The magnetic state (or phase) of a material depends on temperature (and other variables such as pressure and applied magnetic field) so that a material may exhibit more than one form of magnetism depending on its temperature, etc.
In ancient China, the earliest literary reference to magnetism lies in a 4th century BCE book called ''Book of the Devil Valley Master'' (鬼谷子): "The lodestone makes iron come or it attracts it." The earliest mention of the attraction of a needle appears in a work composed between AD 20 and 100 (''Louen-heng''): "A lodestone attracts a needle." The ancient Chinese scientist Shen Kuo (1031–1095) was the first person to write of the magnetic needle compass and that it improved the accuracy of navigation by employing the astronomical concept of true north ''(Dream Pool Essays'', AD 1088), and by the 12th century the Chinese were known to use the lodestone compass for navigation. They sculpted a directional spoon from lodestone in such a way that the handle of the spoon always pointed south.
Alexander Neckham, by 1187, was the first in Europe to describe the compass and its use for navigation. In 1269, Peter Peregrinus de Maricourt wrote the ''Epistola de magnete'', the first extant treatise describing the properties of magnets. In 1282, the properties of magnets and the dry compass were discussed by Al-Ashraf, a Yemeni physicist, astronomer, and geographer.
In 1600, William Gilbert published his ''De Magnete, Magneticisque Corporibus, et de Magno Magnete Tellure'' (''On the Magnet and Magnetic Bodies, and on the Great Magnet the Earth''). In this work he describes many of his experiments with his model earth called the terrella. From his experiments, he concluded that the Earth was itself magnetic and that this was the reason compasses pointed north (previously, some believed that it was the pole star (Polaris) or a large magnetic island on the north pole that attracted the compass).
An understanding of the relationship between electricity and magnetism began in 1819 with work by Hans Christian Oersted, a professor at the University of Copenhagen, who discovered more or less by accident that an electric current could influence a compass needle. This landmark experiment is known as Oersted's Experiment. Several other experiments followed, with André-Marie Ampère, who in 1820 discovered that the magnetic field circulating in a closed-path was related to the current flowing through the perimeter of the path; Carl Friedrich Gauss; Jean-Baptiste Biot and Félix Savart, both of which in 1820 came up with the Biot-Savart Law giving an equation for the magnetic field from a current-carrying wire; Michael Faraday, who in 1831 found that a time-varying magnetic flux through a loop of wire induced a voltage, and others finding further links between magnetism and electricity. James Clerk Maxwell synthesized and expanded these insights into Maxwell's equations, unifying electricity, magnetism, and optics into the field of electromagnetism. In 1905, Einstein used these laws in motivating his theory of special relativity, requiring that the laws held true in all inertial reference frames.
Electromagnetism has continued to develop into the 21st century, being incorporated into the more fundamental theories of gauge theory, quantum electrodynamics, electroweak theory, and finally the standard model.
In magnetic materials, sources of magnetization are the electrons' orbital angular motion around the nucleus, and the electrons' intrinsic magnetic moment (see ''electron magnetic dipole moment''). The other sources of magnetism are the nuclear magnetic moments of the nuclei in the material which are typically thousands of times smaller than the electrons' magnetic moments, so they are negligible in the context of the magnetization of materials. Nuclear magnetic moments are important in other contexts, particularly in nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI).
Ordinarily, the enormous number of electrons in a material are arranged such that their magnetic moments (both orbital and intrinsic) cancel out. This is due, to some extent, to electrons combining into pairs with opposite intrinsic magnetic moments as a result of the Pauli exclusion principle (see ''electron configuration''), or combining into filled subshells with zero net orbital motion. In both cases, the electron arrangement is so as to exactly cancel the magnetic moments from each electron. Moreover, even when the electron configuration ''is'' such that there are unpaired electrons and/or non-filled subshells, it is often the case that the various electrons in the solid will contribute magnetic moments that point in different, random directions, so that the material will not be magnetic.
However, sometimes — either spontaneously, or owing to an applied external magnetic field — each of the electron magnetic moments will be, on average, lined up. Then the material can produce a net total magnetic field, which can potentially be quite strong.
The magnetic behavior of a material depends on its structure, particularly its electron configuration, for the reasons mentioned above, and also on the temperature. At high temperatures, random thermal motion makes it more difficult for the electrons to maintain alignment.
:When a material is put in a magnetic field, the electrons circling the nucleus will experience, in addition to their Coulomb attraction to the nucleus, a Lorentz force from the magnetic field. Depending on which direction the electron is orbiting, this force may increase the centripetal force on the electrons, pulling them in towards the nucleus, or it may decrease the force, pulling them away from the nucleus. This effect systematically increases the orbital magnetic moments that were aligned opposite the field, and decreases the ones aligned parallel to the field (in accordance with Lenz's law). This results in a small bulk magnetic moment, with an opposite direction to the applied field.
Note that this description is meant only as an heuristic; a proper understanding requires a quantum-mechanical description.
Note that all materials undergo this orbital response. However, in paramagnetic and ferromagnetic substances, the diamagnetic effect is overwhelmed by the much stronger effects caused by the unpaired electrons.
Every ferromagnetic substance has its own individual temperature, called the Curie temperature, or Curie point, above which it loses its ferromagnetic properties. This is because the thermal tendency to disorder overwhelms the energy-lowering due to ferromagnetic order.
Some well-known ferromagnetic materials that exhibit easily detectable magnetic properties (to form magnets) are nickel, iron, cobalt, gadolinium and their alloys.
left|thumb|200px|Effect of a magnet on the domains.When a domain contains too many molecules, it becomes unstable and divides into two domains aligned in opposite directions so that they stick together more stably as shown at the right.
When exposed to a magnetic field, the domain boundaries move so that the domains aligned with the magnetic field grow and dominate the structure as shown at the left. When the magnetizing field is removed, the domains may not return to an unmagnetized state. This results in the ferromagnetic material's being magnetized, forming a permanent magnet.
When magnetized strongly enough that the prevailing domain overruns all others to result in only one single domain, the material is magnetically saturated. When a magnetized ferromagnetic material is heated to the Curie point temperature, the molecules are agitated to the point that the magnetic domains lose the organization and the magnetic properties they cause cease. When the material is cooled, this domain alignment structure spontaneously returns, in a manner roughly analogous to how a liquid can freeze into a crystalline solid.
In some materials, neighboring electrons want to point in opposite directions, but there is no geometrical arrangement in which ''each'' pair of neighbors is anti-aligned. This is called a spin glass, and is an example of geometrical frustration.
The first discovered magnetic substance, magnetite, was originally believed to be a ferromagnet; Louis Néel disproved this, however, with the discovery of ferrimagnetism.
In a vacuum, : where is the vacuum permeability.
In a material, : The quantity is called ''magnetic polarization''.
If the field is small, the response of the magnetization in a diamagnet or paramagnet is approximately linear: : the constant of proportionality being called the magnetic susceptibility. If so, :
In a hard magnet such as a ferromagnet, is not proportional to the field and is generally nonzero even when is zero (see Remanence).
The phenomenon of magnetism is "mediated" by the magnetic field. An electric current or magnetic dipole creates a magnetic field, and that field, in turn, imparts magnetic forces on other particles that are in the fields.
Maxwell's equations, which simplify to the Biot-Savart law in the case of steady currents, describe the origin and behavior of the fields that govern these forces. Therefore magnetism is seen whenever electrically charged particles are in motion---for example, from movement of electrons in an electric current, or in certain cases from the orbital motion of electrons around an atom's nucleus. They also arise from "intrinsic" magnetic dipoles arising from quantum-mechanical spin.
The same situations that create magnetic fields — charge moving in a current or in an atom, and intrinsic magnetic dipoles — are also the situations in which a magnetic field has an effect, creating a force. Following is the formula for moving charge; for the forces on an intrinsic dipole, see magnetic dipole.
When a charged particle moves through a magnetic field B, it feels a Lorentz force F given by the cross product:
: where : is the electric charge of the particle, and : v is the velocity vector of the particle
Because this is a cross product, the force is perpendicular to both the motion of the particle and the magnetic field. It follows that the magnetic force does no work on the particle; it may change the direction of the particle's movement, but it cannot cause it to speed up or slow down. The magnitude of the force is : where is the angle between v and B.
One tool for determining the direction of the velocity vector of a moving charge, the magnetic field, and the force exerted is labeling the index finger "V", the middle finger "B", and the thumb "F" with your right hand. When making a gun-like configuration, with the middle finger crossing under the index finger, the fingers represent the velocity vector, magnetic field vector, and force vector, respectively. See also right hand rule.
A very common source of magnetic field shown in nature is a dipole, with a "South pole" and a "North pole", terms dating back to the use of magnets as compasses, interacting with the Earth's magnetic field to indicate North and South on the globe. Since opposite ends of magnets are attracted, the north pole of a magnet is attracted to the south pole of another magnet. The Earth's North Magnetic Pole (currently in the Arctic Ocean, north of Canada) is physically a south pole, as it attracts the north pole of a compass.
A magnetic field contains energy, and physical systems move toward configurations with lower energy. When diamagnetic material is placed in a magnetic field, a ''magnetic dipole'' tends to align itself in opposed polarity to that field, thereby lowering the net field strength. When ferromagnetic material is placed within a magnetic field, the magnetic dipoles align to the applied field, thus expanding the domain walls of the magnetic domains.
Nevertheless, some theoretical physics models predict the existence of these magnetic monopoles. Paul Dirac observed in 1931 that, because electricity and magnetism show a certain symmetry, just as quantum theory predicts that individual positive or negative electric charges can be observed without the opposing charge, isolated South or North magnetic poles should be observable. Using quantum theory Dirac showed that if magnetic monopoles exist, then one could explain the quantization of electric charge---that is, why the observed elementary particles carry charges that are multiples of the charge of the electron.
Certain grand unified theories predict the existence of monopoles which, unlike elementary particles, are solitons (localized energy packets). The initial results of using these models to estimate the number of monopoles created in the big bang contradicted cosmological observations — the monopoles would have been so plentiful and massive that they would have long since halted the expansion of the universe. However, the idea of inflation (for which this problem served as a partial motivation) was successful in solving this problem, creating models in which monopoles existed but were rare enough to be consistent with current observations.
According the Heitler-London theory, so-called two-body molecular -orbitals are formed, namely the resulting orbital is:
:
Here the last product means that a first electron, r1, is in an atomic hydrogen-orbital centered at the second nucleus, whereas the second electron runs around the first nucleus. This "exchange" phenomenon is an expression for the quantum-mechanical property that particles with identical properties cannot be distinguished. It is specific not only for the formation of chemical bonds, but as we will see, also for magnetism, i.e. in this connection the term exchange interaction arises, a term which is essential for the origin of magnetism, and which is stronger, roughly by factors 100 and even by 1000, than the energies arising from the electrodynamic dipole-dipole interaction.
As for the ''spin function'' , which is responsible for the magnetism, we have the already mentioned Pauli's principle, namely that a symmetric orbital (i.e. with the + sign as above) must be multiplied with an antisymmetric spin function (i.e. with a - sign), and ''vice versa''. Thus: :,
I.e., not only and must be substituted by ''α'' and ''β'', respectively (the first entity means "spin up", the second one "spin down"), but also the sign + by the − sign, and finally ri by the discrete values ''s''i (= ±½); thereby we have and . The "singlet state", i.e. the - sign, means: the spins are ''antiparallel'', i.e. for the solid we have antiferromagnetism, and for two-atomic molecules one has diamagnetism. The tendency to form a (homoeopolar) chemical bond (this means: the formation of a ''symmetric'' molecular orbital , i.e. with the + sign) results through the Pauli principle automatically in an ''antisymmetric'' spin state (i.e. with the - sign). In contrast, the Coulomb repulsion of the electrons, i.e. the tendency that they try to avoid each other by this repulsion, would lead to an ''antisymmetric'' orbital function (i.e. with the - sign) of these two particles, and complementary to a ''symmetric'' spin function (i.e. with the + sign, one of the so-called "triplet functions"). Thus, now the spins would be ''parallel'' (ferromagnetism in a solid, paramagnetism in two-atomic gases).
The last-mentioned tendency dominates in the metals iron, cobalt and nickel, and in some rare earths, which are ''ferromagnetic''. Most of the other metals, where the first-mentioned tendency dominates, are ''nonmagnetic'' (e.g. sodium, aluminium, and magnesium) or ''antiferromagnetic'' (e.g. manganese). Diatomic gases are also almost exclusively diamagnetic, and not paramagnetic. However, the oxygen molecule, because of the involvement of π-orbitals, is an exception important for the life-sciences.
The Heitler-London considerations can be generalized to the Heisenberg model of magnetism (Heisenberg 1928).
The explanation of the phenomena is thus essentially based on all subtleties of quantum mechanics, whereas the electrodynamics covers mainly the phenomenology.
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