The Great Rift Valley is a name given in the late 19th century by British explorer John Walter Gregory to the continuous geographic trench, approximately 6,000 kilometres (3,700 mi) in length, that runs from northern Syria in Southwest Asia to central Mozambique in South East Africa. The name continues in some usages, although it is today considered geologically imprecise as it combines features that are today regarded as separate, although related, rift and fault systems. Today, the term is most often used to refer to the valley of the East African Rift, the divergent plate boundary which extends from the Afar Triple Junction southward across eastern Africa, and is in the process of splitting the African Plate into two new separate plates. Geologists generally refer to these incipient plates as the Nubian Plate and the Somali Plate.

The Great Rift Valley as originally described was thought to extend from Lebanon in the north to Mozambique in the south, and constitutes one of two distinct physiographic provinces of the East African mountains. It included the Jordan Rift Valley, Red Sea Rift and the East African Rift. Today these rifts and faults are seen as distinct, although connected.

A rift valley is a linear-shaped lowland between highlands or mountain ranges created by the action of a geologic rift or fault. This action is manifest as crustal extension, a spreading apart of the surface which is subsequently further deepened by the forces of erosion. When the tensional forces are strong enough to cause the plate to split apart it will do so such that a center block will drop down relative to its flanking blocks, forming a graben. This creates the nearly parallel steeply dipping walls. This feature is the beginning of the rift valley. As this process continues, the valley gets wider and wider until it becomes a large basin that fills with sediment from the rift walls and the surrounding area. One of the better long term examples of this process is the Basin and Range province in Nevada and Utah. Rifts can occur at all elevations, from the sea floor to plateaus and mountain ranges. They can occur in continental crust or in oceanic crust. Rift valleys are often associated with a number of adjoining subsidiary or co-extensive valleys which are typically considered geologically part of the principal rift valley.