Lead telluride[1][2] [3]
Other names Lead(II) telluride Altaite
Identifiers
CAS number	1314-91-6 Y
PubChem	4389803
Properties
Molecular formula	PbTe
Molar mass	334.80 g/mol
Appearance	gray cubic crystals
Density	8.164 g/cm3
Melting point	924°C
Solubility in water	insoluble
Band gap	0.25 eV (0 K) 0.32 eV (300 K)
Electron mobility	1600 cm2 V−1 s−1 (0 K) 6000 cm2 V−1 s−1 (300 K)
Structure
Crystal structure	Halite (cubic), cF8
Space group	Fm3m, No. 225
Coordination geometry	Octahedral (Pb2+) Octahedral (Te2−)
Thermochemistry
Std enthalpy of formation ΔfHo298	-70.7 kJ·mol-1
Std enthalpy of combustion ΔcHo298	110.0 J·mol-1·K-1
Standard molar entropy So298	50.5 J·mol-1·K-1
Hazards
MSDS	External MSDS
EU Index	082-001-00-6
EU classification	Repr. Cat. 1/3 Harmful (Xn) Dangerous for the environment (N)
R-phrases	R61, R20/22, R33, R62, R50/53
S-phrases	S53, S45, S60, S61
Flash point	Non-flammable
Related compounds
Other anions	Lead(II) oxide Lead(II) sulfide Lead selenide
Other cations	Carbon monotelluride Silicon monotelluride Germanium telluride Tin telluride
Related compounds	Thallium telluride Bismuth telluride
Y (verify) (what is: Y/N?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Lead telluride is a compound of lead and tellurium (PbTe); it is a narrow gap semiconductor. It occurs naturally as the mineral altaite.

Properties[link]

• Dielectric constant ~1000.
• Electron Effective mass ~ 0.01m_e
• Hole mobility, μ_p = 600 cm² V⁻¹ s⁻¹ (0 K); 4000 cm² V⁻¹ s⁻¹ (300 K)

Applications[link]

It is often alloyed with tin to make lead tin telluride, which is used as an infrared detector material. It also has good performance as a thermoelectric material, partly due to a low thermal conductivity.

References[link]

This article needs additional citations for verification. Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed. (May 2009)

External links[link]

• National Pollutant Inventory Lead and compounds fact sheet
• Webelements

Paolo Nutini
Paolo Nutini performing in 2009.
Background information
Birth name	Paolo Giovanni Nutini
Born	(1987-01-09) 9 January 1987 (age 25)
Origin	Paisley, Scotland
Genres	Pop rock, Blue eyed soul, folk, blues, Easy Listening,
Occupations	Singer-songwriter, musician
Instruments	Vocals, guitar
Years active	2005–present
Labels	Atlantic
Website	paolonutini.com

Paolo Giovanni Nutini (born 9 January 1987^[1]) is a Scottish singer, songwriter and musician from Paisley.

Paolo Nutini's debut album, These Streets, was released by Atlantic Records in the United Kingdom in July 2006 and included the singles "Last Request", "Jenny Don't Be Hasty", "Rewind" and "New Shoes". "Last Request", the most successful, reached number five on the UK Singles Chart. The album peaked at number three on the UK Album Chart and was certified 4× platinum by the British Phonographic Industry (BPI).^[2] It has been in the album charts for a record-breaking 196 weeks.

In May 2009 Nutini released his second album, Sunny Side Up, which debuted at number one in the UK and has produced four singles; "Candy", "Coming Up Easy", "Pencil Full of Lead" and "10/10". It has so far been certified 4x platinum by the BPI.^[2] On 19 February 2010, it scooped "Best International Album" at the 2010 Meteor Awards.

Life and career[link]

Early life and breakthrough (1987–2006)[link]

Nutini's father is of Italian descent, from Barga, Tuscany, although both his parents are third-generation Scottish.

Paolo Nutini was expecting to follow his father into the family fish and chip shop business. He was first encouraged to sing by his music-loving grandfather, Jackie, and a teacher at his school, St Andrews Academy, who recognised his talent. He left school to work as a roadie and to sell t-shirts for Speedway. He spent three years learning the music business and performing live. He later worked as a studio hand at Glasgow's Park Lane Studio.

His big chance came when he attended a concert staged by 102.5 Clyde 1 for David Sneddon's return to his home town of Paisley at the beginning of 2003. Sneddon was delayed, and as the winner of an impromptu pop quiz, Nutini was given the chance to perform a couple of songs on stage during the wait. The favourable reaction of the crowd impressed another member of the audience, Brendan Moon, who offered to become his manager. Brendan and his business partner Mike Bawden continue to manage Paolo. Only 17, Nutini moved to London and performed regularly at The Bedford pub in Balham. Other radio and live appearances followed, including two live acoustic spots on Radio London, The Hard Rock Cafe, and support slots for The Rolling Stones, Amy Winehouse and KT Tunstall.

When Nutini was young he was a member of PACE Youth Theatre

[edit] These Streets and mainstream breakthrough (2006–2009)

Nutini performing in September 2006.

Throughout 2006 Nutini played a number of sold-out concerts in the UK and performed at a wide variety of venues worldwide, including King Tut's Wah Wah Hut in Glasgow, a TV appearance on Later with Jools Holland, Carnegie Hall in New York, The Montreux Jazz Festival, The Wireless Festival, Oxegen and T in the Park. He supported the Rolling Stones in Vienna and was invited to appear with them again at the Don Valley Stadium in August 2006. He was also booked to appear at the V Festival and The Austin City Limits Music Festival, Texas later in 2006, with a European tour in the autumn. In May 2006, he also played at BBC Radio 1's Big Weekend in Dundee.

On Hogmanay 2006, Nutini appeared on BBC Scotland's Hogmanay Live celebrations, after the official celebrations in Princes Street Gardens were cancelled at short notice due to abysmal weather. He performed several songs in the Great Hall of Edinburgh Castle for the TV audience with little or no rehearsal. On Wednesday 11 April 2007, Nutini performed in a concert that was streamed live via MSN Music.

Nutini performed at the Glastonbury Festival in June 2007 on the famous Pyramid Stage on the second day of the event. Nutini also performed at the UK leg of Live Earth at Wembley Stadium on 7 July 2007, with his set including a cover of "What A Wonderful World", a classic pop tune by Bob Thiele, George David Weiss, and George Douglas. He performed the following day at T in the Park, in Scotland.^[3] He performed at the Ahmet Ertegün Tribute Concert on 10 December 2007, an event that drew enormous international attention as it was the first full live concert performance by Led Zeppelin in 27 years. Scottish independent TV company Volt MediaFix made a one-off documentary of Nutini's US tour. The programme, for the BBC, was scheduled for broadcast on BBC2, on Thursday 7 June throughout Scotland and on Sky channel 990 throughout the rest of the UK.

Nutini's songs have infiltrated American TV shows as well. "Last Request" featured at the end of the Scrubs episode "My Words of Wisdom" from Season 6, the first-ever episode of "Gavin and Stacey," and the One Tree Hill Season-4 episode "The Birth and Death of the Day." "Million Faces" could be heard at the end of the Grey's Anatomy episode "Testing 1–2–3" from Season 3 and is on the Volume 3 Soundtrack. "Rewind" was played at the end of CSI: Miami Season-5 episode "Broken Home." "Jenny, Don't Be Hasty" was also featured on another member of the CSI franchise when it played on CSI: NY's Season-3-finale, "Snow Day". "New Shoes" featured in The Jane Austen Book Club and in a TV ad for Puma AG during summer 2008. On 24 July 2007, Nutini was awarded The Golden St. Christopher medal by the city of Barga in Italy, the highest honour the city can give, to celebrate his extraordinary contributions to Barga and its people.^[4] On 17 September, Nutini performed on The Tonight Show with Jay Leno performing "Last Request". In September 2007, Nutini recorded a short radio show with imeem.com where he listed his top 10 favourite tracks and the reasons behind his choices.^[5] In October 2007, Nutini performed for the annual Voodoo Fest held in New Orleans, Louisiana. In 2008, Nutini's music was featured in a movie adaptation of Irvine Welsh's best-selling novel Ecstasy: Three Tales of Chemical Romance. On New Year's Eve 2008–09, Nutini performed at the Hogmanay street parties in both Edinburgh and Glasgow, Scotland, becoming the first act to play both locations on the same day for the event. In The View's 2009 album Which Bitch?, he is featured singing on the song "Covers."

[edit] Sunny Side Up and continued musical success (2009–present)

On 1 June 2009, Nutini released his second studio album Sunny Side Up, which debuted at number one. The first single from the album "Candy" was released on 25 May. In July, he appeared on Friday Night with Jonathan Ross, performing "Coming Up Easy". This was released as the second single to the album on 10 August and it debuted at number 62 in the UK Singles Chart on 16 August 2009.^[6] On 10 September 2009, Nutini performed "Coming Up Easy" on The Tonight Show with Conan O'Brien. The third single from the album was "Pencil Full of Lead".

The album received a mixed critical reception. Allmusic's Thom Jurek noted the move away from the sound of the debut album: "Nutini has taken huge chunks of America's (and Scotland's) pop and folk pasts and reshaped them in his own image," going on to describe it as "wise beyond this songwriter's years".^[7] Andy Gill of The Independent commented on Nutini's progress since his debut, saying the album "sees the singer making giant strides in several directions", and going on to say "don't be surprised if, come December, this is one of the year's biggest-selling albums."^[8] Neil McCormick of The Daily Telegraph was also positive, stating "his joyous second album organically blends soul, country, folk and the brash, horny energy of ragtime swing."^[9]

Some reviewers were less impressed. It was described by The Guardian's Caroline Sullivan as "not bad", with opening track "10/10" described as "jaunty enough to make you retch".^[10] Graeme Thompson of The Observer saw the album as an attempt by Nutini at "rebranding himself as a mongrel hybrid of John Martyn, Otis Redding and Bob Marley".^[11]

The album debuted at number one on the UK Albums Chart with sales of over 60,000 copies, fighting off strong competition from Love & War, the debut album of fellow male solo artist Daniel Merriweather. The album performed similarly well on the Irish Albums Chart, debuting at number two behind Eminem's new album before rising to the top of the charts the week after.

The album has been one of the best UK album sales of the year. On the UK Albums Chart on the Week of Monday 19 Oct, the album move from number 31 to number 5, making the album sell more than The Saturdays' second album.^[12] On 3 January 2010 Sunny Side Up topped the UK Album Charts for a second time, making the album the first Number one album in the United Kingdom of 2010 and the decade.^{[13][14][15][16][17]}

On 19 February 2010, Colin Farrell presented Nutini with "Best International Album" for Sunny Side Up at the 2010 Meteor Awards.^[18]

Paolo Nutini embarked on a world tour with his Sunny Side Up album. The band consisted of, in addition to Paolo: Donny Little-Guitars, Vocals Seamus Simon-Drums Michael McDaid-Bass, Keyboard Dave Nelson-Guitars, Keyboard, Vocals, Percussion Gavin Fitzjohn-Trumpet, Saxophone Ben Edwards - trumpet & flugelhorn, and Tom Pinder - trombone & sousaphone. The brass section are collectively known as the "Horns of Thunder" (a name formed by Paolo himself)

Legacy[link]

Recording history[link]

Paolo Nutini performing in 2008.

Nutini made his first demo which saw him signed to Atlantic Records in May 2005, shortly after his 18th birthday. He released his first single "These Streets" as a free download in May 2006; this was then followed by his next single "Last Request" which was released on 4 July 2006 and charted at number 5 in the official UK charts. In the video for "Last Request", Nutini plays the part of a robber – though this is not revealed until the end. Nutini's third single, "Jenny Don't Be Hasty", was released on 25 September 2006 and got to number 20 on the UK Singles Chart. "Rewind" was Nutini's fourth single. It was released on 4 December 2006, and reached number 27 in the UK.

His debut album These Streets, produced by Ken Nelson (who has also worked with Coldplay and Gomez), was released on 17 July 2006 and immediately entered the UK album charts at number three. Many of the songs on the album, including "Last Request" and "Rewind", were inspired by a turbulent relationship with his girlfriend Teri Brogan, and "Jenny Don't Be Hasty" is a true story about encounters with an older woman. These Streets, as Paolo himself puts it on his official website, he states, "The album is a little glimpse of some of the experiences I have been through in the last three years". In late 2007 he covered Labi Siffre's "It Must Be Love" for BBC Radio 1's Radio 1 Established 1967 album.

His self-produced second album Sunny Side Up was released on 1 June 2009.^[19]

As of February 2011, Paolo Nutini was in the studio working on new material.^[20]

Discography[link]

Albums[link]

• These Streets (2006)
• Sunny Side Up (2009)

Awards and nominations[link]

External links[link]

• Official Paolo Nutini website
• "Singer Paulo Nutini headlined the Hogmanay bash..." eveningtimes.co.uk,^[29] 1–1–09.

References[link]

Doc Watson
Doc Watson at Sugar Grove Music Festival in 2009
Background information
Birth name	Arthel Lane Watson
Also known as	Doc Watson
Born	(1923-03-03)March 3, 1923 Deep Gap, North Carolina
Died	May 29, 2012(2012-05-29) (aged 89) Winston-Salem, North Carolina
Genres	Blues, bluegrass, country, folk, gospel
Occupations	Musician, singer-songwriter
Instruments	Vocals, guitar, banjo, harmonica
Labels	Folkways, Vanguard, United Artists, Flying Fish, Sugar Hill

Arthel Lane "Doc" Watson (March 3, 1923 – May 29, 2012) was an American guitarist, songwriter and singer of bluegrass, folk, country, blues and gospel music. Watson won seven Grammy awards as well as a Grammy Lifetime Achievement Award. Watson's flatpicking skills and knowledge of traditional American music are highly regarded. He performed with his son Merle for over 15 years until Merle's death in 1985, in an accident on the family farm.^[1][2][3]

Biography[link]

Early life[link]

Watson was born in Deep Gap, North Carolina. According to Watson on his three-CD biographical recording Legacy, he got the nickname "Doc" during a live radio broadcast when the announcer remarked that his given name Arthel was odd and he needed an easy nickname. A fan in the crowd shouted "Call him Doc!" presumably in reference to the literary character Sherlock Holmes's sidekick Doctor Watson. The name stuck ever since.^[4]

An eye infection caused Doc Watson to lose his vision before his first birthday. Despite this, he was taught by his parents to work hard and care for himself. He attended North Carolina's school for the visually impaired, The Governor Morehead School, in Raleigh, North Carolina.^[5]

In a 1989 radio interview with host Terry Gross on the Fresh Air show of National Public Radio (NPR), Watson explains how he got his first guitar. His father told him that if he and his brother (David Watson) chopped down all the small, dead, chestnut trees along the edge of their field, he could sell the wood to the tannery and make money. The brothers did the work and Watson bought a $10 Stella guitar from Sears Roebuck while his brother bought a new suit.^[6] Later in that same interview, Watson explained that his first high quality guitar was a Martin Guitar D-18.^[7]

Watson's earliest influences were the roots of country, including the Carter Family and Jimmy Rodgers. The first song he learned to play on the guitar was "When Roses Bloom in Dixieland", first recorded by the Carter Family in 1930. Watson stated in an interview with American Songwriter that, "Jimmy Rodgers was the first man that I started to claim as my favorite."^[8] Watson proved to be a natural musical talent and within months was performing on local street corners playing songs from the Delmore Brothers, Louvin Brothers, and Monroe Brothers alongside his brother Linny. By the time Watson reached adulthood, he had become a proficient acoustic and electric guitar player.^[9]

Career[link]

In 1953, Watson joined the Johnson City, Tennessee-based Jack Williams' country and western swing band on electric guitar. The band seldom had a fiddle player, but was often asked to play at square dances. Following the example of country guitarists Grady Martin and Hank Garland, Watson taught himself to play fiddle tunes on his Les Paul electric guitar. He later transferred the technique to acoustic guitar, and playing fiddle tunes became part of his signature sound.^[1][10] During his time with Jack Williams, Doc also supported his family as a piano tuner.

In 1960, as the American folk music revival grew, Watson took the advice of folk musicologist Ralph Rinzler and began playing acoustic guitar and banjo exclusively.^[5] That move ignited Watson's career when he played on his first recording, Old Time Music at Clarence Ashley's. Also of pivotal importance for his career was his February 11, 1961 appearance at P.S. 41 in Greenwich Village.^[11] He subsequently began to tour as a solo performer and appeared at universities and clubs like the Ash Grove in Los Angeles. Watson would eventually get his big break and rave reviews for his performance at the renowned Newport Folk Festival in Newport, Rhode Island in 1963. Watson recorded his first solo album in 1964 and began performing with his son Merle the same year.

After the folk revival waned during the late 1960s, Watson's career was sustained by his performance of "Tennessee Stud" on the 1972 live album recording Will the Circle Be Unbroken. As popular as ever, Doc and Merle began playing as a trio, with T. Michael Coleman on bass guitar, in 1974. The trio toured the globe during the late seventies and early eighties, recorded nearly fifteen albums between 1973 and 1985, and brought Doc and Merle’s unique blend of acoustic music to millions of new fans. In 1985, Merle died in a tractor accident.^[10]

Doc Watson sculpture on the corner of King and Depot Streets in Boone, North Carolina. The plaque on the bench reads "Just one of the People".

Watson played guitar in both flatpicking and fingerpicking style, but is best known for his flatpick work. His guitar playing skills, combined with his authenticity as a mountain musician, made him a highly influential figure during the folk music revival. Watson pioneered a fast and flashy bluegrass, lead guitar style including fiddle tunes and crosspicking techniques which were adopted and extended by Clarence White, Tony Rice and many others. Watson was also an accomplished banjo player and sometimes accompanied himself on harmonica as well. Known also for his distinctive and rich baritone voice, Watson over the years developed a vast repertoire of mountain ballads, which he learned via the oral tradition of his home area in Deep Gap, North Carolina. His affable manner, humble nature and delightful wit endeared him to his fans nearly as much as his musical talent.

Watson played a Martin model D-18 guitar on his earliest recordings. In 1968, Watson began a relationship with Gallagher Guitars when he started playing their G-50 model. His first Gallagher, which Watson refers to as "Old Hoss", is on display at the Country Music Hall of Fame in Nashville, Tennessee. In 1974, Gallagher created a customized G-50 line to meet Watson's preferred specifications, which bears the Doc Watson name. In 1991, Gallagher customized a personal cutaway guitar for Watson that he played until his death and which he referred to as "Donald" in honor of Gallagher guitar's second generation proprietor and builder, Don Gallagher. ^[12] For the last few years, Doc had been playing a Dana Bourgeois dreadnought given to him by Ricky Skaggs for his 80th birthday.

In 1986, Watson received the North Carolina Award and in 1994 he received a North Carolina Folk Heritage Award. Also in 1994, Watson teamed up with musicians Randy Scruggs and Earl Scruggs to contribute the classic song "Keep on the Sunny Side" to the AIDS benefit album Red Hot + Country produced by the Red Hot Organization.

Later life[link]

In 2000, Watson was inducted into the International Bluegrass Music Hall of Honor in Owensboro, Kentucky. In 1997, Watson received the National Medal of Arts from U.S. president Bill Clinton.^[13] In 2010, he was awarded an honorary doctor of music degree from Berklee College of Music in Boston, Massachusetts.^[14]

In his later life, Watson scaled back his touring schedule. Watson was generally joined onstage by his grandson (Merle's son) Richard, as well as longtime musical partners David Holt or Jack Lawrence. On one occasion, Watson was accompanied by Australian guitar player Tommy Emmanuel at a concert at the Bass Performance Hall in Fort Worth, Texas. Watson also performed, accompanied by Holt and Richard, at the Hardly Strictly Bluegrass festival in San Francisco, California in 2009, as he had done in several previous years.

Watson hosted the annual MerleFest music festival held every April at Wilkes Community College in Wilkesboro, North Carolina. The festival features a vast array of acoustic style music focusing on the folk, bluegrass, blues and old-time music genres. It was named in honor of Merle Watson and is one of the most popular acoustic music festivals in the world, drawing over 70,000 music fans each year.^[15]

In 2010, Blooming Twig Books published "Blind But Now I See" by Dr. Kent Gustavson, the first comprehensive biography of the seminal flatpicking guitarist.

Personal life[link]

In 1947, Doc married Rosa Lee Carlton, the daughter of popular fiddle player Gaither Carlton. Watson and Rosa Lee had two children — Eddy Merle (named after country music legends Eddy Arnold and Merle Travis) in 1949 and Nancy Ellen in 1951.^[5]

In late May 2012, Watson was listed in critical condition but was responsive at Wake Forest Baptist Medical Center in Winston-Salem, North Carolina, after undergoing colon surgery.^[16] Watson fell at his home earlier in the week, after which he was sent to Watauga Medical Center in nearby Boone, NC. Watson was not seriously injured in the fall, but an underlying medical condition prompted the surgery which required him to be airlifted to Winston-Salem.^[17] Watson died on May 29, 2012 at Wake Forest Baptist at the age of 89.^[18]

Discography[link]

Awards & honors[link]

Grammy awards[link]

• 1973 Best Ethnic Or Traditional Recording (Including Traditional Blues): Doc Watson for Then And Now
• 1974 Best Ethnic Or Traditional Recording: Merle Watson & Doc Watson for Two Days In November
• 1979 Best Country Instrumental Performance: Doc Watson & Merle Watson for Big Sandy/Leather Britches
• 1986 Best Traditional Folk Recording: Doc Watson for Riding The Midnight Train
• 1990 Best Traditional Folk Recording: Doc Watson for On Praying Ground
• 2002 Best Traditional Folk Album: Doc Watson & David Holt for Legacy
• 2004 Lifetime Achievement Award
• 2006 Best Country Instrumental Performance: Bryan Sutton & Doc Watson for Whiskey Before Breakfast track from Not Too Far From The Tree by Bryan Sutton

References[link]

External links[link]

• Doc's Guitar : A site dedicated to the guitar and music of Doc Watson
• Podcast of Doc Watson and Jack Lawrence performing live at the 1996 Florida Folk Festival from the Florida Folklife Collection (made available for public use by the State Archives of Florida)
• Live 1977 recording of "The Cuckoo Bird" by Doc and Merle Watson from the Florida Folklife Collection (made available for public use by the State Archives of Florida)
• Live 1996 recording of "Shady Grove" by Doc and Jack Lawrence from the Florida Folklife Collection (made available for public use by the State Archives of Florida)
• MerleFest
  • MerleFest official website
  • "Doc's orders: No heavy metal at MerleFest" 2007 article in the Hook weekly
• National Public Radio
  • Guitarist Arthel 'Doc' Watson Interview on NPR's Fresh Air
  • Morning Edition's Bob Edwards interview Doc Watson from 1985
  • Morning Edition's Bob Edwards interview Doc Watson from 1989
• Prairie Home Companion
  • Doc Watson & Taj Mahal August 9, 1986 (db.etree.org)
  • October 23, 1999
  • February 14, 2004

Article on Doc Watson and other western NC guitar players [2]