Brookville may refer to any of the following:

James Monroe (April 28, 1758 – July 4, 1831) was the fifth President of the United States (1817–1825). Monroe was the last president who was a Founding Father of the United States, and the last president from the Virginia dynasty and the Republican Generation. His presidency was marked both by an "Era of Good Feelings" – a period of relatively little partisan strife – and later by the Panic of 1819 and a fierce national debate over the admission of the Missouri Territory. Monroe is most noted for his proclamation of the Monroe Doctrine in 1823, which stated that the United States would not tolerate further European intervention in the Americas.

Born in Westmoreland County, Virginia, Monroe fought in the American Revolutionary War. He was injured in the Battle of Trenton with a musket ball to his shoulder. After studying law under Thomas Jefferson from 1780 to 1783, he served as a delegate in the Continental Congress. As an anti-federalist delegate to the Virginia convention that considered ratification of the United States Constitution, Monroe opposed ratification, claiming it gave too much power to the central government. Nonetheless, Monroe took an active part in the new government and in 1790 he was elected to the Senate of the first United States Congress, where he joined the Jeffersonians. He gained experience as an executive as the Governor of Virginia and rose to national prominence when as a diplomat in France he helped negotiate the Louisiana Purchase in 1803. Monroe was of French and Scottish descent.