Aldehydes and Ketones - Carbonyl Organic Chemistry Reactions Practice Test / Exam Review
This video tutorial provides an overview of aldehydes and ketones. It provides a nice review of what you need for your next organic chemistry test or exam.
Here's a list of topics contained in this video:
1. Nomenclature - Naming Compounds Containing Aldehyde and Ketone
Functional Groups.
Common names such as Benzaldehyde,
Acetone, Acetophenone, Cyclohexane Carbaldehyde, and Benzophenone are included.
2.
Physical Properties of Aldehydes & Ketones Including
Boiling Point,
Vapor Pressure, and
Water Solubility
3. Hydration
Reaction of Aldehydes & Ketones -
Forming Hydrates -Mechanism included.
4.
Relative Reactivity of Aldehydes & Ketones - Most Reactive to Least Reactive or Least
Stable to Most Stable
5. Steric
Factors Such as Steric
Hindrance vs
Electronic Factors Such
Electron Donating Groups and Electron Withdrawing Groups.
6. Enol-Ketone Tautomerism -
Reaction Mechanism of a Ketone into an Enol -
Acidic and
Basic Conditions.
7. The
Stability of Conjugated and
Aromatic Enols.
8. Acetal, Ketal, Hemiacetal, and Hemiketal
Formation.
9. Acetal Protecting Groups Using
Ethylene Glycol - Reaction Mechanism
10.
Grignard Reagent Reaction Mechanism With Aldehydes & Ketones
11. Aldehydes & Ketones Nucleophilic
Addition - NaBH4 & LiAlH4
Reduction Reactions
12. Cyanohydrin Formation - Reaction Mechanism - Acidic & Basic Conditions
13.
Primary Alcohol to Aldehyde Using
PCC Reaction Overview
14.
Secondary Alcohol to Ketone Using Na2Cr2O7 &
H2SO4
15.
Terminal Alkyne to Aldehyde Using Sia2BH
THF H2O2 NaOH
16. Terminal Alkyne to Ketone Using HgSO4, H2SO4, and
H2O
17.
Conversion of Nitrile to Imine to Ketone Reaction Mechanism
18.
Organolithium Reagents With Carbonyl Compounds
19. Imine vs Enamine - Primary vs Secondary Amines on Ketones
20. Ozonolysis - Converting Alkenes Into Aldehydes & Ketones
21. Fridel Crafts Acylation - Adding a Ketone
Near a Benzene
Ring
22. The
Wittig Reaction and
It's mechanism - Ylide, TriphenylPhosphine, Oxaphosphetane, Betain, Butyl
Lithium, etc.
23.
Tollen's Test - Ag(
NH3)2+ or Ag2O with THF and H2O
24.
Clemmensen Reduction - Zn, Hg, and HCl - Converting a Ketone into an Alkane
25. Wolff - Kishner Reduction Using
KOH and H2N-NH2 or
N2H4 / Hydrazine
26.
Direct Alkylation or alpha hydrogen substitution reactions of aldehydes and ketones with an alkyl halide like CH3Br or CH3CH2Br
27. Direct Alkylation Using an Enamine