- published: 07 May 2013
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An ideal gas is a theoretical gas composed of a set of randomly-moving, non-interacting point particles. The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is amenable to analysis under statistical mechanics.
At normal conditions such as standard temperature and pressure, most real gases behave qualitatively like an ideal gas. Many gases such as air, nitrogen, oxygen, hydrogen, noble gases, and some heavier gases like carbon dioxide can be treated like ideal gases within reasonable tolerances. Generally, a gas behaves more like an ideal gas at higher temperature and lower density (i.e. lower pressure), as the work performed by intermolecular forces becomes less significant compared with the particles' kinetic energy, and the size of the molecules becomes less significant compared to the empty space between them.
The ideal gas model tends to fail at lower temperatures or higher pressures, when intermolecular forces and molecular size become important. It also fails for most heavy gases, such as water vapor or many refrigerants. At some point of low temperature and high pressure, real gases undergo a phase transition, such as to a liquid or a solid. The model of an ideal gas, however, does not describe or allow phase transitions. These must be modeled by more complex equations of state.
Ideal may refer to:
Gas is one of the three classical states of matter (the others being liquid and solid). Near absolute zero, a substance exists as a solid. As heat is added to this substance it melts into a liquid at its melting point (see phase change), boils into a gas at its boiling point, and if heated high enough would enter a plasma state in which the electrons are so energized that they leave their parent atoms from within the gas. A pure gas may be made up of individual atoms (e.g. a noble gas or atomic gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or compound molecules made from a variety of atoms (e.g. carbon dioxide). A gas mixture would contain a variety of pure gases much like the air. What distinguishes a gas from liquids and solids is the vast separation of the individual gas particles. This separation usually makes a colorless gas invisible to the human observer. The interaction of gas particles in the presence of electric and gravitational fields are considered negligible as indicated by the constant velocity vectors in the image.