Chlorite group

For the chemistry term, see chlorite.

Chlorite group
General
Category	Phyllosilicates
Formula (repeating unit)	(Mg,Fe)3(Si,Al)4O10 (OH)2·(Mg,Fe)3(OH)6
Identification
Color	Various shades of green; rarely yellow, red, or white.
Crystal habit	Foliated masses, scaley aggregates, disseminated flakes.
Crystal system	Monoclinic 2/m; with some triclinic polymorphs.
Cleavage	Perfect 001
Fracture	Lamellar
Mohs scale hardness	2–2.5
Luster	Vitreous, pearly, dull
Streak	Pale green to grey
Specific gravity	2.6–3.3
Refractive index	1.57–1.67
Other characteristics	Folia flexible – not elastic

The chlorites are a group of phyllosilicate minerals. Chlorites can be described by the following four endmembers based on their chemistry via substitution of the following four elements in the silicate lattice; Mg, Fe, Ni, and Mn.

• Clinochlore: (Mg₅Al)(AlSi₃)O₁₀(OH)₈
• Chamosite: (Fe₅Al)(AlSi₃)O₁₀(OH)₈
• Nimite: (Ni₅Al)(AlSi₃)O₁₀(OH)₈
• Pennantite: (Mn,Al)₆(Si,Al)₄O₁₀(OH)₈

In addition, zinc, lithium, and calcium species are known. The great range in composition results in considerable variation in physical, optical, and X-ray properties. Similarly, the range of chemical composition allows chlorite group minerals to exist over a wide range of temperature and pressure conditions. For this reason chlorite minerals are ubiquitous minerals within low and medium temperature metamorphic rocks, some igneous rocks, hydrothermal rocks and deeply buried sediments.

Chlorite structure

The typical general formula is: (Mg,Fe)₃(Si,Al)₄O₁₀(OH)₂·(Mg,Fe)₃(OH)₆. This formula emphasises the structure of the group.

Chlorites have a 2:1 sandwich structure (2:1 sandwich layer = tetrahedral-octahedral-tetrahedral = t-o-t...), this is often referred to as a talc layer. Unlike other 2:1 clay minerals, a chlorite's interlayer space (the space between each 2:1 sandwich filled by a cation) is composed of (Mg²⁺, Fe³⁺)(OH)₆. This (Mg²⁺, Fe³⁺)(OH)₆ unit is more commonly referred to as the brucite-like layer, due to its closer resemblance to the mineral brucite (Mg(OH)₂). Therefore, chlorite's structure appears as follows:

-t-o-t-brucite-t-o-t-brucite ...

An older classification divided the chlorites into two subgroups: the orthochlorites and leptochlorites. The terms are seldom used and the ortho prefix is somewhat misleading as the chlorite crystal system is monoclinic and not orthorhombic.

Occurrence

Quartz crystal with chlorite inclusions from Minas Gerais, Brazil (size: 4.2 × 3.9 × 3.3 cm)

Chlorite is commonly found in igneous rocks as an alteration product of mafic minerals such as pyroxene, amphibole, and biotite. In this environment chlorite may be a retrograde metamorphic alteration mineral of existing ferromagnesian minerals, or it may be present as a metasomatism product via addition of Fe, Mg, or other compounds into the rock mass. Chlorite is a common mineral associated with hydrothermal ore deposits and commonly occurs with epidote, sericite, adularia and sulfide minerals. Chlorite is also a common metamorphic mineral, usually indicative of low-grade metamorphism. It is the diagnostic species of the zeolite facies and of lower greenschist facies. It occurs in the quartz, albite, sericite, chlorite, garnet assemblage of pelitic schist. Within ultramafic rocks, metamorphism can also produce predominantly clinochlore chlorite in association with talc.

Chlorite pseudomorph after garnet from Michigan (size: 3.5 × 3.1 × 2.7 cm)

Experiments indicate that chlorite can be stable in peridotite of the Earth's mantle above the ocean lithosphere carried down by subduction, and chlorite may even be present in the mantle volume from which island arc magmas are generated.

Chlorite occurs naturally in a variety of locations and forms. For example, chlorite is found naturally in certain parts of Wales in mineral schists. Chlorite is found in large boulders scattered on the ground surface on Ring Mountain in Marin County, California.

Members of the chlorite group

Chlorite schist

Baileychlore	(Zn,Fe+2,Al,Mg)6(Al,Si)4O10(O,OH)8
Chamosite	(Fe,Mg)5Al(Si3Al)O10(OH)8
Clinochlore	(Mg,Fe2+)5Al(Si3Al)O10(OH)8
Cookeite	LiAl4(Si3Al)O10(OH)8
Donbassite	Al2[Al2.33][Si3AlO10](OH)8
Gonyerite	(Mn,Mg)5(Fe+3)2Si3O10(OH)8
Nimite	(Ni,Mg,Al)6(Si,Al)4O10(OH)8
Odinite	(Fe,Mg,Al,Fe,Ti,Mn)2.4(Al,Si)2O5OH4
Orthochamosite	(Fe+2,Mg,Fe+3)5Al(Si3Al)O10(O,OH)8
Pennantite	(Mn5Al)(Si3Al)O10(OH)8
Ripidolite	(Mg,Fe,Al)6(Al,Si)4O10(OH)8
Sudoite	Mg2(Al,Fe)3Si3AlO10(OH)8

Clinoclore, pennantite, and chamosite are the most common varieties. Several other sub-varieties have been described. A massive compact variety of clinochlore used as a decorative carving stone is referred to by the trade name seraphinite. It occurs in the Korshunovskoye iron skarn deposit in the Irkutskaya Oblast of Eastern Siberia.

The name chlorite is from the Greek chloros (χλωρός), meaning "green", in reference to its color.

Distinguishing from other minerals

Chlorite is so soft that it can be scratched by a finger nail. The powder generated by scratching is green. It feels oily when rubbed between the fingers. The plates are flexible, but not elastic like mica.

Talc is much softer and feels soapy between fingers. The powder generated by scratching is white.

Mica plates are elastic whereas chlorite plates are flexible without bending back.

See also

• List of minerals
• Thuringite

References

• Cornelius S. Hurlbut and Cornelis Klein, 1985, Manual of Mineralogy, 20th ed., John Wiley and Sons, New York ISBN 0-471-80580-7
• Grove, T; Chatterjee, N; Parman, S; Medard, E (2006). "The influence of H₂O on mantle wedge melting". Earth and Planetary Science Letters 249: 74–89. Bibcode:2006E&PSL.249...74G. doi:10.1016/j.epsl.2006.06.043. 
• Mineral Galleries
• Mindat.org
• Chlorite – Maricopa edu