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From left to right: 1 mW Uniphase HeNe on alignment-rig, 2 Watt Lexel 88 Argon Ion laser, and power-supply. To the rear are hoses for water cooling.

An ion laser is a gas laser which uses an ionized gas as its lasing medium.^[1] Like other gas lasers, ion lasers feature a sealed cavity containing the laser medium and mirrors forming a Fabry–Pérot resonator. Unlike HeNe lasers, the energy level transitions that contribute to laser action come from ions. Because of the large amount of energy required to excite the ionic transitions used in ion lasers, the required current is much greater, and as a result all but the smallest ion lasers are water-cooled. A small air-cooled ion laser might produce, for example, 130mW of light with a tube current of 10A @ 105V. This is a total power draw over 1 kW, which translates into a large amount of heat which must be dissipated.

Types[link]

Krypton laser[link]

A krypton laser is an ion laser, a type of gas laser using krypton ions as a gain medium, pumped by electric discharge. Krypton lasers are used for scientific research, or when krypton is mixed with argon, for creation of "white-light" lasers, useful for laser light shows. Krypton lasers are also used in medicine (e.g. for coagulation of retina), for manufacture of security holograms, and numerous other purposes.

Krypton lasers emit at several wavelengths through the visible spectrum: at 406.7 nm, 413.1 nm, 415,4 nm, 468.0 nm, 476.2 nm, 482.5 nm, 520.8 nm, 530.9 nm, 568.2 nm, 647.1 nm, 676.4 nm.

Argon laser[link]

This argon-ion laser emits blue-green light at 488/514 nm.

The Argon laser was invented in 1964 by William Bridges at Hughes Aircraft ^[2]and is one of a family of Ion lasers that use a noble gas as the active medium.

Argon lasers are used for retinal phototherapy (for diabetes), lithography, and pumping other lasers. Argon lasers emit at 13 wavelengths through the visible, ultraviolet, and near-visible spectrum, including: 351.1 nm, 363.8 nm, 454.6 nm, 457.9 nm, 465.8 nm, 476.5 nm, 488.0 nm, 496.5 nm, 501.7 nm, 514.5 nm, 528.7 nm, 1092.3 nm^[3].

An argon laser beam consisting of multiple colors (wavelengths) strikes a silicon diffraction mirror grating and is separated into several beams, one for each wavelength. The wavelengths are (left to right) 458nm, 476nm, 488nm, 497nm, 502nm, 515nm.

Common argon and krypton lasers are capable of emitting continual wave output of several milliwatts to tens of watts. Their tubes are usually made of Nickel end bells, kovar metal to ceramic seals, beryllium oxide ceramics, or tungsten disks mounted on a copper heat spreader in a ceramic liner. The earliest tubes were simple quartz, followed by quartz with graphite disks. In comparison with the helium-neon lasers requiring just a few milliamps, the current used for pumping the krypton laser ranges in several amperes, as the gas has to be ionized. The ion laser tube produces a lot of waste heat and requires active cooling.

The typical noble gas ion laser plasma consists of a high-current-density glow discharge in a noble gas, in the presence of a magnetic field. Typical CW plasma conditions are current densities of 100 to 2000 A/cm^2, tube diameters of 1 to 10 mm, filling pressures of 0.1 to 1.0 torr, and an axial magnetic field of the order of 1000 G. (Bridges,Halstead et al., Proceedings of the IEEE, 59 (5). pp. 724-739)

William R. Bennett was co-inventor of the first gas laser (the helium-neon laser), was first to observe spectral hole burning effects in gas lasers, and created a theory of hole burning effects on laser oscillation. He was co-discoverer of lasers using electron impact excitation in each of the noble gases, dissociative excitation transfer in the neon-oxygen laser (the first chemical laser), and collision excitation in several metal vapor lasers.

Other commercially available types[link]

• Ar/Kr: A mix of argon and krypton can result in a laser with output wavelengths that appear as white light.
• Helium Cadmium, Blue laser emission at 442 nm and Ultraviolet at 325 nm
• Copper Vapor, Yellow and Green emission at 578 nm and 510 nm

Experimental[link]

• Xenon^[4]
• Iodine ^[5]
• Oxygen ^[6]

Power supplies[link]

This section is in a list format that may be better presented using prose. You can help by converting this section to prose, if appropriate. Editing help is available. (February 2011)

• NPN passbank like the Spectra-physics 270 supply
• MOSFET switchers like the Omnichrome 150 supply
• Early switchers used NPN_PNP Pairs, (i.e. American Laser or HGM Medical)
• IGBT will be seen more in days to come
• Switched resistor (Spectra Physics)
• Non-switched resistor (Home-made, typically a water heater element)
• Water-cooled resistor (Laser Ionics etc.)
• Phased SCR power supplies similar to long xenon arc lamps are used in medical lasers to reduce expense (Coherent)
• Power on Demand power supplies are used for pulsed medical ion laser systems, these power supplies consist of a large capacitor bank charged by a switching supply to enable multi watt lasers to run off common single phase power supplies in doctor's offices.
• A typical air-cooled Argon Tube needs an equivalent series resistance of ~6 Ohms when running @ 10 amps off 117V power. The plasma in an ion laser, unlike a Helium Neon Laser, has a slightly positive resistance, but will still run away without ballasting. This is why ion laser supplies are very difficult to design. On a large frame laser, the plasma itself has an effective resistance of about -7 Ohms (Spectra Physics 171 Service Manual)

Applications[link]

This section is in a list format that may be better presented using prose. You can help by converting this section to prose, if appropriate. Editing help is available. (February 2011)

• Surgical.
• Laser medicine.
• High speed typesetters.
• Laser light shows.
• DNA sequencers for DNA sequencing.
• Spectroscopy experiments.
• Providing the excitation source for tunable dye lasers.^[7]
• Semiconductor mask inspection.
• Semiconductor wafer inspection.
• Direct write high density PCB lithography.
• Fiber Bragg Grating production.
• Long coherence length models can be used for holography.

See also[link]

• Laser
• List of laser types
• List of plasma (physics) articles

References[link]

This article needs additional citations for verification. Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed. (December 2007)

Hydrogen atom (center) contains a single proton and a single electron. Removal of the electron gives a cation (left), whereas addition of an electron gives an anion (right). The hydrogen anion, with its loosely held two-electron cloud, has a larger radius than the neutral atom, which in turn is much larger than the bare proton of the cation. Hydrogen forms the only cation that has no electrons, but even cations that (unlike hydrogen) still retain one or more electrons are still smaller than the neutral atoms or molecules from which they are derived.

An ion is an atom or molecule in which the total number of electrons is not equal to the total number of protons, giving it a net positive or negative electrical charge. The name was given by physicist Michael Faraday for the substances that allow a current to pass ("go") between electrodes in a solution, when an electric field is applied. It is the transliteration of the Greek participle ἰόν, ión, "going".

An ion consisting of a single atom is an atomic or monatomic ion; if it consists of two or more atoms, it is a molecular or polyatomic ion.

Anions and cations[link]

An anion (−) ( /ˈæn.aɪ.ən/ AN-eye-ən), from the Greek word ἄνω (ánō), meaning "up", is an ion with more electrons than protons, giving it a net negative charge (since electrons are negatively charged and protons are positively charged).

A cation (+) ( /ˈkæt.aɪ.ən/ KAT-eye-ən), from the Greek word κατά (katá), meaning "down", is an ion with fewer electrons than protons, giving it a positive charge. Since the charge on a proton is equal in magnitude to the charge on an electron, the net charge on an ion is equal to the number of protons in the ion minus the number of electrons.

General[link]

History and discovery[link]

The word ion is the Greek ιον (going), the present participle of ιεναι, ienai, "to go". This term was introduced by English physicist and chemist Michael Faraday in 1834 for the then-unknown species that goes from one electrode to the other through an aqueous medium.^[1][2] Faraday did not know the nature of these species, but he knew that since metals dissolved into and entered solution at one electrode, and new metal came forth from solution at the other electrode, that some kind of substance moved through the solution in a current, conveying matter from one place to the other.

Faraday also introduced the words anion for a negatively charged ion, and cation for a positively charged one. In Faraday's nomenclature, cations were named because they were attracted to the cathode in a galvanic device and anions were named due to their attraction to the anode.

Characteristics[link]

Ions in their gas-like state are highly reactive, and do not occur in large amounts on Earth, except in flames, lightning, electrical sparks, and other plasmas. These gas-like ions rapidly interact with ions of opposite charge to give neutral molecules or ionic salts. Ions are also produced in the liquid or solid state when salts interact with solvents (for example, water) to produce "solvated ions," which are more stable, for reasons involving a combination of energy and entropy changes as the ions move away from each other to interact with the liquid. These stabilized species are more commonly found in the environment at low temperatures. A common example is the ions present in seawater, which are derived from the dissolved salts.

All ions are charged, which means that like all charged objects they are:

• attracted to opposite electric charges (positive to negative, and vice versa),
• repelled by like charges
• when moving, travel in trajectories that are deflected by a magnetic field.

Electrons, due to their smaller mass and thus larger space-filling properties as matter waves, determine the size of atoms and molecules that possess any electrons at all. Thus, anions (negatively charged ions) are larger than the parent molecule or atom, as the excess electron(s) repel each other, and add to the physical size of the ion, because its size is determined by its electron cloud. As such, in general, cations are smaller than the corresponding parent atom or molecule due to the smaller size of its electron cloud. One particular cation (that of hydrogen) contains no electrons, and thus is very much smaller than the parent hydrogen atom.

Natural occurrences[link]

Ions are ubiquitous in nature and are responsible for diverse phenomena from the luminescence of the Sun to the existence of the Earth's ionosphere. Atoms in their ionic state may have a different color from neutral atoms, and thus light absorption by metal ions gives the color of gemstones. In both inorganic and organic chemistry (including biochemistry), the interaction of water and ions is extremely important; an example is the energy that drives breakdown of ATP. The following sections describe contexts in which ions feature prominently; these are arranged in decreasing physical length-scale, from the astronomical to the microscopic.

Astronomical[link]

The remnant of "Tycho's Supernova", a huge ball of expanding plasma. The outer shell shown in blue is X-ray emission by high-speed electrons.

A collection of non-aqueous gas-like ions, or even a gas containing a proportion of charged particles, is called a plasma. Greater than 99.9% of visible matter in the Universe may be in the form of plasmas.^[3] These include our Sun and other stars and the space between planets, as well as the space in between stars. Plasmas are often called the fourth state of matter because their properties are substantially different from those of solids, liquids, and gases. Astrophysical plasmas predominantly contain a mixture of electrons and protons (ionized hydrogen).

Related technology[link]

Ions can be non-chemically prepared using various ion sources, usually involving high voltage or temperature. These are used in a multitude of devices such as mass spectrometers, optical emission spectrometers, particle accelerators, ion implanters, and ion engines.

As reactive charged particles, they are also used in air purification by disrupting microbes, and in household items such as smoke detectors.

As signaling and metabolism in organisms are controlled by a precise ionic gradient across membranes, the disruption of this gradient contributes to cell death. This is a common mechanism exploited by natural and artificial biocides, including the ion channels gramicidin and amphotericin (a fungicide).

Inorganic dissolved ions are a component of total dissolved solids, an indicator of water quality in the world.

Chemistry[link]

Notation[link]

Denoting the charged state[link]

Equivalent notations for an iron atom (Fe) that lost two electrons.

When writing the chemical formula for an ion, its net charge is written in superscript immediately after the chemical structure for the molecule/atom. The net charge is written with the magnitude before the sign; that is, a doubly charged cation is indicated as 2+ instead of +2. However, the magnitude of the charge is omitted for singly charged molecules/atoms; for example, the sodium cation is indicated as Na⁺ and not Na¹⁺.

An alternative (and acceptable) way of showing a molecule/atom with multiple charges is by drawing out the signs multiple times; this is often seen with transition metals. Chemists sometimes circle the sign; this is merely ornamental and does not alter the chemical meaning. All three representations of Fe²⁺ shown in the figure are, thus, equivalent.

Mixed Roman numerals and charge notations for the uranyl ion. The oxidation state of the metal is shown as superscripted Roman numerals, whereas the charge of the entire complex is shown by the angle symbol together with the magnitude and sign of the net charge.

Monatomic ions are sometimes also denoted with Roman numerals; for example, the Fe²⁺ example seen above is occasionally referred to as Fe(II) or Fe^II. The Roman numeral designates the formal oxidation state of an element, whereas the superscripted numerals denotes the net charge. The two notations are, therefore, exchangeable for monatomic ions, but the Roman numerals cannot be applied to polyatomic ions. However, it is possible to mix the notations for the individual metal center with a polyatomic complex, as shown by the uranyl ion example.

Sub-classes[link]

If an ion contains unpaired electrons, it is called a radical ion. Just like uncharged radicals, radical ions are very reactive. Polyatomic ions containing oxygen, such as carbonate and sulfate, are called oxyanions. Molecular ions that contain at least one carbon to hydrogen bond are called organic ions. If the charge in an organic ion is formally centered on a carbon, it is termed a carbocation (if positively charged) or carbanion (if negatively charged).

Formation[link]

Formation of monatomic ions[link]

Monatomic ions are formed by the addition of electrons to the valence shell of the atom, which is the outer-most electron shell in an atom, or the losing of electrons from this shell. The inner shells of an atom are filled with electrons that are tightly bound to the positively charged atomic nucleus, and so do not participate in this kind of chemical interaction. The process of gaining or losing electrons from a neutral atom or molecule is called ionization.

Atoms can be ionized by bombardment with radiation, but the more usual process of ionization encountered in chemistry is the transfer of electrons between atoms or molecules. This transfer is usually driven by the attaining of stable ("closed shell") electronic configurations. Atoms will gain or lose electrons depending on which action takes the least energy.

For example, a sodium atom, Na, has a single electron in its valence shell, surrounding 2 stable, filled inner shells of 2 and 8 electrons. Since these filled shells are very stable, a sodium atom tends to lose its extra electron and attain this stable configuration, becoming a sodium cation in the process

Na → Na⁺ + e−

On the other hand, a chlorine atom, Cl, has 7 electrons in its valence shell, which is one short of the stable, filled shell with 8 electrons. Thus, a chlorine atom tends to gain an extra electron and attain a stable 8-electron configuration, becoming a chloride anion in the process:

Cl + e−
→ Cl⁻

This driving force is what causes sodium and chlorine to undergo a chemical reaction, wherein the "extra" electron is transferred from sodium to chlorine, forming sodium cations and chloride anions. Being oppositely charged, these cations and anions form ionic bonds and combine to form sodium chloride, NaCl, more commonly known as rock salt.

Na⁺ + Cl⁻ → NaCl

Formation of polyatomic and molecular ions[link]

An electrostatic potential map of the nitrate ion (NO−
3). The 3-dimensional shell represents a single arbitrary isopotential.

Polyatomic and molecular ions are often formed by the gaining or losing of elemental ions such as H⁺ in neutral molecules. For example, when ammonia, NH₃, accepts a proton, H⁺, it forms the ammonium ion, NH+
4. Ammonia and ammonium have the same number of electrons in essentially the same electronic configuration, but ammonium has an extra proton that gives it a net positive charge.

Ammonia can also lose an electron to gain a positive charge, forming the ion ·NH+
3. However, this ion is unstable, because it has an incomplete valence shell around the nitrogen atom, making it a very reactive radical ion.

Due to the instability of radical ions, polyatomic and molecular ions are usually formed by gaining or losing elemental ions such as H⁺, rather than gaining or losing electrons. This allows the molecule to preserve its stable electronic configuration while acquiring an electrical charge.

Ionization potential[link]

The energy required to detach an electron in its lowest energy state from an atom or molecule of a gas with less net electric charge is called the ionization potential, or ionization energy. The nth ionization energy of an atom is the energy required to detach its nth electron after the first n − 1 electrons have already been detached.

Each successive ionization energy is markedly greater than the last. Particularly great increases occur after any given block of atomic orbitals is exhausted of electrons. For this reason, ions tend to form in ways that leave them with full orbital blocks. For example, sodium has one valence electron in its outermost shell, so in ionized form it is commonly found with one lost electron, as Na⁺. On the other side of the periodic table, chlorine has seven valence electrons, so in ionized form it is commonly found with one gained electron, as Cl⁻. Caesium has the lowest measured ionization energy of all the elements and helium has the greatest.^[4] In general, the ionization energy of metals is much lower than the ionization energy of nonmetals, which is why, in general, metals will lose electrons to form positively charged ions and nonmetals will gain electrons to form negatively charged ions.

Ionic bonding[link]

Ionic bonding is a kind of chemical bonding that arises from the mutual attraction of oppositely charged ions. Since ions of like charge repel each other, they do not usually exist on their own. Instead, many of them may form a crystal lattice, in which ions of opposite charge are bound to each other. The resulting compound is called an ionic compound, and is said to be held together by ionic bonding. In ionic compounds there arise characteristic distances between ion neighbors from which the spatial extension and the ionic radius of individual ions may be derived.

The most common type of ionic bonding is seen in compounds of metals and nonmetals (except noble gases, which rarely form chemical compounds). Metals are characterized by having a small number of electrons in excess of a stable, closed-shell electronic configuration. As such, they have the tendency to lose these extra electrons in order to attain a stable configuration. This property is known as electropositivity. Non-metals, on the other hand, are characterized by having an electron configuration just a few electrons short of a stable configuration. As such, they have the tendency to gain more electrons in order to achieve a stable configuration. This tendency is known as electronegativity. When a highly electropositive metal is combined with a highly electronegative nonmetal, the extra electrons from the metal atoms are transferred to the electron-deficient nonmetal atoms. This reaction produces metal cations and nonmetal anions, which are attracted to each other to form a salt.

Chemical applications[link]

This section requires expansion.

Gas-like ions and solvated ions both have tremendous impact on chemical analysis and synthesis.

Mass spectrometry[link]

Catalysis[link]

Transition metal ions catalysis[link]

This section is empty. You can help by adding to it.

Templated synthesis of organic compounds[link]

This section is empty. You can help by adding to it.

Common ions[link]

See also[link]

• Air ionizer
• Anode
• Cathode
• Ion beam
• Ion source
• Ionic radius
• Auroras
• List of plasma (physics) articles

References[link]

v t e Galvanic cells Non-rechargeable: primary cells Alkaline battery Aluminium battery Bunsen cell Chromic acid cell Clark cell Daniell cell Dry cell Grove cell Leclanché cell Lithium battery Mercury battery Nickel oxyhydroxide battery Silicon–air battery Silver-oxide battery Weston cell Zamboni pile Zinc–air battery Zinc–carbon battery Zinc–chloride battery Rechargeable: secondary cells Automotive battery Lead–acid battery Lead–acid battery (gel) Lithium–air battery Lithium-ion battery Beltway battery Lithium-ion polymer battery Lithium iron phosphate battery Lithium–sulfur battery Lithium–titanate battery Nickel–cadmium battery Nickel–hydrogen battery Nickel–iron battery Nickel–lithium battery Nickel–metal hydride battery Low self-discharge NiMH battery Nickel–zinc battery Potassium-ion battery Rechargeable alkaline battery Sodium-ion battery Sodium–sulfur battery Vanadium redox battery Zinc–bromine battery Zinc–cerium battery Kinds of cells Battery Wet cell Dry cell Concentration cell Flow battery Fuel cell Trough battery Voltaic pile Parts of cells Anode Catalyst Cathode Electrolyte Half-cell Ions Salt bridge Semipermeable membrane

United States Air Force laser experiment

Red (635 nm), green (532 nm), and blue-violet (445 nm) lasers

A laser is a device that emits light (electromagnetic radiation) through a process of optical amplification based on the stimulated emission of photons. The term "laser" originated as an acronym for Light Amplification by Stimulated Emission of Radiation.^[1][2] The emitted laser light is notable for its high degree of spatial and temporal coherence, unattainable using other technologies.

Spatial coherence typically is expressed through the output being a narrow beam which is diffraction-limited, often a so-called "pencil beam." Laser beams can be focused to very tiny spots, achieving a very high irradiance. Or they can be launched into a beam of very low divergence in order to concentrate their power at a large distance.

Temporal (or longitudinal) coherence implies a polarized wave at a single frequency whose phase is correlated over a relatively large distance (the coherence length) along the beam.^[3] A beam produced by a thermal or other incoherent light source has an instantaneous amplitude and phase which vary randomly with respect to time and position, and thus a very short coherence length.

Most so-called "single wavelength" lasers actually produce radiation in several modes having slightly different frequencies (wavelengths), often not in a single polarization. And although temporal coherence implies monochromaticity, there are even lasers that emit a broad spectrum of light, or emit different wavelengths of light simultaneously. There are some lasers which are not single spatial mode and consequently their light beams diverge more than required by the diffraction limit. However all such devices are classified as "lasers" based on their method of producing that light: stimulated emission. Lasers are employed in applications where light of the required spatial or temporal coherence could not be produced using simpler technologies.

Terminology[link]

Laser beams in fog, reflected on a car windshield

The word laser started as an acronym for "light amplification by stimulated emission of radiation"; in modern usage "light" broadly denotes electromagnetic radiation of any frequency, not only visible light, hence infrared laser, ultraviolet laser, X-ray laser, and so on. Because the microwave predecessor of the laser, the maser, was developed first, devices of this sort operating at microwave and radio frequencies are referred to as "masers" rather than "microwave lasers" or "radio lasers". In the early technical literature, especially at Bell Telephone Laboratories, the laser was called an optical maser; this term is now obsolete.^[4]

A laser which produces light by itself is technically an optical oscillator rather than an optical amplifier as suggested by the acronym. It has been humorously noted that the acronym LOSER, for "light oscillation by stimulated emission of radiation," would have been more correct.^[5] With the widespread use of the original acronym as a common noun, actual optical amplifiers have come to be referred to as "laser amplifiers", notwithstanding the apparent redundancy in that designation.

The back-formed verb to lase is frequently used in the field, meaning "to produce laser light,"^[6] especially in reference to the gain medium of a laser; when a laser is operating it is said to be "lasing." Further use of the words laser and maser in an extended sense, not referring to laser technology or devices, can be seen in usages such as astrophysical maser and atom laser.

Design[link]

Components of a typical laser:
1. Gain medium
2. Laser pumping energy
3. High reflector
4. Output coupler
5. Laser beam

A laser consists of a gain medium, a mechanism to supply energy to it, and something to provide optical feedback.^[7] The gain medium is a material with properties that allow it to amplify light by stimulated emission. Light of a specific wavelength that passes through the gain medium is amplified (increases in power).

For the gain medium to amplify light, it needs to be supplied with energy. This process is called pumping. The energy is typically supplied as an electrical current, or as light at a different wavelength. Pump light may be provided by a flash lamp or by another laser.

The most common type of laser uses feedback from an optical cavity—a pair of mirrors on either end of the gain medium. Light bounces back and forth between the mirrors, passing through the gain medium and being amplified each time. Typically one of the two mirrors, the output coupler, is partially transparent. Some of the light escapes through this mirror. Depending on the design of the cavity (whether the mirrors are flat or curved), the light coming out of the laser may spread out or form a narrow beam. This type of device is sometimes called a laser oscillator in analogy to electronic oscillators, in which an electronic amplifier receives electrical feedback that causes it to produce a signal.

Most practical lasers contain additional elements that affect properties of the emitted light such as the polarization, the wavelength, and the shape of the beam.

Laser physics[link]

Electrons and how they interact with electromagnetic fields are important in our understanding of chemistry and physics.

Stimulated emission[link]

In the classical view, the energy of an electron orbiting an atomic nucleus is larger for orbits further from the nucleus of an atom. However, quantum mechanical effects force electrons to take on discrete positions in orbitals. Thus, electrons are found in specific energy levels of an atom, two of which are shown below:

When an electron absorbs energy either from light (photons) or heat (phonons), it receives that incident quanta of energy. But transitions are only allowed in between discrete energy levels such as the two shown above. This leads to emission lines and absorption lines.

When an electron is excited from a lower to a higher energy level, it will not stay that way forever. An electron in an excited state may decay to a lower energy state which is not occupied, according to a particular time constant characterizing that transition. When such an electron decays without external influence, emitting a photon, that is called "spontaneous emission". The phase associated with the photon that is emitted is random. A material with many atoms in such an excited state may thus result in radiation which is very spectrally limited (centered around one wavelength of light), but the individual photons would have no common phase relationship and would emanate in random directions. This is the mechanism of fluorescence and thermal emission.

An external electromagnetic field at a frequency associated with a transition can affect the quantum mechanical state of the atom. As the electron in the atom makes a transition between two stationary states (neither of which shows a dipole field), it enters a transition state which does have a dipole field, and which acts like a small electric dipole, and this dipole oscillates at a characteristic frequency. In response to the external electric field at this frequency, the probability of the atom entering this transition state is greatly increased. Thus, the rate of transitions between two stationary states is enhanced beyond that due to spontaneous emission. Such a transition to the higher state is called absorption, and it destroys an incident photon (the photon's energy goes into powering the increased energy of the higher state). A transition from the higher to a lower energy state, however, produces an additional photon; this is the process of stimulated emission.

Gain medium and cavity[link]

A helium-neon laser demonstration at the Kastler-Brossel Laboratory at Univ. Paris 6. The pink-orange glow running through the center of the tube is from the electric discharge which produces incoherent light, just as in a neon tube. This glowing plasma is excited and then acts as the gain medium through which the internal beam passes, as it is reflected between the two mirrors. Laser radiation output through the front mirror can be seen to produce a tiny (about 1mm in diameter) intense spot on the screen, to the right. Although it is a deep and pure red color, spots of laser light are so intense that cameras are typically overexposed and distort their color.

Spectrum of a helium neon laser illustrating its very high spectral purity (limited by the measuring apparatus). The .002 nm bandwidth of the lasing medium is well over 10,000 times narrower than the spectral width of a light-emitting diode (whose spectrum is shown here for comparison), with the bandwidth of a single longitudinal mode being much narrower still.

The gain medium is excited by an external source of energy into an excited state. In most lasers this medium consists of population of atoms which have been excited into such a state by means of an outside light source, or a electrical field which supplies energy for atoms to absorb and be transformed into their excited states.

The gain medium of a laser is normally a material of controlled purity, size, concentration, and shape, which amplifies the beam by the process of stimulated emission described above. This material can be of any state: gas, liquid, solid, or plasma. The gain medium absorbs pump energy, which raises some electrons into higher-energy ("excited") quantum states. Particles can interact with light by either absorbing or emitting photons. Emission can be spontaneous or stimulated. In the latter case, the photon is emitted in the same direction as the light that is passing by. When the number of particles in one excited state exceeds the number of particles in some lower-energy state, population inversion is achieved and the amount of stimulated emission due to light that passes through is larger than the amount of absorption. Hence, the light is amplified. By itself, this makes an optical amplifier. When an optical amplifier is placed inside a resonant optical cavity, one obtains a laser oscillator.^[8]

In a few situations it is possible to obtain lasing with only a single pass of EM radiation through the gain medium, and this produces a laser beam without any need for a resonant or reflective cavity (see for example nitrogen laser).^[9] Thus, reflection in a resonant cavity is usually required for a laser, but is not absolutely necessary.

The optical resonator is sometimes referred to as an "optical cavity", but this is a misnomer: lasers use open resonators as opposed to the literal cavity that would be employed at microwave frequencies in a maser. The resonator typically consists of two mirrors between which a coherent beam of light travels in both directions, reflecting back on itself so that an average photon will pass through the gain medium repeatedly before it is emitted from the output aperture or lost to diffraction or absorption. If the gain (amplification) in the medium is larger than the resonator losses, then the power of the recirculating light can rise exponentially. But each stimulated emission event returns an atom from its excited state to the ground state, reducing the gain of the medium. With increasing beam power the net gain (gain times loss) reduces to unity and the gain medium is said to be saturated. In a continuous wave (CW) laser, the balance of pump power against gain saturation and cavity losses produces an equilibrium value of the laser power inside the cavity; this equilibrium determines the operating point of the laser. If the applied pump power is too small, the gain will never be sufficient to overcome the resonator losses, and laser light will not be produced. The minimum pump power needed to begin laser action is called the lasing threshold. The gain medium will amplify any photons passing through it, regardless of direction; but only the photons in a spatial mode supported by the resonator will pass more than once through the medium and receive substantial amplification.

The light emitted[link]

The light generated by stimulated emission is very similar to the input signal in terms of wavelength, phase, and polarization. This gives laser light its characteristic coherence, and allows it to maintain the uniform polarization and often monochromaticity established by the optical cavity design.

The beam in the cavity and the output beam of the laser, when travelling in free space (or a homogenous medium) rather than waveguides (as in an optical fiber laser), can be approximated as a Gaussian beam in most lasers; such beams exhibit the minimum divergence for a given diameter. However some high power lasers may be multimode, with the transverse modes often approximated using Hermite-Gaussian or Laguerre-Gaussian functions. It has been shown that unstable laser resonators (not used in most lasers) produce fractal shaped beams.^[10] Near the beam "waist" (or focal region) it is highly collimated: the wavefronts are planar, normal to the direction of propagation, with no beam divergence at that point. However due to diffraction, that can only remain true well within the Rayleigh range. The beam of a single transverse mode (gaussian beam) laser eventually diverges at an angle which varies inversely with the beam diameter, as required by diffraction theory. Thus, the "pencil beam" directly generated by a common helium-neon laser would spread out to a size of perhaps 500 kilometers when shone on the Moon (from the distance of the earth). On the other hand the light from a semiconductor laser typically exits the tiny crystal with a large divergence: up to 50°. However even such a divergent beam can be transformed into a similarly collimated beam by means of a lens system, as is always included, for instance, in a laser pointer whose light originates from a laser diode. That is possible due to the light being of a single spatial mode. This unique property of laser light, spatial coherence, cannot be replicated using standard light sources (except by discarding most of the light) as can be appreciated by comparing the beam from a flashlight (torch) or spotlight to that of almost any laser.

Quantum vs. classical emission processes[link]

The mechanism of producing radiation in a laser relies on stimulated emission, where energy is extracted from a transition in an atom or molecule. This is a quantum phenomenon discovered by Einstein who derived the relationship between the A coefficient describing spontaneous emission and the B coefficient which applies to absorption and stimulated emission. However in the case of the free electron laser, atomic energy levels are not involved; it appears that the operation of this rather exotic device can be explained without reference to quantum mechanics.

Continuous and pulsed modes of operation[link]

A laser can be classified as operating in either continuous or pulsed mode, depending on whether the power output is essentially continuous over time or whether its output takes the form of pulses of light on one or another time scale. Of course even a laser whose output is normally continuous can be intentionally turned on and off at some rate in order to create pulses of light. When the modulation rate is on time scales much slower than the cavity lifetime and the time period over which energy can be stored in the lasing medium or pumping mechanism, then it is still classified as a "modulated" or "pulsed" continuous wave laser. Most laser diodes used in communication systems fall in that category.

Continuous wave operation[link]

Some applications of lasers depend on a beam whose output power is constant over time. Such a laser is known as continuous wave (CW). Many types of lasers can be made to operate in continuous wave mode to satisfy such an application. Many of these lasers actually lase in several longitudinal modes at the same time, and beats between the slightly different optical frequencies of those oscillations will in fact produce amplitude variations on time scales shorter than the round-trip time (the reciprocal of the frequency spacing between modes), typically a few nanoseconds or less. In most cases these lasers are still termed "continuous wave" as their output power is steady when averaged over any longer time periods, with the very high frequency power variations having little or no impact in the intended application. (However the term is not applied to mode-locked lasers, where the intention is to create very short pulses at the rate of the round-trip time).

For continuous wave operation it is required for the population inversion of the gain medium to be continually replenished by a steady pump source. In some lasing media this is impossible. In some other lasers it would require pumping the laser at a very high continuous power level which would be impractical or destroy the laser by producing excessive heat. Such lasers cannot be run in CW mode.

Pulsed operation[link]

Pulsed operation of lasers refers to any laser not classified as continuous wave, so that the optical power appears in pulses of some duration at some repetition rate. This encompasses a wide range of technologies addressing a number of different motivations. Some lasers are pulsed simply because they cannot be run in continuous mode.

In other cases the application requires the production of pulses having as large an energy as possible. Since the pulse energy is equal to the average power divided by the repetition rate, this goal can sometimes be satisfied by lowering the rate of pulses so that more energy can be built up in between pulses. In laser ablation for example, a small volume of material at the surface of a work piece can be evaporated if it is heated in a very short time, whereas supplying the energy gradually would allow for the heat to be absorbed into the bulk of the piece, never attaining a sufficiently high temperature at a particular point.

Other applications rely on the peak pulse power (rather than the energy in the pulse), especially in order to obtain nonlinear optical effects. For a given pulse energy, this requires creating pulses of the shortest possible duration utilizing techniques such as Q-switching.

The optical bandwidth of a pulse cannot be narrower than the reciprocal of the pulse width. In the case of extremely short pulses, that implies lasing over a considerable bandwidth, quite contrary to the very narrow bandwidths typical of CW lasers. The lasing medium in some dye lasers and vibronic solid-state lasers produces optical gain over a wide bandwidth, making a laser possible which can thus generate pulses of light as short as a few femtoseconds (10⁻¹⁵ s).

Q-switching[link]

In a Q-switched laser, the population inversion is allowed to build up by introducing loss inside the resonator which exceeds the gain of the medium; this can also be described as a reduction of the quality factor or 'Q' of the cavity. Then, after the pump energy stored in the laser medium has approached the maximum possible level, the introduced loss mechanism (often an electro- or acousto-optical element) is rapidly removed (or that occurs by itself in a passive device), allowing lasing to begin which rapidly obtains the stored energy in the gain medium. This results in a short pulse incorporating that energy, and thus a high peak power.

Mode-locking[link]

A mode-locked laser is capable of emitting extremely short pulses on the order of tens of picoseconds down to less than 10 femtoseconds. These pulses will repeat at the round trip time, that is, the time that it takes light to complete one round trip between the mirrors comprising the resonator. Due to the Fourier limit (also known as energy-time uncertainty), a pulse of such short temporal length has a spectrum spread over a considerable bandwidth. Thus such a gain medium must have a gain bandwidth sufficiently broad to amplify those frequencies. An example of a suitable material is titanium-doped, artificially grown sapphire (Ti:sapphire) which has a very wide gain bandwidth and can thus produce pulses of only a few femtoseconds duration.

Such mode-locked lasers are a most versatile tool for researching processes occurring on extremely short time scales (known as femtosecond physics, femtosecond chemistry and ultrafast science), for maximizing the effect of nonlinearity in optical materials (e.g. in second-harmonic generation, parametric down-conversion, optical parametric oscillators and the like) due to the large peak power, and in ablation applications.^{[citation needed]} Again, because of the extremely short pulse duration, such a laser will produce pulses which achieve an extremely high peak power.

Pulsed pumping[link]

Another method of achieving pulsed laser operation is to pump the laser material with a source that is itself pulsed, either through electronic charging in the case of flash lamps, or another laser which is already pulsed. Pulsed pumping was historically used with dye lasers where the inverted population lifetime of a dye molecule was so short that a high energy, fast pump was needed. The way to overcome this problem was to charge up large capacitors which are then switched to discharge through flashlamps, producing an intense flash. Pulsed pumping is also required for three-level lasers in which the lower energy level rapidly becomes highly populated preventing further lasing until those atoms relax to the ground state. These lasers, such as the excimer laser and the copper vapor laser, can never be operated in CW mode.

History[link]

Foundations[link]

In 1917, Albert Einstein established the theoretic foundations for the laser and the maser in the paper Zur Quantentheorie der Strahlung (On the Quantum Theory of Radiation); via a re-derivation of Max Planck’s law of radiation, conceptually based upon probability coefficients (Einstein coefficients) for the absorption, spontaneous emission, and stimulated emission of electromagnetic radiation; in 1928, Rudolf W. Ladenburg confirmed the existences of the phenomena of stimulated emission and negative absorption;^[11] in 1939, Valentin A. Fabrikant predicted the use of stimulated emission to amplify “short” waves;^[12] in 1947, Willis E. Lamb and R. C. Retherford found apparent stimulated emission in hydrogen spectra and effected the first demonstration of stimulated emission;^[11] in 1950, Alfred Kastler (Nobel Prize for Physics 1966) proposed the method of optical pumping, experimentally confirmed, two years later, by Brossel, Kastler, and Winter.^[13]

Maser[link]

Aleksandr Prokhorov

In 1953, Charles Hard Townes and graduate students James P. Gordon and Herbert J. Zeiger produced the first microwave amplifier, a device operating on similar principles to the laser, but amplifying microwave radiation rather than infrared or visible radiation. Townes's maser was incapable of continuous output.^{[citation needed]} Meanwhile, in the Soviet Union, Nikolay Basov and Aleksandr Prokhorov were independently working on the quantum oscillator and solved the problem of continuous-output systems by using more than two energy levels. These gain media could release stimulated emissions between an excited state and a lower excited state, not the ground state, facilitating the maintenance of a population inversion. In 1955, Prokhorov and Basov suggested optical pumping of a multi-level system as a method for obtaining the population inversion, later a main method of laser pumping.

Townes reports that several eminent physicists – among them Niels Bohr, John von Neumann, Isidor Rabi, Polykarp Kusch, and Llewellyn Thomas — argued the maser violated Heisenberg's uncertainty principle and hence could not work.[1] In 1964 Charles H. Townes, Nikolay Basov, and Aleksandr Prokhorov shared the Nobel Prize in Physics, “for fundamental work in the field of quantum electronics, which has led to the construction of oscillators and amplifiers based on the maser–laser principle”.

Laser[link]

In 1957, Charles Hard Townes and Arthur Leonard Schawlow, then at Bell Labs, began a serious study of the infrared laser. As ideas developed, they abandoned infrared radiation to instead concentrate upon visible light. The concept originally was called an "optical maser". In 1958, Bell Labs filed a patent application for their proposed optical maser; and Schawlow and Townes submitted a manuscript of their theoretical calculations to the Physical Review, published that year in Volume 112, Issue No. 6.

Simultaneously, at Columbia University, graduate student Gordon Gould was working on a doctoral thesis about the energy levels of excited thallium. When Gould and Townes met, they spoke of radiation emission, as a general subject; afterwards, in November 1957, Gould noted his ideas for a “laser”, including using an open resonator (later an essential laser-device component). Moreover, in 1958, Prokhorov independently proposed using an open resonator, the first published appearance (the USSR) of this idea. Elsewhere, in the U.S., Schawlow and Townes had agreed to an open-resonator laser design – apparently unaware of Prokhorov’s publications and Gould’s unpublished laser work.

At a conference in 1959, Gordon Gould published the term LASER in the paper The LASER, Light Amplification by Stimulated Emission of Radiation.^[1][5] Gould’s linguistic intention was using the “-aser” word particle as a suffix – to accurately denote the spectrum of the light emitted by the LASER device; thus x-rays: xaser, ultraviolet: uvaser, et cetera; none established itself as a discrete term, although “raser” was briefly popular for denoting radio-frequency-emitting devices.

Gould’s notes included possible applications for a laser, such as spectrometry, interferometry, radar, and nuclear fusion. He continued developing the idea, and filed a patent application in April 1959. The U.S. Patent Office denied his application, and awarded a patent to Bell Labs, in 1960. That provoked a twenty-eight-year lawsuit, featuring scientific prestige and money as the stakes. Gould won his first minor patent in 1977, yet it was not until 1987 that he won the first significant patent lawsuit victory, when a Federal judge ordered the U.S. Patent Office to issue patents to Gould for the optically pumped and the gas discharge laser devices. The question of just how to assign credit for inventing the laser remains unresolved by historians.^[14]

On May 16, 1960, Theodore H. Maiman operated the first functioning laser,^[15][16] at Hughes Research Laboratories, Malibu, California, ahead of several research teams, including those of Townes, at Columbia University, Arthur Schawlow, at Bell Labs,^[17] and Gould, at the TRG (Technical Research Group) company. Maiman’s functional laser used a solid-state flashlamp-pumped synthetic ruby crystal to produce red laser light, at 694 nanometres wavelength; however, the device only was capable of pulsed operation, because of its three-level pumping design scheme. Later in 1960, the Iranian physicist Ali Javan, and William R. Bennett, and Donald Herriott, constructed the first gas laser, using helium and neon that was capable of continuous operation in the infrared (U.S. Patent 3,149,290); later, Javan received the Albert Einstein Award in 1993. Basov and Javan proposed the semiconductor laser diode concept. In 1962, Robert N. Hall demonstrated the first laser diode device, made of gallium arsenide and emitted at 850 nm the near-infrared band of the spectrum. Later, in 1962, Nick Holonyak, Jr. demonstrated the first semiconductor laser with a visible emission. This first semiconductor laser could only be used in pulsed-beam operation, and when cooled to liquid nitrogen temperatures (77 K). In 1970, Zhores Alferov, in the USSR, and Izuo Hayashi and Morton Panish of Bell Telephone Laboratories also independently developed room-temperature, continual-operation diode lasers, using the heterojunction structure.

Recent innovations[link]

Graph showing the history of maximum laser pulse intensity throughout the past 40 years.

Since the early period of laser history, laser research has produced a variety of improved and specialized laser types, optimized for different performance goals, including:

• new wavelength bands
• maximum average output power
• maximum peak pulse energy
• maximum peak pulse power
• minimum output pulse duration
• maximum power efficiency
• minimum cost

and this research continues to this day.

Lasing without maintaining the medium excited into a population inversion^{[dubious – discuss]} was discovered in 1992 in sodium gas and again in 1995 in rubidium gas by various international teams.^{[citation needed]} This was accomplished by using an external maser to induce "optical transparency" in the medium by introducing and destructively interfering the ground electron transitions between two paths, so that the likelihood for the ground electrons to absorb any energy has been cancelled.

Types and operating principles[link]

For a more complete list of laser types see this list of laser types.

Wavelengths of commercially available lasers. Laser types with distinct laser lines are shown above the wavelength bar, while below are shown lasers that can emit in a wavelength range. The color codifies the type of laser material (see the figure description for more details).

Gas lasers[link]

Following the invention of the HeNe gas laser, many other gas discharges have been found to amplify light coherently. Gas lasers using many different gases have been built and used for many purposes. The helium-neon laser (HeNe) is able to operate at a number of different wavelengths, however the vast majority are engineered to lase at 633 nm; these relatively low cost but highly coherent lasers are extremely common in optical research and educational laboratories. Commercial carbon dioxide (CO₂) lasers can emit many hundreds of watts in a single spatial mode which can be concentrated into a tiny spot. This emission is in the thermal infrared at 10.6 µm; such lasers are regularly used in industry for cutting and welding. The efficiency of a CO₂ laser is unusually high: over 10%. Argon-ion lasers can operate at a number of lasing transitions between 351 and 528.7 nm. Depending on the optical design one or more of these transitions can be lasing simultaneously; the most commonly used lines are 458 nm, 488 nm and 514.5 nm. A nitrogen transverse electrical discharge in gas at atmospheric pressure (TEA) laser is an inexpensive gas laser, often home-built by hobbyists, which produces rather incoherent UV light at 337.1 nm.^[18] Metal ion lasers are gas lasers that generate deep ultraviolet wavelengths. Helium-silver (HeAg) 224 nm and neon-copper (NeCu) 248 nm are two examples. Like all low-pressure gas lasers, the gain media of these lasers have quite narrow oscillation linewidths, less than 3 GHz (0.5 picometers),^[19] making them candidates for use in fluorescence suppressed Raman spectroscopy.

Chemical lasers[link]

Chemical lasers are powered by a chemical reaction permitting a large amount of energy to be released quickly. Such very high power lasers are especially of interest to the military, however continuous wave chemical lasers at very high power levels, fed by streams of gasses, have been developed and have some industrial applications. As examples, in the Hydrogen fluoride laser (2700–2900 nm) and the Deuterium fluoride laser (3800 nm) the reaction is the combination of hydrogen or deuterium gas with combustion products of ethylene in nitrogen trifluoride.

Excimer lasers[link]

Excimer lasers are a special sort of gas laser powered by an electric discharge in which the lasing medium is an excimer, or more precisely an exciplex in existing designs. These are molecules which can only exist with one atom in an excited electronic state. Once the molecule transfers its excitation energy to a photon, therefore, its atoms are no longer bound to each other and the molecule disintegrates. This drastically reduces the population of the lower energy state thus greatly facilitating a population inversion. Excimers currently used are all noble gas compounds; noble gasses are chemically inert and can only form compounds while in an excited state. Excimer lasers typically operate at ultraviolet wavelengths with major applicatons including semiconductor photolithography and LASIK eye surgery. Commonly used excimer molecules include ArF (emission at 193 nm), KrCl (222 nm), KrF (248 nm), XeCl (308 nm), and XeF (351 nm).^[20] The molecular fluorine laser, emitting at 157 nm in the vacuum ultraviolet is sometimes referred to as an excimer laser, however this appears to be a misnomer inasmuch as F₂ is a stable compound.

Solid-state lasers[link]

A frequency-doubled green laser pointer, showing internal construction. Two AAA cells and electronics power the laser module (lower diagram) This contains a powerful 808 nm IR diode laser that optically pumps a Nd:YVO₄ crystal inside a laser cavity. That laser produces 1064 nm (infrared) light which is mainly confined inside the resonator. Also inside the laser cavity, however, is a non-linear KTP crystal which causes frequency doubling, resulting in green light at 532 nm. The front mirror is transparent to this visible wavelength which is then expanded and collimated using two lenses (in this particular design).

Solid-state lasers use a crystalline or glass rod which is "doped" with ions that provide the required energy states. For example, the first working laser was a ruby laser, made from ruby (chromium-doped corundum). The population inversion is actually maintained in the "dopant", such as chromium or neodymium. These materials are pumped optically using a shorter wavelength than the lasing wavelength, often from a flashtube or from another laser.

It should be noted that "solid-state" in this sense refers to a crystal or glass, but this usage is distinct from the designation of "solid-state electronics" in referring to semiconductors. Semiconductor lasers (laser diodes) are pumped electrically and are thus not referred to as solid-state lasers. The class of solid-state lasers would, however, properly include fiber lasers in which dopants in the glass lase under optical pumping. But in practice these are simply referred to as "fiber lasers" with "solid-state" reserved for lasers using a solid rod of such a material.

Neodymium is a common "dopant" in various solid-state laser crystals, including yttrium orthovanadate (Nd:YVO₄), yttrium lithium fluoride (Nd:YLF) and yttrium aluminium garnet (Nd:YAG). All these lasers can produce high powers in the infrared spectrum at 1064 nm. They are used for cutting, welding and marking of metals and other materials, and also in spectroscopy and for pumping dye lasers.

These lasers are also commonly frequency doubled, tripled or quadrupled, in so-called "diode pumped solid state" or DPSS lasers. Under second, third, or fourth harmonic generation these produce 532 nm (green, visible), 355 nm and 266 nm (UV) beams. This is the technology behind the bright laser pointers particularly at green (532 nm) and other short visible wavelengths.

Ytterbium, holmium, thulium, and erbium are other common "dopants" in solid-state lasers. Ytterbium is used in crystals such as Yb:YAG, Yb:KGW, Yb:KYW, Yb:SYS, Yb:BOYS, Yb:CaF2, typically operating around 1020–1050 nm. They are potentially very efficient and high powered due to a small quantum defect. Extremely high powers in ultrashort pulses can be achieved with Yb:YAG. Holmium-doped YAG crystals emit at 2097 nm and form an efficient laser operating at infrared wavelengths strongly absorbed by water-bearing tissues. The Ho-YAG is usually operated in a pulsed mode, and passed through optical fiber surgical devices to resurface joints, remove rot from teeth, vaporize cancers, and pulverize kidney and gall stones.

Titanium-doped sapphire (Ti:sapphire) produces a highly tunable infrared laser, commonly used for spectroscopy. It is also notable for use as a mode-locked laser producing ultrashort pulses of extremely high peak power.

Thermal limitations in solid-state lasers arise from unconverted pump power that manifests itself as heat. This heat, when coupled with a high thermo-optic coefficient (dn/dT) can give rise to thermal lensing as well as reduced quantum efficiency. These types of issues can be overcome by another novel diode-pumped solid-state laser, the diode-pumped thin disk laser. The thermal limitations in this laser type are mitigated by using a laser medium geometry in which the thickness is much smaller than the diameter of the pump beam. This allows for a more even thermal gradient in the material. Thin disk lasers have been shown to produce up to kilowatt levels of power.^[21]

Fiber lasers[link]

Solid-state lasers or laser amplifiers where the light is guided due to the total internal reflection in a single mode optical fiber are instead called fiber lasers. Guiding of light allows extremely long gain regions providing good cooling conditions; fibers have high surface area to volume ratio which allows efficient cooling. In addition, the fiber's waveguiding properties tend to reduce thermal distortion of the beam. Erbium and ytterbium ions are common active species in such lasers.

Quite often, the fiber laser is designed as a double-clad fiber. This type of fiber consists of a fiber core, an inner cladding and an outer cladding. The index of the three concentric layers is chosen so that the fiber core acts as a single-mode fiber for the laser emission while the outer cladding acts as a highly multimode core for the pump laser. This lets the pump propagate a large amount of power into and through the active inner core region, while still having a high numerical aperture (NA) to have easy launching conditions.

Pump light can be used more efficiently by creating a fiber disk laser, or a stack of such lasers.

Fiber lasers have a fundamental limit in that the intensity of the light in the fiber cannot be so high that optical nonlinearities induced by the local electric field strength can become dominant and prevent laser operation and/or lead to the material destruction of the fiber. This effect is called photodarkening. In bulk laser materials, the cooling is not so efficient, and it is difficult to separate the effects of photodarkening from the thermal effects, but the experiments in fibers show that the photodarkening can be attributed to the formation of long-living color centers.^{[citation needed]}

Photonic crystal lasers[link]

Photonic crystal lasers are lasers based on nano-structures that provide the mode confinement and the density of optical states (DOS) structure required for the feedback to take place.^{[clarification needed]} They are typical micrometre-sized^{[dubious – discuss]} and tunable on the bands of the photonic crystals.^{[22][clarification needed]}

Semiconductor lasers[link]

A 5.6 mm 'closed can' commercial laser diode, probably from a CD or DVD player

Semiconductor lasers are diodes which are electrically pumped. Recombination of electrons and holes created by the applied current introduces optical gain. Reflection from the ends of the crystal form an optical resonator, although the resonator can be external to the semiconductor in some designs.

Commercial laser diodes emit at wavelengths from 375 nm to 3500 nm. Low to medium power laser diodes are used in laser printers and CD/DVD players. Laser diodes are also frequently used to optically pump other lasers with high efficiency. The highest power industrial laser diodes, with power up to 10 kW (70dBm)^{[citation needed]}, are used in industry for cutting and welding. External-cavity semiconductor lasers have a semiconductor active medium in a larger cavity. These devices can generate high power outputs with good beam quality, wavelength-tunable narrow-linewidth radiation, or ultrashort laser pulses.

Vertical cavity surface-emitting lasers (VCSELs) are semiconductor lasers whose emission direction is perpendicular to the surface of the wafer. VCSEL devices typically have a more circular output beam than conventional laser diodes, and potentially could be much cheaper to manufacture. As of 2005, only 850 nm VCSELs are widely available, with 1300 nm VCSELs beginning to be commercialized,^[23] and 1550 nm devices an area of research. VECSELs are external-cavity VCSELs. Quantum cascade lasers are semiconductor lasers that have an active transition between energy sub-bands of an electron in a structure containing several quantum wells.

The development of a silicon laser is important in the field of optical computing. Silicon is the material of choice for integrated circuits, and so electronic and silicon photonic components (such as optical interconnects) could be fabricated on the same chip. Unfortunately, silicon is a difficult lasing material to deal with, since it has certain properties which block lasing. However, recently teams have produced silicon lasers through methods such as fabricating the lasing material from silicon and other semiconductor materials, such as indium(III) phosphide or gallium(III) arsenide, materials which allow coherent light to be produced from silicon. These are called hybrid silicon laser. Another type is a Raman laser, which takes advantage of Raman scattering to produce a laser from materials such as silicon.

Dye lasers[link]

Dye lasers use an organic dye as the gain medium. The wide gain spectrum of available dyes, or mixtures of dyes, allows these lasers to be highly tunable, or to produce very short-duration pulses (on the order of a few femtoseconds). Although these tunable lasers are mainly known in their liquid form, researchers have also demonstrated narrow-linewidth tunable emission in dispersive oscillator configurations incorporating solid-state dye gain media.^[24] In their most prevalent form these solid state dye lasers use dye-doped polymers as laser media.

Free electron lasers[link]

Free electron lasers, or FELs, generate coherent, high power radiation, that is widely tunable, currently ranging in wavelength from microwaves, through terahertz radiation and infrared, to the visible spectrum, to soft X-rays. They have the widest frequency range of any laser type. While FEL beams share the same optical traits as other lasers, such as coherent radiation, FEL operation is quite different. Unlike gas, liquid, or solid-state lasers, which rely on bound atomic or molecular states, FELs use a relativistic electron beam as the lasing medium, hence the term free electron.

Bio laser[link]

Living cells can be genetically engineered to produce Green fluorescent protein (GFP). The GFP is used as the laser's "gain medium", where light amplification takes place. The cells are then placed between two tiny mirrors, just 20 millionths of a metre across, which acted as the "laser cavity" in which light could bounce many times through the cell. Upon bathing the cell with blue light, it could be seen to emit directed and intense green laser light.^[25][26]

Exotic laser media[link]

In September 2007, the BBC News reported that there was speculation about the possibility of using positronium annihilation to drive a very powerful gamma ray laser.^[27] Dr. David Cassidy of the University of California, Riverside proposed that a single such laser could be used to ignite a nuclear fusion reaction, replacing the banks of hundreds of lasers currently employed in inertial confinement fusion experiments.^[27]

Space-based X-ray lasers pumped by a nuclear explosion have also been proposed as antimissile weapons.^[28][29] Such devices would be one-shot weapons.

Uses[link]

Lasers range in size from microscopic diode lasers (top) with numerous applications, to football field sized neodymium glass lasers (bottom) used for inertial confinement fusion, nuclear weapons research and other high energy density physics experiments.

When lasers were invented in 1960, they were called "a solution looking for a problem".^[30] Since then, they have become ubiquitous, finding utility in thousands of highly varied applications in every section of modern society, including consumer electronics, information technology, science, medicine, industry, law enforcement, entertainment, and the military.

The first use of lasers in the daily lives of the general population was the supermarket barcode scanner, introduced in 1974. The laserdisc player, introduced in 1978, was the first successful consumer product to include a laser but the compact disc player was the first laser-equipped device to become common, beginning in 1982 followed shortly by laser printers.

Some other uses are:

• Medicine: Bloodless surgery, laser healing, surgical treatment, kidney stone treatment, eye treatment, dentistry
• Industry: Cutting, welding, material heat treatment, marking parts, non-contact measurement of parts
• Military: Marking targets, guiding munitions, missile defence, electro-optical countermeasures (EOCM), alternative to radar, blinding troops.
• Law enforcement: used for latent fingerprint detection in the forensic identification field^[31][32]
• Research: Spectroscopy, laser ablation, laser annealing, laser scattering, laser interferometry, LIDAR, laser capture microdissection, fluorescence microscopy
• Product development/commercial: laser printers, optical discs (e.g. CDs and the like), barcode scanners, thermometers, laser pointers, holograms, bubblegrams.
• Laser lighting displays: Laser light shows
• Cosmetic skin treatments: acne treatment, cellulite and striae reduction, and hair removal.

In 2004, excluding diode lasers, approximately 131,000 lasers were sold with a value of US$2.19 billion.^[33] In the same year, approximately 733 million diode lasers, valued at $3.20 billion, were sold.^[34]

Examples by power[link]

Laser application in astronomical adaptive optics imaging

Different applications need lasers with different output powers. Lasers that produce a continuous beam or a series of short pulses can be compared on the basis of their average power. Lasers that produce pulses can also be characterized based on the peak power of each pulse. The peak power of a pulsed laser is many orders of magnitude greater than its average power. The average output power is always less than the power consumed.

Examples of pulsed systems with high peak power:

• 700 TW (700×10¹² W) – National Ignition Facility, a 192-beam, 1.8-megajoule laser system adjoining a 10-meter-diameter target chamber.^[39]
• 1.3 PW (1.3×10¹⁵ W) – world's most powerful laser as of 1998, located at the Lawrence Livermore Laboratory^[40]

Hobby uses[link]

In recent years, some hobbyists have taken interests in lasers. Lasers used by hobbyists are generally of class IIIa or IIIb, although some have made their own class IV types.^[41] However, compared to other hobbyists, laser hobbyists are far less common, due to the cost and potential dangers involved. Due to the cost of lasers, some hobbyists use inexpensive means to obtain lasers, such as salvaging laser diodes from broken DVD players (red), Blu-ray players (violet), or even higher power laser diodes from CD or DVD burners.^[42]

Hobbyists also have been taking surplus pulsed lasers from retired military applications and modifying them for pulsed holography. Pulsed Ruby and pulsed YAG lasers have been used.

Safety[link]

Warning symbol for lasers

Laser warning label

Even the first laser was recognized as being potentially dangerous. Theodore Maiman characterized the first laser as having a power of one "Gillette" as it could burn through one Gillette razor blade. Today, it is accepted that even low-power lasers with only a few milliwatts of output power can be hazardous to human eyesight, when the beam from such a laser hits the eye directly or after reflection from a shiny surface. At wavelengths which the cornea and the lens can focus well, the coherence and low divergence of laser light means that it can be focused by the eye into an extremely small spot on the retina, resulting in localized burning and permanent damage in seconds or even less time.

Lasers are usually labeled with a safety class number, which identifies how dangerous the laser is:

• Class I/1 is inherently safe, usually because the light is contained in an enclosure, for example in CD players.
• Class II/2 is safe during normal use; the blink reflex of the eye will prevent damage. Usually up to 1 mW power, for example laser pointers.
• Class IIIa/3R lasers are usually up to 5 mW and involve a small risk of eye damage within the time of the blink reflex. Staring into such a beam for several seconds is likely to cause damage to a spot on the retina.
• Class IIIb/3B can cause immediate eye damage upon exposure.
• Class IV/4 lasers can burn skin, and in some cases, even scattered light can cause eye and/or skin damage. Many industrial and scientific lasers are in this class.

The indicated powers are for visible-light, continuous-wave lasers. For pulsed lasers and invisible wavelengths, other power limits apply. People working with class 3B and class 4 lasers can protect their eyes with safety goggles which are designed to absorb light of a particular wavelength.

Certain infrared lasers with wavelengths beyond about 1.4 micrometres are often referred to as being "eye-safe". This is because the intrinsic molecular vibrations of water molecules very strongly absorb light in this part of the spectrum, and thus a laser beam at these wavelengths is attenuated so completely as it passes through the eye's cornea that no light remains to be focused by the lens onto the retina. The label "eye-safe" can be misleading, however, as it only applies to relatively low power continuous wave beams; any high power or Q-switched laser at these wavelengths can burn the cornea, causing severe eye damage.

As weapons[link]

Laser beams are famously employed as weapon systems in science fiction, but actual laser weapons are still in the experimental stage. The general idea of laser-beam weaponry is to hit a target with a train of brief pulses of light. The rapid evaporation and expansion of the surface causes shockwaves^{[citation needed]} that damage the target. The power needed to project a high-powered laser beam of this kind is beyond the limit of current mobile power technology thus favoring chemically powered gas dynamic lasers.

Lasers of all but the lowest powers can potentially be used as incapacitating weapons, through their ability to produce temporary or permanent vision loss in varying degrees when aimed at the eyes. The degree, character, and duration of vision impairment caused by eye exposure to laser light varies with the power of the laser, the wavelength(s), the collimation of the beam, the exact orientation of the beam, and the duration of exposure. Lasers of even a fraction of a watt in power can produce immediate, permanent vision loss under certain conditions, making such lasers potential non-lethal but incapacitating weapons. The extreme handicap that laser-induced blindness represents makes the use of lasers even as non-lethal weapons morally controversial, and weapons designed to cause blindness have been banned by the Protocol on Blinding Laser Weapons. The U.S. Air Force is currently working on the Boeing YAL-1 airborne laser, mounted in a Boeing 747, to shoot down enemy ballistic missiles over enemy territory.

In the field of aviation, the hazards of exposure to ground-based lasers deliberately aimed at pilots have grown to the extent that aviation authorities have special procedures to deal with such hazards.^[43]

On March 18, 2009 Northrop Grumman claimed that its engineers in Redondo Beach had successfully built and tested an electrically powered solid state laser capable of producing a 100-kilowatt beam, powerful enough to destroy an airplane. According to Brian Strickland, manager for the United States Army's Joint High Power Solid State Laser program, an electrically powered laser is capable of being mounted in an aircraft, ship, or other vehicle because it requires much less space for its supporting equipment than a chemical laser.^[44] However the source of such a large electrical power in a mobile application remains unclear.

Fictional predictions[link]

Several novelists described devices similar to lasers, prior to the discovery of stimulated emission:

• A laser-like device was described in Alexey Tolstoy's science fiction novel The Hyperboloid of Engineer Garin in 1927.
• Mikhail Bulgakov exaggerated the biological effect (laser bio stimulation) of intensive red light in his science fiction novel Fatal Eggs (1925), without any reasonable description of the source of this red light. (In that novel, the red light first appears occasionally from the illuminating system of an advanced microscope; then the protagonist Prof. Persikov arranges the special set-up for generation of the red light.)

See also[link]

References[link]

Notes

Further reading

Books

• Bertolotti, Mario (1999, trans. 2004). The History of the Laser, Institute of Physics. ISBN 0-7503-0911-3
• Csele, Mark (2004). Fundamentals of Light Sources and Lasers, Wiley. ISBN 0-471-47660-9
• Koechner, Walter (1992). Solid-State Laser Engineering, 3rd ed., Springer-Verlag. ISBN 0-387-53756-2
• Siegman, Anthony E. (1986). Lasers, University Science Books. ISBN 0-935702-11-3
• Silfvast, William T. (1996). Laser Fundamentals, Cambridge University Press. ISBN 0-521-55617-1
• Svelto, Orazio (1998). Principles of Lasers, 4th ed. (trans. David Hanna), Springer. ISBN 0-306-45748-2
• Taylor, Nick (2000). LASER: The inventor, the Nobel laureate, and the thirty-year patent war. New York: Simon & Schuster. ISBN 0-684-83515-0. 
• Wilson, J. & Hawkes, J.F.B. (1987). Lasers: Principles and Applications, Prentice Hall International Series in Optoelectronics, Prentice Hall. ISBN 0-13-523697-5
• Yariv, Amnon (1989). Quantum Electronics, 3rd ed., Wiley. ISBN 0-471-60997-8
• Bromberg, Joan Lisa (1991). The Laser in America, 1950–1970, MIT Press. ISBN 978-0-262-02318-4

Periodicals

• Applied Physics B: Lasers and Optics (ISSN 0946-2171)
• IEEE Journal of Lightwave Technology (ISSN 0733-8724)
• IEEE Journal of Quantum Electronics (ISSN 0018-9197)
• IEEE Journal of Selected Topics in Quantum Electronics (ISSN 1077-260X)
• IEEE Photonics Technology Letters (ISSN 1041-1135)
• Journal of the Optical Society of America B: Optical Physics (ISSN 0740-3224)
• Laser Focus World (ISSN 0740-2511)
• Optics Letters (ISSN 0146-9592)
• Photonics Spectra (ISSN 0731-1230)

External links[link]

Wikimedia Commons has media related to: Lasers

• Encyclopedia of laser physics and technology by Dr. Rüdiger Paschotta
• A Practical Guide to Lasers for Experimenters and Hobbyists by Samuel M. Goldwasser
• Homebuilt Lasers Page by Professor Mark Csele
• Powerful laser is 'brightest light in the universe' – The world's most powerful laser as of 2008 might create supernova-like shock waves and possibly even antimatter (New Scientist, April 9, 2008)
• Homemade laser project by Kip Kedersha
• "The Laser: basic principles" an online course by Prof. F. Balembois and Dr. S. Forget. Instrumentation for Optics, 2008
• Northrop Grumman's Press Release on the Firestrike 15kw tactical laser product.
• Website on Lasers 50th anniversary by APS, OSA, SPIE
• Advancing the Laser anniversary site by SPIE: Video interviews, open-access articles, posters, DVDs
• Bright Idea: The First Lasers
• Free software for Simulation of random laser dynamics
• Video Demonstrations in Lasers and Optics Produced by the Massachusetts Institute of Technology (MIT). Real-time effects are demonstrated in a way that would be difficult to see in a classroom setting.
• Virtual Museum of Laser History, from the touring exhibit by SPIE