fuse School sponsored by Fuse. These videos can be used in a flipped classroom model or as a revision aid. Find our other Chemistry videos here: https://www.youtube.com/playlist?list=PLW0gavSzhMlReKGMVfUt6YuNQsO0bqSMV Be sure to follow our social media for the latest videos and information! Twitter: https://twitter.com/fuseschool Faceb...
This chemistry video tutorial explains the concept of acids and bases using the arrhenius definition, bronsted - lowry and lewis acid base definition. It also shows you how to identify conjugate acid base pairs. This video contains plenty of examples and practice problems. List of topics: 1. Arrhenius Acid Base Definition 2. Acids release Hydrogen ions (H+) or Hydronium Ions in Solution 3. Bases release Hydroxide Ions (OH-) in solution. 4. Bronsted Lowry Acid Base Definition 5. Bronsted Lowry Acids are proton donors and Bronsted Lowry bases are proton acceptors 6. Acid base reactions with water 7. How to identify the bronsted lowry acid and base in a chemical reaction - Examples: NH3, HF, HCl, HCO3- 8. How to identify the conjugate acid and conjugate base pairs in a reaction 9....
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