- published: 05 Aug 2013
- views: 822733
Quantum chemistry is a branch of chemistry whose primary focus is the application of quantum mechanics in physical models and experiments of chemical systems. It is also called molecular quantum mechanics.
It involves heavy interplay of experimental and theoretical methods:
Khan Academy is a non-profit educational organization created in 2006 by educator Salman Khan with the aim of providing a free, world-class education for anyone, anywhere. The organization produces short lectures in the form of YouTube videos. In addition to micro lectures, the organization's website features practice exercises and tools for educators. All resources are available for free to anyone around the world. The main language of the website is English, but the content is also available in other languages.
The founder of the organization, Salman Khan, was born in New Orleans, Louisiana, United States to immigrant parents from Bangladesh and India. After earning three degrees from the Massachusetts Institute of Technology (a BS in mathematics, a BS in electrical engineering and computer science, and an MEng in electrical engineering and computer science), he pursued an MBA from Harvard Business School.
In late 2004, Khan began tutoring his cousin Nadia who needed help with math using Yahoo!'s Doodle notepad.When other relatives and friends sought similar help, he decided that it would be more practical to distribute the tutorials on YouTube. The videos' popularity and the testimonials of appreciative students prompted Khan to quit his job in finance as a hedge fund analyst at Connective Capital Management in 2009, and focus on the tutorials (then released under the moniker "Khan Academy") full-time.
In physics, a quantum (plural: quanta) is the minimum amount of any physical entity involved in an interaction. Behind this, one finds the fundamental notion that a physical property may be "quantized," referred to as "the hypothesis of quantization". This means that the magnitude can take on only certain discrete values.
A photon is a single quantum of (visible) light as well as all other forms of electromagnetic radiation and can be referred to as a "light quantum". The energy of an electron bound to an atom is quantized, which results in the stability of atoms, and hence of matter in general.
As incorporated into the theory of quantum mechanics, this is regarded by physicists as part of the fundamental framework for understanding and describing nature.
The word "quantum" comes from the Latin "quantus", meaning "how much". "Quanta", short for "quanta of electricity" (electrons) was used in a 1902 article on the photoelectric effect by Philipp Lenard, who credited Hermann von Helmholtz for using the word in the area of electricity. However, the word quantum in general was well known before 1900. It was often used by physicians, such as in the term quantum satis. Both Helmholtz and Julius von Mayer were physicians as well as physicists. Helmholtz used "quantum" with reference to heat in his article on Mayer's work, and indeed, the word "quantum" can be found in the formulation of the first law of thermodynamics by Mayer in his letter dated July 24, 1841. Max Planck used "quanta" to mean "quanta of matter and electricity", gas, and heat. In 1905, in response to Planck's work and the experimental work of Lenard (who explained his results by using the term "quanta of electricity"), Albert Einstein suggested that radiation existed in spatially localized packets which he called "quanta of light" ("Lichtquanta").
Chemistry is a branch of physical science that studies the composition, structure, properties and change of matter. Chemistry includes topics such as the properties of individual atoms, how atoms form chemical bonds to create chemical compounds, the interactions of substances through intermolecular forces that give matter its general properties, and the interactions between substances through chemical reactions to form different substances.
Chemistry is sometimes called the central science because it bridges other natural sciences, including physics, geology and biology. For the differences between chemistry and physics see Comparison of chemistry and physics.
Scholars disagree about the etymology of the word chemistry. The history of chemistry can be traced to alchemy, which had been practiced for several millennia in various parts of the world.
The word chemistry comes from the word alchemy which was an earlier set of practices that encompassed elements of chemistry, metallurgy, philosophy, astrology, astronomy, mysticism and medicine. It is often seen as linked to the quest to turn lead or another common starting material into gold. Alchemy, which was practiced around 330, is the study of the composition of waters, movement, growth, embodying, disembodying, drawing the spirits from bodies and bonding the spirits within bodies (Zosimos). An alchemist was called a 'chemist' in popular speech, and later the suffix "-ry" was added to this to describe the art of the chemist as "chemistry".
Quantum mechanics (QM; also known as quantum physics or quantum theory) including quantum field theory, is a fundamental branch of physics concerned with processes involving, for example, atoms and photons. In such processes, said to be quantized, the action has been observed to be only in integer multiples of the Planck constant, a physical quantity that is exceedingly, indeed perhaps ultimately, small. This is utterly inexplicable in classical physics.
Quantum mechanics gradually arose from Max Planck's solution in 1900 to the black-body radiation problem (reported 1859) and Albert Einstein's 1905 paper which offered a quantum-based theory to explain the photoelectric effect (reported 1887). Early quantum theory was profoundly reconceived in the mid-1920s.
The reconceived theory is formulated in various specially developed mathematical formalisms. In one of them, a mathematical function, the wave function, provides information about the probability amplitude of position, momentum, and other physical properties of a particle.
Orbitals: Crash Course Chemistry #25
Quantum numbers | Electronic structure of atoms | Chemistry | Khan Academy
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In this episode of Crash Course Chemistry, Hank discusses what Molecules actually look like and why, some quantum-mechanical three dimensional wave functions are explored, he touches on hybridization, and delves into sigma and pi bonds. -- Table of Contents Molecules: Clumpy Globs... 0:18 Quantum-Mechanical Three-Dimensional Wave Functions 3:06 S & P Orbital Hybridization 5:27 Sigma & Pi Bonds 7:32 Hybridized Orbitals 5:52 -- Want to find Crash Course elsewhere on the internet? Facebook - http://www.facebook.com/YouTubeCrashCourse Twitter - http://www.twitter.com/TheCrashCourse Tumblr - http://thecrashcourse.tumblr.com Support CrashCourse on Subbable: http://subbable.com/crashcourse
Definition of orbital as region of high probability for finding electron, and how quantum numbers are used to describe the orbitals. Compares Bohr model orbits and quantum mechanical model of atom. Created by Jay. Watch the next lesson: https://www.khanacademy.org/science/chemistry/electronic-structure-of-atoms/orbitals-and-electrons/v/quantum-numbers-for-the-first-four-shells?utm_source=YT&utm;_medium=Desc&utm;_campaign=chemistry Missed the previous lesson? https://www.khanacademy.org/science/chemistry/electronic-structure-of-atoms/orbitals-and-electrons/v/heisenberg-uncertainty-principle?utm_source=YT&utm;_medium=Desc&utm;_campaign=chemistry Chemistry on Khan Academy: Did you know that everything is made out of chemicals? Chemistry is the study of matter: its composition, properties, and...
Like us on Facebook: https://www.facebook.com/advexondocumentary Watch our new Video -- https://www.youtube.com/watch?v=gmw4Me4uSBk The World of Quantum - Full Documentary HD 2014 http://www.advexon.com For more Scientific DOCUMENTARIES. Subscribe for more Videos... Quantum mechanics (QM -- also known as quantum physics, or quantum theory) is a branch of physics which deals with physical phenomena at nanoscopic scales where the action is on the order of the Planck constant. It departs from classical mechanics primarily at the quantum realm of atomic and subatomic length scales. Quantum mechanics provides a mathematical description of much of the dual particle-like and wave-like behavior and interactions of energy and matter. Quantum mechanics provides a substantially useful framework for...
Orbitals! Oh no. They're so weird. Don't worry, nobody understands these in first-year chemistry. You just pretend to, and then in second-year you learn them a little better, the following year a little better, and once you have a PhD you will know what they are. But let Professor Dave give you a head start! Subscribe: http://bit.ly/ProfDaveSubscribe ProfessorDaveExplains@gmail.com http://professordaveexplains.com http://facebook.com/ProfessorDaveExpl... http://twitter.com/DaveExplains General Chemistry - Online Tutorials: http://bit.ly/ProfDaveGenChem Organic Chemistry - Online Tutorials: http://bit.ly/ProfDaveOrgChem Science for Common Folk - Online Tutorials: http://bit.ly/ProfDaveScience4CommonFolk
IBM Q systems will be designed to tackle problems in business and science that are too complex and exponential in nature for classical computing systems to handle. One of the first and most promising applications will be in the area of chemistry. Even for simple molecules like caffeine, the number of quantum states in the molecule can be astoundingly large -- so large that all the conventional computing memory and processing power that could ever be built could not model it. Jerry Chow, manager of experimental quantum computing for IBM Research, explains that modeling a molecule is the key to understanding its properties -- and could lead to the discovery of new materials and medicines. For more about IBMQ: https://ibm.com/ibmq
How quantum chemistry can be used to improve our understanding of chemical reactions, via the example of oxygen binding to iron in haemoglobin in our lungs.
9:00 – 9:15 AM Welcome and Introduction Speaker: Michael Freedman, Microsoft Station Q Bio: Michael Freedman is Director of Station Q, Microsoft’s Project on quantum physics and quantum computation located on the UCSB campus. The project is a collaborative effort between Microsoft and academia directed towards exploring the mathematical theory and physical foundations for quantum computing. 9:15 – 9:30 AM Quantum Computing: A Short Tutorial Speaker: Krysta Svore, Microsoft Research QuArC Bio: Krysta Svore is a Researcher in the Quantum Architectures and Computation Group (QuArC) at Microsoft Research in Redmond, WA. 9:30 – 9:45 AM Motivation for the meeting Speaker: Matthias Troyer, ETH Zurich Abstract: While a quantum computer can solve many electronic structure problems in po...
Short lecture on postulate 1 of quantum mechanics. A postulate is a statement that is not proven, but assumed to be true and judged on the validity of its conclusions. Postulate 1 of quantum mechanics states that the state of a quantum system is completely specified by the wavefunction, which is a function of both space and time. The complex conjugate of the wavefunction times itself and a small volume element is the probability of finding the particle within that volume element. In order to meet these criteria, the wavefunction must be "square integrable", giving a finite value for the integral of its square magnitude over all space. Notes Slide: http://i.imgur.com/jISFuor.png --- About TMP Chem --- All TMP Chem content is free for everyone, everywhere, and created independently by Tr...
Short lecture on the three-dimensional particle in a box. The three dimensional particle in a box has a Hamiltonian which can be factored into an independent function of the x, y, and z directions. Thus, we can use separation of variables to express the wave function as a product of three one-dimensional wavefunctions, and solve three individual Schrodinger equations for each dimension. The energy is then a sum of the energy in each dimension. Each dimension has its own quantum number (nx, ny, and nz) all of which can take on any integer value from one to infinity. Notes Slide: http://i.imgur.com/dabtQFr.png --- About TMP Chem --- All TMP Chem content is free for everyone, everywhere, and created independently by Trent Parker. If you would like to support this work, you may do so thro...
Short lecture on particle in a box wavefunctions and energies. The particle in a box is a model system for a particle which is constrained to a finite region of space. The potential energy is zero inside the box (zero to L) and infinite outside the box. We substitute this potential energy function into the Schrodinger equation and solve for the wavefunction and the energy levels of the particle in a box. Using the boundary conditions that the wavefunction must be zero at the edges of the box, we determine that the wavefunctions are a half integer of a sine wave inside the box. The energy depends quadratically on the positive quantum number n (n = 1, 2, 3), inverse with mass, and inverse quadratic with the length of the box. Notes Slide: http://i.imgur.com/ARoaMTQ.png --- About TMP Chem ...
In this episode of Crash Course Chemistry, Hank discusses what Molecules actually look like and why, some quantum-mechanical three dimensional wave functions are explored, he touches on hybridization, and delves into sigma and pi bonds. -- Table of Contents Molecules: Clumpy Globs... 0:18 Quantum-Mechanical Three-Dimensional Wave Functions 3:06 S & P Orbital Hybridization 5:27 Sigma & Pi Bonds 7:32 Hybridized Orbitals 5:52 -- Want to find Crash Course elsewhere on the internet? Facebook - http://www.facebook.com/YouTubeCrashCourse Twitter - http://www.twitter.com/TheCrashCourse Tumblr - http://thecrashcourse.tumblr.com Support CrashCourse on Subbable: http://subbable.com/crashcourse
Definition of orbital as region of high probability for finding electron, and how quantum numbers are used to describe the orbitals. Compares Bohr model orbits and quantum mechanical model of atom. Created by Jay. Watch the next lesson: https://www.khanacademy.org/science/chemistry/electronic-structure-of-atoms/orbitals-and-electrons/v/quantum-numbers-for-the-first-four-shells?utm_source=YT&utm;_medium=Desc&utm;_campaign=chemistry Missed the previous lesson? https://www.khanacademy.org/science/chemistry/electronic-structure-of-atoms/orbitals-and-electrons/v/heisenberg-uncertainty-principle?utm_source=YT&utm;_medium=Desc&utm;_campaign=chemistry Chemistry on Khan Academy: Did you know that everything is made out of chemicals? Chemistry is the study of matter: its composition, properties, and...
Like us on Facebook: https://www.facebook.com/advexondocumentary Watch our new Video -- https://www.youtube.com/watch?v=gmw4Me4uSBk The World of Quantum - Full Documentary HD 2014 http://www.advexon.com For more Scientific DOCUMENTARIES. Subscribe for more Videos... Quantum mechanics (QM -- also known as quantum physics, or quantum theory) is a branch of physics which deals with physical phenomena at nanoscopic scales where the action is on the order of the Planck constant. It departs from classical mechanics primarily at the quantum realm of atomic and subatomic length scales. Quantum mechanics provides a mathematical description of much of the dual particle-like and wave-like behavior and interactions of energy and matter. Quantum mechanics provides a substantially useful framework for...
Orbitals! Oh no. They're so weird. Don't worry, nobody understands these in first-year chemistry. You just pretend to, and then in second-year you learn them a little better, the following year a little better, and once you have a PhD you will know what they are. But let Professor Dave give you a head start! Subscribe: http://bit.ly/ProfDaveSubscribe ProfessorDaveExplains@gmail.com http://professordaveexplains.com http://facebook.com/ProfessorDaveExpl... http://twitter.com/DaveExplains General Chemistry - Online Tutorials: http://bit.ly/ProfDaveGenChem Organic Chemistry - Online Tutorials: http://bit.ly/ProfDaveOrgChem Science for Common Folk - Online Tutorials: http://bit.ly/ProfDaveScience4CommonFolk
IBM Q systems will be designed to tackle problems in business and science that are too complex and exponential in nature for classical computing systems to handle. One of the first and most promising applications will be in the area of chemistry. Even for simple molecules like caffeine, the number of quantum states in the molecule can be astoundingly large -- so large that all the conventional computing memory and processing power that could ever be built could not model it. Jerry Chow, manager of experimental quantum computing for IBM Research, explains that modeling a molecule is the key to understanding its properties -- and could lead to the discovery of new materials and medicines. For more about IBMQ: https://ibm.com/ibmq
How quantum chemistry can be used to improve our understanding of chemical reactions, via the example of oxygen binding to iron in haemoglobin in our lungs.
9:00 – 9:15 AM Welcome and Introduction Speaker: Michael Freedman, Microsoft Station Q Bio: Michael Freedman is Director of Station Q, Microsoft’s Project on quantum physics and quantum computation located on the UCSB campus. The project is a collaborative effort between Microsoft and academia directed towards exploring the mathematical theory and physical foundations for quantum computing. 9:15 – 9:30 AM Quantum Computing: A Short Tutorial Speaker: Krysta Svore, Microsoft Research QuArC Bio: Krysta Svore is a Researcher in the Quantum Architectures and Computation Group (QuArC) at Microsoft Research in Redmond, WA. 9:30 – 9:45 AM Motivation for the meeting Speaker: Matthias Troyer, ETH Zurich Abstract: While a quantum computer can solve many electronic structure problems in po...
Short lecture on postulate 1 of quantum mechanics. A postulate is a statement that is not proven, but assumed to be true and judged on the validity of its conclusions. Postulate 1 of quantum mechanics states that the state of a quantum system is completely specified by the wavefunction, which is a function of both space and time. The complex conjugate of the wavefunction times itself and a small volume element is the probability of finding the particle within that volume element. In order to meet these criteria, the wavefunction must be "square integrable", giving a finite value for the integral of its square magnitude over all space. Notes Slide: http://i.imgur.com/jISFuor.png --- About TMP Chem --- All TMP Chem content is free for everyone, everywhere, and created independently by Tr...
Short lecture on the three-dimensional particle in a box. The three dimensional particle in a box has a Hamiltonian which can be factored into an independent function of the x, y, and z directions. Thus, we can use separation of variables to express the wave function as a product of three one-dimensional wavefunctions, and solve three individual Schrodinger equations for each dimension. The energy is then a sum of the energy in each dimension. Each dimension has its own quantum number (nx, ny, and nz) all of which can take on any integer value from one to infinity. Notes Slide: http://i.imgur.com/dabtQFr.png --- About TMP Chem --- All TMP Chem content is free for everyone, everywhere, and created independently by Trent Parker. If you would like to support this work, you may do so thro...
Short lecture on particle in a box wavefunctions and energies. The particle in a box is a model system for a particle which is constrained to a finite region of space. The potential energy is zero inside the box (zero to L) and infinite outside the box. We substitute this potential energy function into the Schrodinger equation and solve for the wavefunction and the energy levels of the particle in a box. Using the boundary conditions that the wavefunction must be zero at the edges of the box, we determine that the wavefunctions are a half integer of a sine wave inside the box. The energy depends quadratically on the positive quantum number n (n = 1, 2, 3), inverse with mass, and inverse quadratic with the length of the box. Notes Slide: http://i.imgur.com/ARoaMTQ.png --- About TMP Chem ...