- published: 27 Jun 2013
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Noble gas compounds are chemical compounds that include an element from Group 18 of the periodic table, the noble gases.
It was initially believed that the noble gases could not form compounds due to their full valence shell of electrons that rendered them very chemically stable and unreactive.
All noble gases have full s and p outer electron shells (except helium, which has no p sublevel), and so do not form chemical compounds easily. Because of their high ionization energy and almost zero electron affinity, they were not expected to be reactive.
In 1933 Linus Pauling predicted that the heavier noble gases would be able to form compounds with fluorine and oxygen. Specifically, he predicted the existence of krypton hexafluoride (KrF6) and xenon hexafluoride (XeF6), speculated that XeF8 might exist as an unstable compound, and suggested that xenic acid would form perxenate salts. These predictions proved quite accurate, although subsequent predictions for XeF8 indicated that it would be not only thermodynamically unstable, but kinematically unstable. As of 2009, XeF8 has not been made, although the octafluoroxenon(VI) anion (XeF82−) has been observed.