- published: 30 Sep 2014
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The phlogiston theory (from the Ancient Greek φλογιστόν phlogistón "burning up", from φλόξ phlóx "flame"), first stated in 1667 by Johann Joachim Becher, is an obsolete scientific theory that postulated the existence of a fire-like element called "phlogiston", which was contained within combustible bodies and released during combustion. The theory was an attempt to explain processes of burning such as combustion and the rusting of metals, which are now collectively known as oxidation.
"Phlogisticated" substances are those that contain phlogiston and are "dephlogisticated" when burned; "in general, substances that burned in air were said to be rich in phlogiston; the fact that combustion soon ceased in an enclosed space was taken as clear-cut evidence that air had the capacity to absorb only a definite amount of phlogiston. When air had become completely phlogisticated it would no longer serve to support combustion of any material, nor would a metal heated in it yield a calx; nor could phlogisticated air support life, for the role of air in respiration was to remove the phlogiston from the body."
Joseph Priestley, FRS (13 March 1733 (O.S.) – 6 February 1804) was an 18th-century English theologian, Dissenting clergyman, natural philosopher, chemist, educator, and political theorist who published over 150 works. He is usually credited with the discovery of oxygen, having isolated it in its gaseous state, although Carl Wilhelm Scheele and Antoine Lavoisier also have a claim to the discovery.
During his lifetime, Priestley's considerable scientific reputation rested on his invention of soda water, his writings on electricity, and his discovery of several "airs" (gases), the most famous being what Priestley dubbed "dephlogisticated air" (oxygen). However, Priestley's determination to defend phlogiston theory and to reject what would become the chemical revolution eventually left him isolated within the scientific community.
Priestley's science was integral to his theology, and he consistently tried to fuse Enlightenment rationalism with Christian theism. In his metaphysical texts, Priestley attempted to combine theism, materialism, and determinism, a project that has been called "audacious and original". He believed that a proper understanding of the natural world would promote human progress and eventually bring about the Christian Millennium. Priestley, who strongly believed in the free and open exchange of ideas, advocated toleration and equal rights for religious Dissenters, which also led him to help found Unitarianism in England. The controversial nature of Priestley's publications combined with his outspoken support of the French Revolution aroused public and governmental suspicion; he was eventually forced to flee, in 1791, first to London, and then to the United States, after a mob burned down his home and church. He spent the last ten years of his life living in Northumberland County, Pennsylvania.
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