- published: 16 Aug 2016
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An acid (from the Latin acidus/acēre meaning sour) is a chemical substance whose aqueous solutions are characterized by a sour taste, the ability to turn blue litmus red, and the ability to react with bases and certain metals (like calcium) to form salts. An aqueous solution of an acid has a pH of less than 7 and is colloquially also referred to as 'acid' (as in 'dissolved in acid'), while the strict definition refers only to the solute. An acid usually contains a hydrogen atom bonded to a chemical structure that is still energetically favorable after loss of H+ (a positive hydrogen ion or proton). A lower pH means a higher acidity, and thus a higher concentration of positive hydrogen ions in the solution. Chemicals or substances having the property of an acid are said to be acidic.
There are three common definitions for acids: the Arrhenius definition, the Brønsted-Lowry definition, and the Lewis definition. The Arrhenius definition defines acids as substances which increase the concentration of hydrogen ions (H+), or more accurately, hydronium ions (H3O+), when dissolved in water. The Brønsted-Lowry definition is an expansion to include solvents other than water: an acid is a substance which can act as a proton donor. By this definition, any compound which can be deprotonated can be considered an acid. Examples include alcohols and amines which contain O-H or N-H fragments. A Lewis acid is a substance that can accept a pair of electrons to form a covalent bond. Examples of Lewis acids include all metal cations, and electron-deficient molecules such as boron trifluoride and aluminium trichloride.
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