Energy

is the electric breakdown of air by strong electric fields and is a flow of energy. The electric potential energy in the atmosphere changes into thermal kinetic energy, light, and sound, which are other forms of energy.]]

In physics, energy (from Greek - energeia, "activity, operation", from - energos, "active, working") is a quantity that is often understood as the ability to perform work. This quantity can be assigned to any particle, object, or system of objects as a consequence of its physical state.

Different forms of energy include kinetic, potential, thermal, gravitational, sound, elastic and electromagnetic energy. The forms of energy are often named after a related force. German physicist Hermann von Helmholtz established that all forms of energy are equivalentenergy in one form can disappear but the same amount of energy will appear in another form. A restatement of this idea is that energy is subject to a conservation law over time.

Any form of energy can be transformed into another form. When energy is in a form other than thermal energy, it may be transformed with good or even perfect efficiency, to any other type of energy. With thermal energy, however, there are often limits to the efficiency of the conversion to other forms of energy, due to the second law of thermodynamics. As an example, when oil reacts with oxygen, potential energy is released, since new chemical bonds are formed in the products which are more stable than those in the oil and oxygen. The released energy resulting from this process may be converted directly to electricity (as in a fuel cell) with good efficiency. Alternately it may be converted into thermal energy if the oil is simply burned. In the latter case, however, some of the thermal energy can no longer be used to perform work at that temperature, and is said to be "degraded." As such, it exists in a form unavailable for further transformation. The remainder of the thermal energy may be used to produce any other type of energy, such as electricity.

In all such energy transformation processes, the total energy remains the same. Energy may not be created nor destroyed. This principle, the conservation of energy, was first postulated in the early 19th century, and applies to any isolated system. According to Noether's theorem, the conservation of energy is a consequence of the fact that the laws of physics do not change over time.

Although the total energy of a system does not change with time, its value may depend on the frame of reference. For example, a seated passenger in a moving airplane has zero kinetic energy relative to the airplane, but non-zero kinetic energy (and higher total energy) relative to the Earth.

Energy is a scalar physical quantity. In the International System of Units (SI), energy is measured in joules, but in some fields other units such as kilowatt-hours and kilocalories are also used.

History

The word energy derives from Greek ἐνέργεια (energeia), which possibly appears for the first time in the work Nicomachean Ethics of Aristotle in the 4th century BC.

The concept of energy emerged out of the idea of vis viva, which Leibniz defined as the product of the mass of an object and its velocity squared; he believed that total vis viva was conserved. To account for slowing due to friction, Leibniz theorized that thermal energy consisted of the random motion of the constituent parts of matter, a view shared by Isaac Newton, although it would be more than a century until this was generally accepted. In 1807, Thomas Young was possibly the first to use the term "energy" instead of vis viva, in its modern sense. Gustave-Gaspard Coriolis described "kinetic energy" in 1829 in its modern sense, and in 1853, William Rankine coined the term "potential energy". It was argued for some years whether energy was a substance (the caloric) or merely a physical quantity, such as momentum.

William Thomson (Lord Kelvin) amalgamated all of these laws into the laws of thermodynamics, which aided in the rapid development of explanations of chemical processes using the concept of energy by Rudolf Clausius, Josiah Willard Gibbs, and Walther Nernst. It also led to a mathematical formulation of the concept of entropy by Clausius and to the introduction of laws of radiant energy by Jožef Stefan.

During a 1961 lecture The human equivalent assists understanding of energy flows in physical and biological systems by expressing energy units in human terms: it provides a “feel” for the use of a given amount of energy In geology, continental drift, mountain ranges, volcanoes, and earthquakes are phenomena that can be explained in terms of energy transformations in the Earth's interior., while meteorological phenomena like wind, rain, hail, snow, lightning, tornadoes and hurricanes, are all a result of energy transformations brought about by solar energy on the atmosphere of the planet Earth.

In cosmology and astronomy the phenomena of stars, nova, supernova, quasars and gamma ray bursts are the universe's highest-output energy transformations of matter. All phenomena (including solar activity) are driven by various kinds of energy transformations. Energy in such transformations is either from gravitational collapse of matter (usually molecular hydrogen) into various classes of astronomical objects (stars, black holes, etc.), or from nuclear fusion (of lighter elements, primarily hydrogen).

Energy transformations in the universe over time are characterized by various kinds of potential energy that has been available since the Big Bang, later being "released" (transformed to more active types of energy such as kinetic or radiant energy), when a triggering mechanism is available.

Familiar examples of such processes include nuclear decay, in which energy is released that was originally "stored" in heavy isotopes (such as uranium and thorium), by nucleosynthesis, a process ultimately using the gravitational potential energy released from the gravitational collapse of supernovae, to store energy in the creation of these heavy elements before they were incorporated into the solar system and the Earth. This energy is triggered and released in nuclear fission bombs. In a slower process, radioactive decay of these atoms in the core of the Earth releases heat. This thermal energy drives plate tectonics and may lift mountains, via orogenesis. This slow lifting represents a kind of gravitational potential energy storage of the thermal energy, which may be later released to active kinetic energy in landslides, after a triggering event. Earthquakes also release stored elastic potential energy in rocks, a store that has been produced ultimately from the same radioactive heat sources. Thus, according to present understanding, familiar events such as landslides and earthquakes release energy that has been stored as potential energy in the Earth's gravitational field or elastic strain (mechanical potential energy) in rocks. Prior to this, they represent release of energy that has been stored in heavy atoms since the collapse of long-destroyed supernova stars created these atoms.

In another similar chain of transformations beginning at the dawn of the universe, nuclear fusion of hydrogen in the Sun also releases another store of potential energy which was created at the time of the Big Bang. At that time, according to theory, space expanded and the universe cooled too rapidly for hydrogen to completely fuse into heavier elements. This meant that hydrogen represents a store of potential energy that can be released by fusion. Such a fusion process is triggered by heat and pressure generated from gravitational collapse of hydrogen clouds when they produce stars, and some of the fusion energy is then transformed into sunlight. Such sunlight from our Sun may again be stored as gravitational potential energy after it strikes the Earth, as (for example) water evaporates from oceans and is deposited upon mountains (where, after being released at a hydroelectric dam, it can be used to drive turbines or generators to produce electricity). Sunlight also drives many weather phenomena, save those generated by volcanic events. An example of a solar-mediated weather event is a hurricane, which occurs when large unstable areas of warm ocean, heated over months, give up some of their thermal energy suddenly to power a few days of violent air movement. Sunlight is also captured by plants as chemical potential energy in photosynthesis, when carbon dioxide and water (two low-energy compounds) are converted into the high-energy compounds carbohydrates, lipids, and proteins. Plants also release oxygen during photosynthesis, which is utilized by living organisms as an electron acceptor, to release the energy of carbohydrates, lipids, and proteins. Release of the energy stored during photosynthesis as heat or light may be triggered suddenly by a spark, in a forest fire, or it may be made available more slowly for animal or human metabolism, when these molecules are ingested, and catabolism is triggered by enzyme action.

Through all of these transformation chains, potential energy stored at the time of the Big Bang is later released by intermediate events, sometimes being stored in a number of ways over time between releases, as more active energy. In all these events, one kind of energy is converted to other types of energy, including heat.

Conservation of energy

Energy is subject to the law of conservation of energy. According to this law, energy can neither be created (produced) nor destroyed by itself. It can only be transformed.

Most kinds of energy (with gravitational energy being a notable exception) are also subject to strict local conservation laws, as well. In this case, energy can only be exchanged between adjacent regions of space, and all observers agree as to the volumetric density of energy in any given space. There is also a global law of conservation of energy, stating that the total energy of the universe cannot change; this is a corollary of the local law, but not vice versa. Conservation of energy is the mathematical consequence of translational symmetry of time (that is, the indistinguishability of time intervals taken at different time) - see Noether's theorem.

According to energy conservation law the total inflow of energy into a system must equal the total outflow of energy from the system, plus the change in the energy contained within the system.

This law is a fundamental principle of physics. It follows from the translational symmetry of time, a property of most phenomena below the cosmic scale that makes them independent of their locations on the time coordinate. Put differently, yesterday, today, and tomorrow are physically indistinguishable.

This is because energy is the quantity which is canonical conjugate to time. This mathematical entanglement of energy and time also results in the uncertainty principle - it is impossible to define the exact amount of energy during any definite time interval. The uncertainty principle should not be confused with energy conservation - rather it provides mathematical limits to which energy can in principle be defined and measured.

In quantum mechanics energy is expressed using the Hamiltonian operator. On any time scales, the uncertainty in the energy is by

: $\backslash Delta\; E\; \backslash Delta\; t\; \backslash ge\; \backslash frac\; \{\; \backslash hbar\; \}\; \{2\; \}$

which is similar in form to the Heisenberg uncertainty principle (but not really mathematically equivalent thereto, since H and t are not dynamically conjugate variables, neither in classical nor in quantum mechanics).

In particle physics, this inequality permits a qualitative understanding of virtual particles which carry momentum, exchange by which and with real particles, is responsible for the creation of all known fundamental forces (more accurately known as fundamental interactions). Virtual photons (which are simply lowest quantum mechanical energy state of photons) are also responsible for electrostatic interaction between electric charges (which results in Coulomb law), for spontaneous radiative decay of exited atomic and nuclear states, for the Casimir force, for van der Waals bond forces and some other observable phenomena.

Applications of the concept of energy

Energy is subject to a strict global conservation law; that is, whenever one measures (or calculates) the total energy of a system of particles whose interactions do not depend explicitly on time, it is found that the total energy of the system always remains constant.

The total energy of a system can be subdivided and classified in various ways. For example, it is sometimes convenient to distinguish potential energy (which is a function of coordinates only) from kinetic energy (which is a function of coordinate time derivatives only). It may also be convenient to distinguish gravitational energy, electric energy, thermal energy, and other forms. These classifications overlap; for instance, thermal energy usually consists partly of kinetic and partly of potential energy.

The transfer of energy can take various forms; familiar examples include work, heat flow, and advection, as discussed below.

The word "energy" is also used outside of physics in many ways, which can lead to ambiguity and inconsistency. The vernacular terminology is not consistent with technical terminology. For example, while energy is always conserved (in the sense that the total energy does not change despite energy transformations), energy can be converted into a form, e.g., thermal energy, that cannot be utilized to perform work. When one talks about "conserving energy by driving less," one talks about conserving fossil fuels and preventing useful energy from being lost as heat. This usage of "conserve" differs from that of the law of conservation of energy. In other words, energy is invariant with respect to rotations of space, but not invariant with respect to rotations of space-time (= boosts).

Energy transfer

Because energy is strictly conserved and is also locally conserved (wherever it can be defined), it is important to remember that by the definition of energy the transfer of energy between the "system" and adjacent regions is work. A familiar example is mechanical work. In simple cases this is written as the following equation:

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if there are no other energy-transfer processes involved. Here $E$ is the amount of energy transferred, and $W$  represents the work done on the system.

More generally, the energy transfer can be split into two categories:

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where $Q$ represents the heat flow into the system.

There are other ways in which an open system can gain or lose energy. In chemical systems, energy can be added to a system by means of adding substances with different chemical potentials, which potentials are then extracted (both of these process are illustrated by fueling an auto, a system which gains in energy thereby, without addition of either work or heat). Winding a clock would be adding energy to a mechanical system. These terms may be added to the above equation, or they can generally be subsumed into a quantity called "energy addition term $E$" which refers to any type of energy carried over the surface of a control volume or system volume. Examples may be seen above, and many others can be imagined (for example, the kinetic energy of a stream of particles entering a system, or energy from a laser beam adds to system energy, without either being either work-done or heat-added, in the classic senses).

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Where E in this general equation represents other additional advected energy terms not covered by work done on a system, or heat added to it.

Energy is also transferred from potential energy ($E\_p$) to kinetic energy ($E\_k$) and then back to potential energy constantly. This is referred to as conservation of energy. In this closed system, energy cannot be created or destroyed; therefore, the initial energy and the final energy will be equal to each other. This can be demonstrated by the following:

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The equation can then be simplified further since $E\_p\; =\; mgh$ (mass times acceleration due to gravity times the height) and $E\_k\; =\; \backslash frac\{1\}\{2\}\; mv^2$ (half mass times velocity squared). Then the total amount of energy can be found by adding $E\_p\; +\; E\_k\; =\; E\_\{total\}$.

Energy and the laws of motion

In classical mechanics, energy is a conceptually and mathematically useful property, as it is a conserved quantity. Several formulations of mechanics have been developed using energy as a core concept.

The Hamiltonian

The total energy of a system is sometimes called the Hamiltonian, after William Rowan Hamilton. The classical equations of motion can be written in terms of the Hamiltonian, even for highly complex or abstract systems. These classical equations have remarkably direct analogs in nonrelativistic quantum mechanics.

The Lagrangian

Another energy-related concept is called the Lagrangian, after Joseph Louis Lagrange. This is even more fundamental than the Hamiltonian, and can be used to derive the equations of motion. It was invented in the context of classical mechanics, but is generally useful in modern physics. The Lagrangian is defined as the kinetic energy minus the potential energy.

Usually, the Lagrange formalism is mathematically more convenient than the Hamiltonian for non-conservative systems (such as systems with friction).

Energy and thermodynamics

Internal energy

Internal energy is the sum of all microscopic forms of energy of a system. It is the energy needed to create the system. It is related to the potential energy, e.g., molecular structure, crystal structure, and other geometric aspects, as well as the motion of the particles, in form of kinetic energy. Thermodynamics is chiefly concerned with changes in internal energy and not its absolute value, which is impossible to determine with thermodynamics alone.

The laws of thermodynamics

According to the second law of thermodynamics, work can be totally converted into heat, but not vice versa. This is a mathematical consequence of statistical mechanics. The first law of thermodynamics simply asserts that energy is conserved, and that heat is included as a form of energy transfer. A commonly used corollary of the first law is that for a "system" subject only to pressure forces and heat transfer (e.g., a cylinder-full of gas), the differential change in energy of the system (with a gain in energy signified by a positive quantity) is given as the following equation:

:$\backslash mathrm\{d\}E\; =\; T\backslash mathrm\{d\}S\; -\; P\backslash mathrm\{d\}V\backslash ,$,

where the first term on the right is the heat transfer into the system, defined in terms of temperature T and entropy S (in which entropy increases and the change dS is positive when the system is heated), and the last term on the right hand side is identified as "work" done on the system, where pressure is P and volume V (the negative sign results since compression of the system requires work to be done on it and so the volume change, dV, is negative when work is done on the system). Although this equation is the standard textbook example of energy conservation in classical thermodynamics, it is highly specific, ignoring all chemical, electric, nuclear, and gravitational forces, effects such as advection of any form of energy other than heat, and because it contains a term that depends on temperature. The most general statement of the first law (i.e., conservation of energy) is valid even in situations in which temperature is undefinable.

Energy is sometimes expressed as the following equation:

:$\backslash mathrm\{d\}E=\backslash delta\; Q+\backslash delta\; W\backslash ,$,

which is unsatisfactory :gain in kinetic energy of a sprinter during a 100 m race: 4 kJ :gain in gravitational potential energy of a 150 kg weight lifted through 2 metres: 3kJ :Daily food intake of a normal adult: 6–8 MJ

It would appear that living organisms are remarkably inefficient (in the physical sense) in their use of the energy they receive (chemical energy or radiation), and it is true that most real machines manage higher efficiencies. In growing organisms the energy that is converted to heat serves a vital purpose, as it allows the organism tissue to be highly ordered with regard to the molecules it is built from. The second law of thermodynamics states that energy (and matter) tends to become more evenly spread out across the universe: to concentrate energy (or matter) in one specific place, it is necessary to spread out a greater amount of energy (as heat) across the remainder of the universe ("the surroundings"). Simpler organisms can achieve higher energy efficiencies than more complex ones, but the complex organisms can occupy ecological niches that are not available to their simpler brethren. The conversion of a portion of the chemical energy to heat at each step in a metabolic pathway is the physical reason behind the pyramid of biomass observed in ecology: to take just the first step in the food chain, of the estimated 124.7 Pg/a of carbon that is fixed by photosynthesis, 64.3 Pg/a (52%) are used for the metabolism of green plants, i.e. reconverted into carbon dioxide and heat.

Measurement

- An instrument used by physicists to measure energy]] Because energy is defined as the ability to do work on objects, there is no absolute measure of energy. Only the transition of a system from one state into another can be defined and thus energy is measured in relative terms. The choice of a baseline or zero point is often arbitrary and can be made in whatever way is most convenient for a problem.

Methods

The methods for the measurement of energy often deploy methods for the measurement of still more fundamental concepts of science, namely mass, distance, radiation, temperature, time, electric charge and electric current.

Conventionally the technique most often employed is calorimetry, a thermodynamic technique that relies on the measurement of temperature using a thermometer or of intensity of radiation using a bolometer.

Units

Throughout the history of science, energy has been expressed in several different units such as ergs and calories. At present, the accepted unit of measurement for energy is the SI unit of energy, the joule. In addition to the joule, other units of energy include the kilowatt hour (kWh) and the British thermal unit (Btu). These are both larger units of energy. One kWh is equivalent to exactly 3.6 million joules, and one Btu is equivalent to about 1055 joules.

Energy density

Energy density is a term used for the amount of useful energy stored in a given system or region of space per unit volume.

For fuels, the energy per unit volume is sometimes a useful parameter. In a few applications, comparing, for example, the effectiveness of hydrogen fuel to gasoline it turns out that hydrogen has a higher specific energy than does gasoline, but, even in liquid form, a much lower energy density.

Forms of energy

, a form of energy, is partly potential energy and partly kinetic energy.]] In the context of physical sciences, several forms of energy have been defined. These include: {| |

Thermal energy, thermal energy in transit is called heat

Chemical energy

Electrical energy

Radiant energy, the energy of electromagnetic radiation

Nuclear energy

|

Magnetic energy

Elastic energy

Sound Energy

Mechanical energy

| |}

These energies may be divided into two main groups; kinetic energy and potential energy. Other familiar types of energy are a varying mix of both potential and kinetic energy. Energy may be transformed between these forms.

However, the above set of the possible forms of energy is not a closed set. Whenever physical scientists discover that certain phenomenon appears to violate the law of energy conservation, new forms may be added, as is the case with dark energy. Classical mechanics distinguishes between potential energy, which is a function of the position of an object, and kinetic energy, which is a function of its movement. Both position and movement are relative to a frame of reference, which must be specified: this is often (and originally) an arbitrary fixed point on the surface of the Earth, the terrestrial frame of reference. It has been attempted to categorize all forms of energy as either kinetic or potential: this is not incorrect, but neither is it clear that it is a real simplification, as Feynman points out:

{| class="wikitable" align=right width=150px |- |+ Examples of the interconversion of energy |- ! colspan=2 | Mechanical energy is converted |- ! into ! by |- | Mechanical energy | Lever |- | Thermal energy | Brakes |- | Electric energy | Dynamo |- | Electromagnetic radiation | Synchrotron |- | Chemical energy | Matches |- | Nuclear energy | Particle accelerator |- |}

Mechanical energy

Mechanical energy manifest in many forms,but can be broadly classified into elastic potential energy and kinetic energy. The term potential energy is a very general term, because it exists in all force fields, such as gravitation, electrostatic and magnetic fields. Potential energy refers to the energy any object gets due to its position in a force field. Potential energy, symbols E_p, V or Φ, is defined as the work done against a given force (= work of given force with minus sign) in changing the position of an object with respect to a reference position (often taken to be infinite separation). If F is the force and s is the displacement, ::$E\_\{\backslash rm\; p\}\; =\; -\backslash int\; \backslash mathbf\{F\}\backslash cdot\{\backslash rm\; d\}\backslash mathbf\{s\}$ with the dot representing the scalar product of the two vectors.

The name "potential" energy originally signified the idea that the energy could readily be transferred as work—at least in an idealized system (reversible process, see below). This is not completely true for any real system, but is often a reasonable first approximation in classical mechanics.

The general equation above can be simplified in a number of common cases, notably when dealing with gravity or with elastic forces.

Elastic potential energy

, it accelerates downward, its initial potential energy converting into kinetic energy. On impact with a hard surface the ball deforms, converting the kinetic energy into elastic potential energy. As the ball springs back, the energy converts back firstly to kinetic energy and then as the ball re-gains height into potential energy. Energy conversion to heat due to inelastic deformation and air resistance cause each successive bounce to be lower than the last.]] Elastic potential energy is defined as a work needed to compress (or expand) a spring. The force, F, in a spring or any other system which obeys Hooke's law is proportional to the extension or compression, x, ::$F\; =\; -kx$ where k is the force constant of the particular spring (or system). In this case, the calculated work becomes ::$E\_\{\backslash rm\; p,e\}\; =\; \{1\backslash over\; 2\}kx^2$ only when k is constant. Hooke's law is a good approximation for behaviour of chemical bonds under normal conditions, i.e. when they are not being broken or formed.

Kinetic energy

Kinetic energy, symbols E_k, T or K, is the work required to accelerate an object to a given speed. Indeed, calculating this work one easily obtains the following:

::$E\_\{\backslash rm\; k\}\; =\; \backslash int\; \backslash mathbf\{F\}\; \backslash cdot\; d\; \backslash mathbf\{x\}\; =\; \backslash int\; \backslash mathbf\{v\}\; \backslash cdot\; d\; \backslash mathbf\{p\}=\; \{1\backslash over\; 2\}mv^2$ At speeds approaching the speed of light, c, this work must be calculated using Lorentz transformations, which results in the following:

::$E\_\{\backslash rm\; k\}\; =\; m\; c^2\backslash left(\backslash frac\{1\}\{\backslash sqrt\{1\; -\; (v/c)^2\}\}\; -\; 1\backslash right)$

Here the two terms on the right hand side are identified with the total energy and the rest energy of the object, respectively. This equation reduces to the one above it, at small (compared to c) speed. The kinetic energy is zero at v=0, so that at rest, the total energy is the rest energy. Thus, a resting mass has the amount of total energy equal to:

::$E\_\{\backslash rm\; rest\}\; =\; mc^2$

This energy is thus called rest mass energy.

Surface energy

If there is any kind of tension in a surface, such as a stretched sheet of rubber or material interfaces, it is possible to define surface energy. In particular, any meeting of dissimilar materials that don't mix will result in some kind of surface tension, if there is freedom for the surfaces to move then, as seen in capillary surfaces for example, the minimum energy will as usual be sought.

A minimal surface, for example, represents the smallest possible energy that a surface can have if its energy is proportional to the area of the surface. For this reason, (open) soap films of small size are minimal surfaces (small size reduces gravity effects, and openness prevents pressure from building up. Note that a bubble is a minimum energy surface but not a minimal surface by definition).

Sound energy

Sound is a form of mechanical vibration, which propagates through any mechanical medium.

Gravitational energy

The gravitational force near the Earth's surface varies very little with the height, h, and is equal to the mass, m, multiplied by the gravitational acceleration, g = 9.81 m/s². In these cases, the gravitational potential energy is given by ::$E\_\{\backslash rm\; p,g\}\; =\; mgh$

A more general expression for the potential energy due to Newtonian gravitation between two bodies of masses m₁ and m₂, useful in astronomy, is ::$E\_\{\backslash rm\; p,g\}\; =\; -G$, where r is the separation between the two bodies and G is the gravitational constant, 6.6742(10)×10⁻¹¹ m³kg⁻¹s⁻². In this case, the reference point is the infinite separation of the two bodies.

Thermal energy

{| class="wikitable" align=right width=150px |- |+ Examples of the interconversion of energy |- ! colspan=2 | Thermal energy is converted |- ! into ! by |- | Mechanical energy | Steam turbine |- | Thermal energy | Heat exchanger |- | Electric energy | Thermocouple |- | Electromagnetic radiation | Hot objects |- | Chemical energy | Blast furnace |- | Nuclear energy | Supernova |- |}

Thermal energy (of some media - gas, plasma, solid, etc.) is the energy associated with the microscopical random motion of particles constituting the media. For example, in case of monoatomic gas it is just a kinetic energy of motion of atoms of gas as measured in the reference frame of the center of mass of gas. In case of molecules in the gas rotational and vibrational energy is involved. In the case of liquids and solids there is also potential energy (of interaction of atoms) involved, and so on.

A heat is defined as a transfer (flow) of thermal energy across certain boundary (for example, from a hot body to cold via the area of their contact. A practical definition for small transfers of heat is ::$\backslash Delta\; q\; =\; \backslash int\; C\_\{\backslash rm\; v\}\{\backslash rm\; d\}T$ where C_v is the heat capacity of the system. This definition will fail if the system undergoes a phase transition—e.g. if ice is melting to water—as in these cases the system can absorb heat without increasing its temperature. In more complex systems, it is preferable to use the concept of internal energy rather than that of thermal energy (see Chemical energy below).

Despite the theoretical problems, the above definition is useful in the experimental measurement of energy changes. In a wide variety of situations, it is possible to use the energy released by a system to raise the temperature of another object, e.g. a bath of water. It is also possible to measure the amount of electric energy required to raise the temperature of the object by the same amount. The calorie was originally defined as the amount of energy required to raise the temperature of one gram of water by 1 °C (approximately 4.1855 J, although the definition later changed), and the British thermal unit was defined as the energy required to heat one pound of water by 1 °F (later fixed as 1055.06 J).

Electric energy

{| class="wikitable" align=right width=150px |- |+ Examples of the interconversion of energy |- ! colspan=2 | Electric energy is converted |- ! into ! by |- | Mechanical energy | Electric motor |- | Thermal energy | Resistor |- | Electric energy | Transformer |- | Electromagnetic radiation | Light-emitting diode |- | Chemical energy | Electrolysis |- | Nuclear energy | Synchrotron |- |}

Electrostatic energy

The electric potential energy of given configuration of charges is defined as the work which must be done against the Coulomb force to rearrange charges from infinite separation to this configuration (or the work done by the Coulomb force separating the charges from this configuration to infinity). For two point-like charges Q₁ and Q₂ at a distance r this work, and hence electric potential energy is equal to: ::$E\_\{\backslash rm\; p,e\}\; =\; \{1\backslash over\; \{4\backslash pi\backslash epsilon\_0\}\}$ where ε₀ is the electric constant of a vacuum, 10⁷/4πc₀² or 8.854188…×10⁻¹² F/m. If the charge is accumulated in a capacitor (of capacitance C), the reference configuration is usually selected not to be infinite separation of charges, but vice versa - charges at an extremely close proximity to each other (so there is zero net charge on each plate of a capacitor). The justification for this choice is purely practical - it is easier to measure both voltage difference and magnitude of charges on a capacitor plates not versus infinite separation of charges but rather versus discharged capacitor where charges return to close proximity to each other (electrons and ions recombine making the plates neutral). In this case the work and thus the electric potential energy becomes ::$E\_\{\backslash rm\; p,e\}\; =$

Electricity energy

If an electric current passes through a resistor, electric energy is converted to heat; if the current passes through an electric appliance, some of the electric energy will be converted into other forms of energy (although some will always be lost as heat). The amount of electric energy due to an electric current can be expressed in a number of different ways: ::$E\; =\; UQ\; =\; UIt\; =\; Pt\; ==\; \{I^2\}Rt$ where U is the electric potential difference (in volts), Q is the charge (in coulombs), I is the current (in amperes), t is the time for which the current flows (in seconds), P is the power (in watts) and R is the electric resistance (in ohms). The last of these expressions is important in the practical measurement of energy, as potential difference, resistance and time can all be measured with considerable accuracy.

Magnetic energy

There is no fundamental difference between magnetic energy and electric energy: the two phenomena are related by Maxwell's equations. The potential energy of a magnet of magnetic moment m in a magnetic field B is defined as the work of magnetic force (actually of magnetic torque) on re-alignment of the vector of the magnetic dipole moment, and is equal: ::$E\_\{\backslash rm\; p,m\}\; =\; -m\backslash cdot\; B$ while the energy stored in an inductor (of inductance L) when current I is passing via it is

::$E\_\{\backslash rm\; p,m\}\; =\; \{1\backslash over\; 2\}LI^2$. This second expression forms the basis for superconducting magnetic energy storage.

Electromagnetic Energy

{| class="wikitable" align=right width=150px |- |+ Examples of the interconversion of energy |- ! colspan=2 | Electromagnetic radiation is converted |- ! into ! by |- | Mechanical energy | Solar sail |- | Thermal energy | Solar collector |- | Electric energy | Solar cell |- | Electromagnetic radiation | Non-linear optics |- | Chemical energy | Photosynthesis |- | Nuclear energy | Mössbauer spectroscopy |- |}

Calculating work needed to create an electric or magnetic field in unit volume (say, in a capacitor or an inductor) results in the electric and magnetic fields energy densities:

::$u\_e=\backslash frac\{\backslash epsilon\_0\}\{2\}\; E^2$ and ::$u\_m=\backslash frac\{1\}\{2\backslash mu\_0\}\; B^2$, in SI units.

Electromagnetic radiation, such as microwaves, visible light or gamma rays, represents a flow of electromagnetic energy. Applying the above expressions to magnetic and electric components of electromagnetic field both the volumetric density and the flow of energy in e/m field can be calculated. The resulting Poynting vector, which is expressed as ::$\backslash mathbf\{S\}\; =\; \backslash frac\{1\}\{\backslash mu\}\; \backslash mathbf\{E\}\; \backslash times\; \backslash mathbf\{B\},$ in SI units, gives the density of the flow of energy and its direction.

The energy of electromagnetic radiation is quantized (has discrete energy levels). The spacing between these levels is equal to

::$E\; =\; h\backslash nu$

where h is the Planck constant, 6.6260693(11)×10⁻³⁴ Js, and ν is the frequency of the radiation. This quantity of electromagnetic energy is usually called a photon. The photons which make up visible light have energies of 270–520 yJ, equivalent to 160–310 kJ/mol, the strength of weaker chemical bonds.

Chemical energy

{| class="wikitable" align=right width=150px |- |+ Examples of the interconversion of energy |- ! colspan=2 | Chemical energy is converted |- ! into ! by |- | Mechanical energy | Muscle |- | Thermal energy | Fire |- | Electric energy | Fuel cell |- | Electromagnetic radiation | Glowworms |- | Chemical energy | Chemical reaction |- |}

Chemical energy is the energy due to associations of atoms in molecules and various other kinds of aggregates of matter. It may be defined as a work done by electric forces during re-arrangement of mutual positions of electric charges, electrons and protons, in the process of aggregation. So, basically it is electrostatic potential energy of electric charges. If the chemical energy of a system decreases during a chemical reaction, the difference is transferred to the surroundings in some form (often heat or light); on the other hand if the chemical energy of a system increases as a result of a chemical reaction - the difference then is supplied by the surroundings (usually again in form of heat or light). For example, :when two hydrogen atoms react to form a dihydrogen molecule, the chemical energy decreases by 724 zJ (the bond energy of the H–H bond); :when the electron is completely removed from a hydrogen atom, forming a hydrogen ion (in the gas phase), the chemical energy increases by 2.18 aJ (the ionization energy of hydrogen). It is common to quote the changes in chemical energy for one mole of the substance in question: typical values for the change in molar chemical energy during a chemical reaction range from tens to hundreds of kilojoules per mole.

The chemical energy as defined above is also referred to by chemists as the internal energy, U: technically, this is measured by keeping the volume of the system constant. Most practical chemistry is performed at constant pressure and, if the volume changes during the reaction (e.g. a gas is given off), a correction must be applied to take account of the work done by or on the atmosphere to obtain the enthalpy, H: ::ΔH = ΔU + PΔV A second correction, for the change in entropy, S, must also be performed to determine whether a chemical reaction will take place or not, giving the Gibbs free energy, G: ::ΔG = ΔH − TΔS These corrections are sometimes negligible, but often not (especially in reactions involving gases).

Since the industrial revolution, the burning of coal, oil, natural gas or products derived from them has been a socially significant transformation of chemical energy into other forms of energy. the energy "consumption" (one should really speak of "energy transformation") of a society or country is often quoted in reference to the average energy released by the combustion of these fossil fuels: :1  tonne of coal equivalent (TCE) = 29.3076 GJ = 8,141 kilowatt hour :1 tonne of oil equivalent (TOE) = 41.868 GJ = 11,630 kilowatt hour On the same basis, a tank-full of gasoline (45 litres, 12 gallons) is equivalent to about 1.6 GJ of chemical energy. Another chemically based unit of measurement for energy is the "tonne of TNT", taken as 4.184 GJ. Hence, burning a tonne of oil releases about ten times as much energy as the explosion of one tonne of TNT: fortunately, the energy is usually released in a slower, more controlled manner.

Simple examples of storage of chemical energy are batteries and food. When food is digested and metabolized (often with oxygen), chemical energy is released, which can in turn be transformed into heat, or by muscles into kinetic energy.

Nuclear energy

{| class="wikitable" align=right width=150px |- |+ Examples of the interconversion of energy |- ! colspan=2 | Nuclear binding energy is converted |- ! into ! by |- | Mechanical energy | Alpha radiation |- | Thermal energy | Sun |- | Electrical energy | Beta radiation |- | Electromagnetic radiation | Gamma radiation |- | Chemical energy | Radioactive decay |- | Nuclear energy | Nuclear isomerism |- |}

Nuclear potential energy, along with electric potential energy, provides the energy released from nuclear fission and nuclear fusion processes. The result of both these processes are nuclei in which the more-optimal size of the nucleus allows the nuclear force (which is opposed by the electromagnetic force) to bind nuclear particles more tightly together than before the reaction.

The Weak nuclear force (different from the strong force) provides the potential energy for certain kinds of radioactive decay, such as beta decay.

The energy released in nuclear processes is so large that the relativistic change in mass (after the energy has been removed) can be as much as several parts per thousand.

Nuclear particles (nucleons) like protons and neutrons are not destroyed (law of conservation of baryon number) in fission and fusion processes. A few lighter particles may be created or destroyed (example: beta minus and beta plus decay, or electron capture decay), but these minor processes are not important to the immediate energy release in fission and fusion. Rather, fission and fusion release energy when collections of baryons become more tightly bound, and it is the energy associated with a fraction of the mass of the nucleons (but not the whole particles) which appears as the heat and electromagnetic radiation generated by nuclear reactions. This heat and radiation retains the "missing" mass, but the mass is missing only because it escapes in the form of heat or light, which retain the mass and conduct it out of the system where it is not measured.

The energy from the Sun, also called solar energy, is an example of this form of energy conversion. In the Sun, the process of hydrogen fusion converts about 4 million metric tons of solar matter per second into light, which is radiated into space, but during this process, the number of total protons and neutrons in the sun does not change. In this system, the light itself retains the inertial equivalent of this mass, and indeed the mass itself (as a system), which represents 4 million tons per second of electromagnetic radiation, moving into space. Each of the helium nuclei which are formed in the process are less massive than the four protons from they were formed, but (to a good approximation), no particles or atoms are destroyed in the process of turning the sun's nuclear potential energy into light.

Transformations of energy

One form of energy can often be readily transformed into another with the help of a device- for instance, a battery, from chemical energy to electric energy; a dam: gravitational potential energy to kinetic energy of moving water (and the blades of a turbine) and ultimately to electric energy through an electric generator. Similarly, in the case of a chemical explosion, chemical potential energy is transformed to kinetic energy and thermal energy in a very short time. Yet another example is that of a pendulum. At its highest points the kinetic energy is zero and the gravitational potential energy is at maximum. At its lowest point the kinetic energy is at maximum and is equal to the decrease of potential energy. If one (unrealistically) assumes that there is no friction, the conversion of energy between these processes is perfect, and the pendulum will continue swinging forever.

Energy gives rise to weight and is equivalent to matter and vice versa. The formula E = mc², derived by Albert Einstein (1905) quantifies the relationship between mass and rest energy within the concept of special relativity. In different theoretical frameworks, similar formulas were derived by J. J. Thomson (1881), Henri Poincaré (1900), Friedrich Hasenöhrl (1904) and others (see Mass-energy equivalence#History for further information). Since $c^2$ is extremely large relative to ordinary human scales, the conversion of ordinary amount of mass (say, 1 kg) to other forms of energy can liberate tremendous amounts of energy (~$9x10^\{16\}$ joules), as can be seen in nuclear reactors and nuclear weapons. Conversely, the mass equivalent of a unit of energy is minuscule, which is why a loss of energy from most systems is difficult to measure by weight, unless the energy loss is very large. Examples of energy transformation into matter (particles) are found in high energy nuclear physics.

Transformation of energy into useful work is a core topic of thermodynamics. In nature, transformations of energy can be fundamentally classed into two kinds: those that are thermodynamically reversible, and those that are thermodynamically irreversible. A reversible process in thermodynamics is one in which no energy is dissipated (spread) into empty energy states available in a volume, from which it cannot be recovered into more concentrated forms (fewer quantum states), without degradation of even more energy. A reversible process is one in which this sort of dissipation does not happen. For example, conversion of energy from one type of potential field to another, is reversible, as in the pendulum system described above. In processes where heat is generated, quantum states of lower energy, present as possible exitations in fields between atoms, act as a reservoir for part of the energy, from which it cannot be recovered, in order to be converted with 100% efficiency into other forms of energy. In this case, the energy must partly stay as heat, and cannot be completely recovered as usable energy, except at the price of an increase in some other kind of heat-like increase in disorder in quantum states, in the universe (such as an expansion of matter, or a randomization in a crystal).

As the universe evolves in time, more and more of its energy becomes trapped in irreversible states (i.e., as heat or other kinds of increases in disorder). This has been referred to as the inevitable thermodynamic heat death of the universe. In this heat death the energy of the universe does not change, but the fraction of energy which is available to do produce work through a heat engine, or be transformed to other usable forms of energy (through the use of generators attached to heat engines), grows less and less.

See also

*Index of energy articles

Outline of energy

Notes and references

Further reading

External links

Category:Fundamental physics concepts Category:Greek loanwords Category:Introductory physics Category:Physical quantities Category:State functions