- published: 24 Mar 2014
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Thiocyanate (also known as rhodanide) is the anion [SCN]−. It is the conjugate base of thiocyanic acid. Common derivatives include the colourless salts potassium thiocyanate and sodium thiocyanate. Organic compounds containing the functional group SCN are also called thiocyanates. Mercury(II) thiocyanate was formerly used in pyrotechnics.
Thiocyanate is analogous to the cyanate ion, [OCN]−, wherein oxygen is replaced by sulfur. [SCN]− is one of the pseudohalides, due to the similarity of its reactions to that of halide ions. Thiocyanate used to be known as rhodanide (from a Greek word for rose) because of the red colour of its complexes with iron. Thiocyanate is produced by the reaction of elemental sulfur or thiosulfate with cyanide:
The second reaction is catalyzed by the enzyme sulfotransferase known as rhodanase and may be relevant to detoxification of cyanide in the body.
Organic and transition metal derivatives of the thiocyanate ion can exist as "linkage isomers." In thiocyanates, the organic group (or metal ion) is attached to sulfur: R−S−C≡N has a S-C single bond and a C≡N triple bond. In isothiocyanates, the substituent is attached to nitrogen: R−N=C=S has a S=C double bond and a C=N double bond:
Lewis structures (also known as Lewis dot diagrams, electron dot diagrams, Lewis dot formulas, Lewis dot structures, and electron dot structures) are diagrams that show the bonding between atoms of a molecule and the lone pairs of electrons that may exist in the molecule. A Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. The Lewis structure was named after Gilbert N. Lewis, who introduced it in his 1916 article The Atom and the Molecule. They are similar to electron dot diagrams in that the valence electrons in lone pairs are represented as dots, but they also contain lines to represent shared pairs in a chemical bond (single, double, triple, etc.).
Lewis structures show each atom and its position in the structure of the molecule using its chemical symbol. Lines are drawn between atoms that are bonded to one another (pairs of dots can be used instead of lines). Excess electrons that form lone pairs are represented as pairs of dots, and are placed next to the atoms.
Tom Ricca (born June 7, 1968) is an American professional wrestler, better known by the ring names Tony Ricca and The Pharaoh. He is also the promoter of the New Jersey-based promotion AKW Arena Kaged Wrestling.
Tom Ricca grew up in Hammonton, New Jersey. He trained as a wrestler under Larry Sharpe at the Monster Factory and debuted in November 1990 as one half of the tag team called "The Hammonton Hitmen", with tag team partner Leo Petetti. His debut was an event that help benefit the troops that were serving in the Gulf War. After his debut, Ricca was asked to work independently as "The Hammonton Hitman".
In July 1991, Ricca was asked to wrestle for the World Wrestling Federation. Ricca's WWF Superstars of Wrestling debut as Tony Ricca was on July 29, 1991, against Hacksaw Jim Duggan at the Worcester Centrum in Worcester, Massachusetts. This was a TV taping that aired nationally on August 31, 1991, on Network Television commentated by WWE owner Vince McMahon and Roddy Piper.
A chemical reaction is a process that leads to the transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes may occur.
The substance (or substances) initially involved in a chemical reaction are called reactants or reagents. Chemical reactions are usually characterized by a chemical change, and they yield one or more products, which usually have properties different from the reactants. Reactions often consist of a sequence of individual sub-steps, the so-called elementary reactions, and the information on the precise course of action is part of the reaction mechanism. Chemical reactions are described with chemical equations, which symbolically present the starting materials, end products, and sometimes intermediate products and reaction conditions.
How to make the Pharaoh's Serpent (Mercury (II) Thiocyanate)
Burning Mercury(II) Thiocyanate
Potassium thiocyanate preparation
More Mercury(II) Thiocyanate Decomposition
Making Mercury Thiocyanate (The Pharaoh's Serpent) - Revisited
Iron(III) and Thiocyanate
VCE UNIT 4: Equilibrium Iron Thiocyanate
SCN- Lewis Structure - How to Draw the Lewis Structure for SCN- (Thiocyanate Ion)
The Strangest and Weirdest Chemical Reaction in the World. (Mercury(II) thiocyanate (Hg(SCN)2))
Make mercury (II) thiocyanate
Mercury (II) Thiocyanate Decomposition - Chemical Reaction
The Pharaoh's Serpent in 4K
Tiocianato de Mercurio - Parte 2 Mercury Thiocyanate
Guanidinium thiocyanate
Warning: This experiments requires the handling of dangerous and volatile chemicals. It must only be carried out in a fumehood or outdoors. All chemicals must be disposed of properly. Everything will be contaminated with mercury/mercury salts. NOTHING CAN GO DOWN THE DRAIN OR IN THE GARBAGE. Only carry out this experiment if you can dispose of the chemicals and combustion products properly. Every step of this synthesis deals with dangerous or toxic materials. Gloves, safety glasses and a lab coat are mandatory. Here is a video to show you how volatile elemental mercury is. It lets off a lot of vapor and breathing this must be avoided. https://www.youtube.com/watch?v=lpZF88fqrl8
We react potassium ferrocyanide with sulfur in a classic 'shake and bake' reaction to form potassium thiocyanate, which we extract from the reaction mixture using hot ethanol. After obtaining a pure product we perform some experiments to test its properties.
More Mercury(II) Thiocyanate Decomposition
Hey guys, today we are going to be revisiting the synthesis of mercury thiocyanate. I won't be demonstrating it in the this video. Instead ill have a dedicated one for it soon. This is scaled up 10x compared to my previous one. Old Video: https://www.youtube.com/watch?v=PC3o2KgQstA "Warning: This experiments requires the handling of dangerous and volatile chemicals. It must only be carried out in a fumehood or outdoors. All chemicals must be disposed of properly. Everything will be contaminated with mercury/mercury salts. NOTHING CAN GO DOWN THE DRAIN OR IN THE GARBAGE. Only carry out this experiment if you can dispose of the chemicals and combustion products properly. Every step of this synthesis deals with dangerous or toxic materials. Gloves, safety glasses and a lab coat are man...
An aqueous solution of Fe3+ is placed in a measuring cylinder and potassium thiocyanate is reacted with it. The fake blood demo is also shown.
Support Chemisode: https://www.paypal.me/goudiejason/5 An example of equilibrium changes involving the Iron Thiocyanate equation. Listen to the chemisode podcast : jgoudie.podomatic.com Join the Edmodo group for podcast notes and quizes.
A step-by-step explanation of how to draw the SCN- Lewis Structure (Thiocyanate Ion). The SCN- Lewis structure is a good structure to help you understand why calculating formal charges is important. There are two resonance structures for SCN-. In order to decide which is the predominate form of the molecule we'll need to compare the electronegativity of the Sulfur (S) atom and the Nitrogen (atom). For the SCN- Lewis structure the total number of valence electrons (found on the periodic table) for the SCN- molecule. Once we know how many valence electrons there are in SCN- we can distribute them around the central atom with the goal of filling the outer shells of each atom. Only use the number of available valence electrons we calculated earlier. Also note that you should put the...
Mercury(II) Thiocyanate decomposition is possibly the weirdest chemical reaction in the world. Mercury(II) thiocyanate (Hg(SCN)2) is an inorganic chemical compound, the salt of Hg2+ and the thiocyanate anion. It is a stable solid at room temperature that has the appearance of white powder with chunks; it can also be grey in color, depending on purity. Mercury compounds are extremely toxic and protective equipment should be used whenever working with mercury thiocyanate. However, it is commercially available, though expensive. Mercury thiocyanate is best known for its former use in pyrotechnics, as it will produce a large, winding "snake" when set on fire. This is known as the Pharaoh's Serpent. Though some people still use it for this purpose, it is generally avoided because of the produc...
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Hey guys, finally I got around to burning all the mercury thiocyanate that I made in a previous video. https://www.youtube.com/watch?v=PSDpgBOtSNY I tried to burn it in a few different ways, but the 300+g that I made didn't actually go as far as I thought it would. This video is free to Patreons. All non-synthesis/in-depth videos that I post and not charged to Patreons. First song: Unseen Horrors Kevin MacLeod (incompetech.com) Licensed under Creative Commons: By Attribution 3.0 License http://creativecommons.org/licenses/by/3.0/ Second song: Echoes of Time Kevin MacLeod (incompetech.com) Licensed under Creative Commons: By Attribution 3.0 License http://creativecommons.org/licenses/by/3.0/ Patreon: https://www.patreon.com/user?u=2448989&ty;=h Facebook: https://www.facebook...
Decomposição do Tiocianato de mercúrio
Guanidinium thiocyanate is a chemical compound used as a general protein denaturant, being a chaotropic agent, although it is most commonly used in the extraction of DNA and RNA. Note: this compound may also be recognized as guanidine thiocyanate. This is because guanidinium is the conjugate acid of guanidine and is called the guanidinium cation, [CH6N3]+. This video is targeted to blind users. Attribution: Article text available under CC-BY-SA Creative Commons image source in video
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