Quartz
Quartz crystal cluster from Tibet
General
Category	Silicate mineral
Chemical formula	Silica (silicon dioxide, SiO2)
Strunz classification	04.DA.05
Dana classification	75.01.03.01
Crystal symmetry	Trigonal H–M Symbol 32
Unit cell	a = 4.9133 Å, c = 5.4053 Å; Z = 3
Identification
Color	From colorless to black, through various colors
Crystal habit	6-sided prism ending in 6-sided pyramid (typical), drusy, fine-grained to microcrystalline, massive
Crystal system	α-quartz: trigonal trapezohedral class 3 2; β-quartz: hexagonal 622[1]
Twinning	Common Dauphine law, Brazil law and Japan law
Cleavage	{0110} Indistinct
Fracture	Conchoidal
Tenacity	Brittle
Mohs scale hardness	7 – lower in impure varieties (defining mineral)
Luster	Vitreous – waxy to dull when massive
Streak	White
Diaphaneity	Transparent to nearly opaque
Specific gravity	2.65; variable 2.59–2.63 in impure varieties
Optical properties	Uniaxial (+)
Refractive index	nω = 1.543–1.545 nε = 1.552–1.554
Birefringence	+0.009 (B-G interval)
Pleochroism	None
Melting point	1670 °C (β tridymite) 1717 °C (β cristobalite)[1]
Solubility	Insoluble at STP; 1 ppmmass at 400 °C and 34 bar to 2600 ppmmass at 500 °C and 103 bar[1]
Other characteristics	Piezoelectric, may be triboluminescent, chiral (hence optically active if not racemic)
References	[2][3][4][5]

Quartz is an abundant mineral in the Earth's continental crust. It is made up of a continuous framework of SiO₄ silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO₂. There are many different varieties of quartz, several of which are semi-precious gemstones. Throughout the world, varieties of quartz have been, since antiquity, the most commonly used minerals in the making of jewelry and hardstone carvings.

Crystal habit and structure[link]

Quartz belongs to the trigonal crystal system. The ideal crystal shape is a six-sided prism terminating with six-sided pyramids at each end. In nature quartz crystals are often twinned, distorted, or so intergrown with adjacent crystals of quartz or other minerals as to only show part of this shape, or to lack obvious crystal faces altogether and appear massive. Well-formed crystals typically form in a 'bed' that has unconstrained growth into a void, but because the crystals must be attached at the other end to a matrix, only one termination pyramid is present. There are exceptions as doubly terminated crystals do occur. An occurrence in Herkimer County, New York is noted for these Herkimer diamonds with terminations at both ends. A quartz geode is such a situation where the void is approximately spherical in shape, lined with a bed of crystals pointing inward.

α-quartz and β-quartz[link]

Crystal structure of α-quartz

β-quartz

α-quartz crystallizes in the trigonal crystal system, space group P3₁21 or P3₂21. β-quartz belongs to the hexagonal system, space group P6₂22 or P6₄22.^[6] These space groups are truly chiral (they each belong to the 11 enantiomorphous pairs). Both α-quartz and β-quartz are examples of chiral crystal structures composed of achiral building blocks (SiO₄ tetrahedra in the present case). The transformation between α- and β-quartz only involves a comparatively minor rotation of the tetrahedra with respect to one another, without change in the way they are linked, this process is called the quartz inversion.

Occurrence[link]

Quartz is an essential constituent of granite and other felsic igneous rocks. It is very common in sedimentary rocks such as sandstone and shale and is also present in variable amounts as an accessory mineral in most carbonate rocks. It is also a common constituent of schist, gneiss, quartzite and other metamorphic rocks. Because of its resistance to weathering it is very common in stream sediments and in residual soils. Quartz, therefore, occupies the lowest potential to weather in the Goldich dissolution series.

Quartz occurs in hydrothermal veins as gangue along with ore minerals. Large crystals of quartz are found in pegmatites. Well-formed crystals may reach several meters in length and weigh as much as 1,400 pounds (640 kg).^[7]

Naturally occurring quartz crystals of extremely high purity, necessary for the crucibles and other equipment used for growing silicon wafers in the semiconductor industry, are expensive and rare. A major mining location for high purity quartz is the Spruce Pine Gem Mine in Spruce Pine, North Carolina, United States.^[8]

Related silica minerals[link]

Tridymite and cristobalite are high-temperature polymorphs of SiO₂ that occur in high-silica volcanic rocks. Coesite is a denser polymorph of quartz found in some meteorite impact sites and in metamorphic rocks formed at pressures greater than those typical of the Earth's crust. Stishovite and Seifertite are yet denser and higher-pressure polymorphs of quartz found in some meteorite impact sites. Lechatelierite is an amorphous silica glass SiO₂ which is formed by lightning strikes in quartz sand.

Synthetic quartz[link]

Most quartz used in microelectronics is produced synthetically. Large, flawless and untwinned crystals are produced in an autoclave via the hydrothermal process. The process involves treating crushed natural quartz with hot aqueous solution of a base such as sodium hydroxide. The hydroxide serves as a "mineralizer", i.e. it helps dissolve the "nutrient" quartz. High temperatures are required, often around 675 °C. The dissolved quartz then recrystallizes at a seed crystal at slightly lower temperatures. Approximately 200 tons of quartz were produced in the US in 2005; large synthesis facilities exist throughout the world. Synthetic quartz is often evaluated on the basis of its Q factor, a measure of its piezoelectric response and an indicator of the purity of the crystal.^[9]

A synthetic silicon dioxide crystal grown by the hydrothermal method, about 19 cm long and weighing about 127 grams

High-temperature glass composed of silicon dioxide with no (or only small amounts of) other components is referred to as "quartz glass" or fused quartz, although it is amorphous in structure, rather than crystalline.

Uses[link]

Quartz is the source of many silicon compounds such as silicones (e.g. high performance polymers), silicon (e.g. microelectronics), and many other compounds of commercial importance. Quartz in the form of sand is reduced by carbothermic reaction as a first step in these energy-intensive processes.

Owing to its high thermal and chemical stability and abundance, quartz is widely used in many large-scale applications related to abrasives, foundry materials, ceramics, and cements.^[9]

Piezoelectricity[link]

Quartz crystals have piezoelectric properties: they develop an electric potential upon the application of mechanical stress. An early use of this property of quartz crystals was in phonograph pickups. A common piezoelectric use of quartz today is as a crystal oscillator. The quartz clock is a familiar device using the mineral. The resonant frequency of a quartz crystal oscillator is changed by mechanically loading it, and this principle is used for very accurate measurements of very small mass changes in the quartz crystal microbalance and in thin-film thickness monitors. Quartz's piezoelectric properties were discovered by Jacques and Pierre Curie in 1880. The quartz oscillator or resonator was first developed by Walter Guyton Cady in 1921.^[10] George Washington Pierce designed and patented quartz crystal oscillators in 1923.^[11] Warren Marrison created the first quartz oscillator clock based on the work of Cady and Pierce in 1927.^[12]

Gemstone and lapidary varieties[link]

The most important distinction between types of quartz is that of macrocrystalline (individual crystals visible to the unaided eye) and the microcrystalline or cryptocrystalline varieties (aggregates of crystals visible only under high magnification).

Coarsely crystalline varieties[link]

Pure quartz, traditionally called rock crystal (sometimes called clear quartz), is colorless and transparent or translucent. Common colored varieties include citrine, rose quartz, amethyst, smoky quartz and milky quartz.

Citrine[link]

Citrine

Citrine is a variety of quartz whose color ranges from a pale yellow to brown. Natural citrines are rare; most commercial citrines are heat-treated amethyst. Citrine contains traces of Fe³⁺ and is rarely found naturally. The name is derived from Latin citrina which means "yellow".^[13]

Rose quartz[link]

Rose quartz crystals, Minas Gerais

Rose quartz is a type of quartz which exhibits a pale pink to rose red hue. The color is usually considered as due to trace amounts of titanium, iron, or manganese, in the massive material. Some types of quartz contain microscopic rutile needles which produces an asterism in transmitted light. Recent X-ray diffraction studies suggest that the color is due to thin microscopic fibers of possibly dumortierite within the massive quartz.^[14]

In crystal form (rarely found) it is called pink quartz and its color is thought to be caused by trace amounts of phosphate or aluminium. The color in crystals is apparently photosensitive and subject to fading. The first crystals were found in a pegmatite found near Rumford, Maine, US, but most crystals on the market come from Minas Gerais, Brazil.^[15]

Amethyst[link]

Amethyst is a form of quartz that ranges from a bright to dark or dull purple color.

Smoky quartz[link]

Smoky quartz is a gray, translucent version of quartz. It ranges in clarity from almost complete transparency to a brownish-gray crystal that is almost opaque.

Milky quartz[link]

Milky quartz sample

Milky quartz may be the most common variety of crystalline quartz and can be found almost anywhere. The white color may be caused by minute fluid inclusions of gas, liquid, or both, trapped during the crystal formation. The cloudiness caused by the inclusions effectively bars its use in most optical and quality gemstone applications.^[16]

Microcrystalline varieties[link]

The cryptocrystalline varieties are either translucent or mostly opaque, while the transparent varieties tend to be macrocrystalline. Chalcedony is a cryptocrystalline form of silica consisting of fine intergrowths of both quartz, and its monoclinic polymorph moganite.^[17] Other opaque gemstone varieties of quartz, or mixed rocks including quartz, often including contrasting bands or patterns of color, are agate, onyx, carnelian, and jasper.

Varieties (according to microstructure)[link]

Although many of the varietal names historically arose from the color of the mineral, current scientific naming schemes refer primarily to the microstructure of the mineral. Color is a secondary identifier for the cryptocrystalline minerals, although it is a primary identifier for the macrocrystalline varieties. This does not always hold true.

Synthetic and artificial treatments[link]

Not all varieties of quartz are naturally occurring. Prasiolite, an olive colored material, is produced by heat treatment; natural prasiolite has also been observed in Lower Silesia in Poland. Although citrine occurs naturally, the majority is the result of heat-treated amethyst. Carnelian is widely heat-treated to deepen its color.

History of naming and usage[link]

Quartz crystal showing transparency

The word "quartz" is derived from the German word "quarz" and its Middle High German ancestor "twarc", which probably originated in Slavic (cf. Czech tvrdý ("hard"), Polish twardy ("hard")).^[18] Quarz (help·info),^[19] which is of Slavic origin (Czech miners called it křemen). Other sources attribute the word's origin to the Saxon word Querkluftertz, meaning cross-vein ore.^[20]

Quartz is the most common material identified as the mystical substance maban in Australian Aboriginal mythology. It is found regularly in passage tomb cemeteries in Europe in a burial context, such as Newgrange or Carrowmore in the Republic of Ireland. The Irish word for quartz is grian cloch, which means 'stone of the sun'. Quartz was also used in Prehistoric Ireland, as well as many other countries, for stone tools; both vein quartz and rock crystal were knapped as part of the lithic technology of the prehistoric peoples.^[21]

Roman naturalist Pliny the Elder believed quartz to be water ice, permanently frozen after great lengths of time. (The word "crystal" comes from the Greek word κρύσταλλος, "ice".) He supported this idea by saying that quartz is found near glaciers in the Alps, but not on volcanic mountains, and that large quartz crystals were fashioned into spheres to cool the hands. He also knew of the ability of quartz to split light into a spectrum. This idea persisted until at least the 17th century.

In the 17th century, Nicolas Steno's study of quartz paved the way for modern crystallography. He discovered that no matter how distorted a quartz crystal, the long prism faces always made a perfect 60° angle.

Charles B. Sawyer invented the commercial quartz crystal manufacturing process in Cleveland, Ohio, United States. This initiated the transition from mined and cut quartz for electrical appliances to manufactured quartz.

See also[link]

Wikisource has original text related to this article: 1911 Encyclopædia Britannica/Quartz

• Fused quartz
• List of minerals
• Shocked quartz
• Quartz reef mining
• Flint

References[link]

External links[link]

Wikimedia Commons has media related to: Quartz

• Quartz varieties, properties, crystal morphology. Photos and illustrations
• Arkansas quartz, Rockhounding Arkansas
• Gilbert Hart Nomenclature of Silica, American Mineralogist, Volume 12, pages 383–395, 1927
• Queensland University of Technology Origin of the word quartz.
• PDF of Charles Sawyer's cultured quartz process description
• "The Quartz Watch – Inventors". The Lemelson Center, National Museum of American History. Smithsonian Institution. http://invention.smithsonian.org/centerpieces/quartz/inventors/index.html. 
• Terminology used to describe the characteristics of Quartz Crystals when used as oscillators
• A follow-up study of miners exposed to unusual concentrations of quartz by BG Miller and others. Institute of Occupational Medicine Research Report TM/95/03
• Further studies on the importance of quartz in the development of coalworkers’ pneumoconiosis by JMG Davis and others. Institute of Occupational Medicine Research Report TM/91/05

This article needs additional citations for verification. Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed. (March 2008)

Dué le quartz (デュールクォーツ, Dyūru Kuōtsu^?) was a Japanese visual kei rock band that formed in December 1998^[1] and signed to PS Company, a sub-division of Free-Will. The band opened a fanclub on August 1, 2000 that was called "Baby Merry".^[1] After releasing a few albums, several singles and a greatest hits compilation, the group disbanded in 2002. Vocalist Sakito and bassist Kikasa later reunited to form the band Figure: (typeset as 【FIGURe:】) (with drummer Kazuki occasionally providing session work)^[2] and guitarist Miyabi changed his name to "Miyavi" and started a solo career.^[3]

Biography[link]

In December 1998, Sakito and Ken formed Dué le quartz^[4] and played their first live on February 14, 1999.^[1] They recruited bassist Kikasa somewhere in between, officially adding Kazuki to the mix on March 22^[1] of that year.

Ken left the band in May 1999 due to musical differences, leaving the guitarist gap to be filled by Miyabi on June 29, 1999 and complete the band's final lineup.^[5]

They made it big quickly, landing their first one-man live on August 21, 2000 at Shibuya on Air West.^[1] Their first full one-man tour kicked off on May 16, 2001, and their second began on December 4, 2001.^[1]

The band landed the feature spot in the indie publication, Expect Rush I (January 2001) and Expect Rush II (March 2002).^[5]

After a 3 year run, Kikasa announced his withdrawal, which led to complete disbandment in 2002.^[4] They played their last live concert on September 22, 2002 at Akasaka Blitz.

Sakito now is director of an institute in Japan, and be married in November 2010 ^[6]

Members[link]

• Sakito – vocals
• Miyabi – guitar, backing vocals
• Kikasa (キカサ) – bass
• Kazuki – drums

Former members

• Ken – guitar

Discography[link]

Demo tapes

• "Ame to Muchi wo..." (アメと鞭を..., July 19, 2000）)
• "Rob Song" (May 18, 2001)

Albums

• Mikansei no Jekyll to Hyde (未完成のジキルとハイド^?, , November 21, 1999)
• Jisatsu Ganbou (自殺願望, May 28, 2000)
• Rodeo (ロデオ, May 12, 2002)
• Best Album (August 14, 2002, Re-released on November 23, 2005 by King Records)

Singles

• "Dear...from XXX (disc 1)" (January 24, 2001)
• "Dear...from XXX (disc 2)" (January 24, 2001)
• "Bitter" (February 14, 2001)
• "Re:plica" (August 1, 2001)
• "Tribal Arivall Warning!!" (August 16, 2001)
• "Last Title" (September 4, 2002)

Compilations

• Matina Prelude (April 26, 2000, Free-Will)
  • (with the song "Kikai Shikake no Butoukai" (機械仕掛けの舞踏会))

Videos

• Jisatsu Ganbou (自殺願望, July 10, 2000)
• Milk (white) (February 14, 2001, VHS)
• Milk (black) (February 14, 2001, VHS)
• History 1999-2001 (January 7, 2002, VHS)
• Braintine (January 09, 2002, VHS)
• 「6419461049162791」-69 (January 09, 2002, VHS)
• Tour「アメと鞭を...」Final2002.01.07 ( July 3, 2002, VHS)
• Video Clips (July 3, 2002, VHS)
• 1st Oneman Live 2000.8.21 at Shibuya on Air West (TOUR 「合法ドラッグ」 at 渋谷ON AIR WEST, 2003, VHS)

Further reading[link]

• Yun, Josephine Jrock, Ink.: A Concise Report On 40 Of The Biggest Rock Acts In Japan Stone Bridge Press (October 30, 2005) ISBN 1-880656-95-7

References[link]

1. ^ ^{a b c d e f} "Dué le quartz HISTORY 1999-2000" (VHS) PS Company, 2002
2. ^ JAME Figure Profile Retrieved Sep 16 2007
3. ^ Anime News Network Miyavi to Appear at Pacific Media Expo Retrieved Sep 16 2007
4. ^ ^{a b} Yun, Josephine Jrock, Ink.: A Concise Report On 40 Of The Biggest Rock Acts In Japan Stone Bridge Press (October 30, 2005) ISBN 1-880656-95-7
5. ^ ^{a b} Expect Rush II
6. ^ http://www.vkdb.jp/Due%27le+quartz.html

External links[link]

• Kikasa official blog
• Miyavi official website