Audi A8 adaptive xenon lights turning on
Filmed by: Tomaž Kožar
Jesenice
Xenon was discovered in
England by
William Ramsay and
Morris Travers on July 12, 1898, shortly after their discovery of the elements krypton and neon. They found it in the residue left over from evaporating components of liquid air.[19][20]
Ramsay suggested the name xenon for this gas from the
Greek word ξένον [xenon], neuter singular form of ξένος [xenos], meaning 'foreign(er)', 'strange(r)', or 'guest'.[21][22] In 1902, Ramsay estimated the proportion of xenon in the
Earth's atmosphere as one part in 20 million.[23]
During the
1930s, engineer
Harold Edgerton began exploring strobe light technology for high speed photography. This led him to the invention of the xenon flash lamp, in which light is generated by sending a brief electrical current through a tube filled with xenon gas. In 1934, Edgerton was able to generate flashes as brief as one microsecond with this method.[12][24][25]
In
1939,
Albert R. Behnke Jr. began exploring the causes of "drunkenness" in deep-sea divers. He tested the effects of varying the breathing mixtures on his subjects, and discovered that this caused the divers to perceive a change in depth. From his results, he deduced that xenon gas could serve as an anesthetic. Although Lazharev, in
Russia, apparently studied xenon anesthesia in
1941, the first published report confirming xenon anesthesia was in 1946 by
J. H. Lawrence, who experimented on mice. Xenon was first used as a surgical anesthetic in 1951 by
Stuart C. Cullen, who successfully operated on two patients.[26]
Xenon and the other noble gases were for a long time considered to be completely chemically inert and not able to form compounds. However, while teaching at the
University of British Columbia,
Neil Bartlett discovered that the gas platinum hexafluoride (PtF6) was a powerful oxidizing agent that could oxidize oxygen gas (O2) to form dioxygenyl hexafluoroplatinate (O2+[PtF6]--).[27] Since O2 and xenon have almost the same first ionization potential,
Bartlett realized that platinum hexafluoride might also be able to oxidize xenon. On March 23, 1962, he mixed the two gases and produced the first known compound of a noble gas, xenon hexafluoroplatinate.[28][9] Bartlett thought its composition to be Xe+[PtF6]--, although later work has revealed that it was probably a mixture of various xenon-containing salts.[29][30][31] Since then, many other xenon compounds have been discovered,[32] along with some compounds of the noble gases argon, krypton, and radon, including argon fluorohydride (HArF),[33] krypton difluoride (KrF2),[34][35] and radon fluoride.[36] By
1971, more than 80 xenon compounds were known.[37][38]
[edit] Characteristics
Xenon flashAn atom of xenon is defined as having a nucleus with 54 protons. At standard temperature and pressure, pure xenon gas has a density of 5.761 kg/m3, about
4.5 times the surface density of the Earth's atmosphere, 1.217 kg/m3.[39] As a liquid, xenon has a density of up to 3.
100 g/mL, with the density maximum occurring at the triple
point.[40] Under the same conditions, the density of solid xenon, 3.640 g/cm3, is higher than the average density of granite, 2.75 g/cm3.[40] Using gigapascals of pressure, xenon has been forced into a metallic phase.[41]
Solid xenon changes from face-centered cubic (fcc) to hexagonal close packed (hcp) crystal phase under pressure and begins to turn metallic at about
140 GPa, with no noticeable volume change in the hcp phase. It is completely metallic at 155 GPa. When metalized, xenon looks sky blue because it absorbs red light and transmits other visible frequencies. Such behavior is unusual for a metal and is explained by the relatively small widths of the electron bands in metallic xenon.[42][43]
Xenon is a member of the zero-valence elements that are called noble or inert gases. It is inert to most common chemical reactions (such as combustion, for example) because the outer valence shell contains eight electrons. This produces a stable, minimum energy configuration in which the outer electrons are tightly bound
.[44] However, xenon can be oxidized by powerful oxidizing agents, and many xenon compounds have been synthesized.
In a gas-filled tube, xenon emits a blue or lavenderish glow when the gas is excited by electrical discharge. Xenon emits a band of emission lines that span the visual spectrum,[45] but the most intense lines occur in the region of blue light, which produces the coloration.[46]