In chemistry, an alcohol is any organic compound in which a hydroxyl functional group (-OH) is bound to a carbon atom, usually connected to other carbon or hydrogen atoms.
An important class are the simple acyclic alcohols, the general formula for which is CnH2n+1OH. Of those, ethanol (C2H5OH) is the type of alcohol found in alcoholic beverages, and in common speech the word alcohol refers specifically to ethanol.
Other alcohols are usually described with a clarifying adjective, as in ''isopropyl alcohol'' (''propan-2-ol'') or ''wood alcohol'' (''methyl alcohol'', or methanol). The suffix ''-ol'' appears in the IUPAC chemical name of all substances where the hydroxyl group is the functional group with the highest priority; in substances where a higher priority group is present the prefix ''hydroxy-'' will appear in the IUPAC name. The suffix ''-ol'' in non-systematic names (such as paracetamol or cholesterol) also typically indicates that the substance includes a hydroxyl functional group and, so, can be termed an alcohol. But many substances (such as citric acid, lactic acid, and sucrose) contain one or more hydroxyl functional groups without using the suffix.
The simplest alcohol is methanol, , which was formerly obtained by the distillation of wood and, therefore, is called "wood alcohol". It is a clear liquid resembling ethanol in smell and properties, with a slightly lower boiling point (64.7 °C), and is used mainly as a solvent, fuel, and raw material. Unlike ethanol, methanol is extremely toxic: One sip (as little as 10 ml) can cause permanent blindness by destruction of the optic nerve and 30 ml (one fluid ounce) is potentially fatal.
Two other alcohols whose uses are relatively widespread (though not so much as those of methanol and ethanol) are propanol and butanol. Like ethanol, they can be produced by fermentation processes. (However, the fermenting agent is a bacterium, ''Clostridium acetobutylicum'', that feeds on cellulose, not sugars like the Saccharomyces yeast that produces ethanol.) Saccharomyces yeast are known to produce these higher alcohols at temperatures above . These alcohols are called fusel alcohols or fusel oils in brewing and tend to have a spicy or peppery flavor. They are considered a fault in most styles of beer.
Simple alcohols, in particular, ethanol and methanol, possess denaturing and inert rendering properties, leading to their use as anti-microbial agents in medicine, pharmacy, and industry.
The IUPAC nomenclature is used in scientific publications and where precise identification of the substance is important. In other less formal contexts, an alcohol is often called with the name of the corresponding alkyl group followed by the word "alcohol", e.g., methyl alcohol, ethyl alcohol. Propyl alcohol may be ''n''-propyl alcohol or isopropyl alcohol, depending on whether the hydroxyl group is bonded to the 1st or 2nd carbon on the propane chain.
Alcohols are classified into ''primary'', ''secondary'', and ''tertiary'', based upon the number of carbon atoms connected to the carbon atom that bears the hydroxyl group. The primary alcohols have general formulas RCH2OH; secondary ones are RR'CHOH; and tertiary ones are RR'R"COH, where R, R', and R" stand for alkyl groups. Ethanol and ''n''-propyl alcohol are primary alcohols; isopropyl alcohol is a secondary one. The prefixes ''sec''- (or ''s''-) and ''tert''- (or ''t''-), conventionally in italics, may be used before the alkyl group's name to distinguish secondary and tertiary alcohols, respectively, from the primary one. For example, isopropyl alcohol is occasionally called ''sec''-propyl alcohol, and the tertiary alcohol (CH3)3COH, or 2-methylpropan-2-ol in IUPAC nomenclature is commonly known as ''tert''-butyl alcohol or ''tert''-butanol.
! Chemical Formula | ! IUPAC Name | ! Common Name |
CH3OH | Methanol | Wood alcohol |
C2H5OH | Ethanol | Grain alcohol |
C3H7OH | Isopropyl alcohol | Rubbing alcohol |
C5H11OH | Pentanol | Amyl alcohol |
C16H33OH | Hexadecan-1-ol | Cetyl alcohol |
C2H4(OH)2 | Ethane-1,2-diol | Ethylene glycol |
C3H5(OH)3 | Propane-1,2,3-triol | Glycerin |
C4H6(OH)4 | Butane-1,2,3,4-tetraol | Erythritol |
C5H7(OH)5 | Pentane-1,2,3,4,5-pentol | Xylitol |
C6H8(OH)6 | Hexane-1,2,3,4,5,6-hexol | Mannitol, Sorbitol |
C7H9(OH)7 | Heptane-1,2,3,4,5,6,7-heptol | Volemitol |
C3H5OH | Prop-2-ene-1-ol | Allyl alcohol |
C10H17OH | 3,7-Dimethylocta-2,6-dien-1-ol | Geraniol |
C3H3OH | Prop-2-in-1-ol | Propargyl alcohol |
C6H6(OH)6 | Cyclohexane-1,2,3,4,5,6-geksol | Inositol |
C10H19OH | 2 - (2-propyl)-5-methyl-cyclohexane-1-ol | Menthol |
'''' is Arabic for the definitive article, ''the'' in English.
The current Arabic name for alcohol is '''', re-introduced from western usage.
'''' was the name given to the very fine powder, produced by the sublimation of the natural mineral stibnite to form antimony sulfide Sb2S3 (hence the essence or "spirit" of the substance), which was used as an antiseptic and eyeliner.
Bartholomew Traheron in his 1543 translation of John of Vigo introduces the word as a term used by "barbarous" (Moorish) authors for "fine powder": :''the barbarous auctours use alcohol, or (as I fynde it sometymes wryten) alcofoll, for moost fine poudre.''
William Johnson in his 1657 ''Lexicon Chymicum'' glosses the word as ''antimonium sive stibium''. By extension, the word came to refer to any fluid obtained by distillation, including "alcohol of wine", the distilled essence of wine. Libavius in ''Alchymia'' (1594) has ''vini alcohol vel vinum alcalisatum''. Johnson (1657) glosses ''alcohol vini'' as ''quando omnis superfluitas vini a vino separatur, ita ut accensum ardeat donec totum consumatur, nihilque fæcum aut phlegmatis in fundo remaneat.'' The word's meaning became restricted to "spirit of wine" (ethanol) in the 18th century, and was again extended to the family of substances so called in modern chemistry from 1850.
In general, the hydroxyl group makes the alcohol molecule polar. Those groups can form hydrogen bonds to one another and to other compounds (except in certain large molecules where the hydroxyl is protected by steric hindrance of adjacent groups). This hydrogen bonding means that alcohols can be used as protic solvents. Two opposing solubility trends in alcohols are: the tendency of the polar OH to promote solubility in water, and the tendency of the carbon chain to resist it. Thus, methanol, ethanol, and propanol are miscible in water because the hydroxyl group wins out over the short carbon chain. Butanol, with a four-carbon chain, is moderately soluble because of a balance between the two trends. Alcohols of five or more carbons (Pentanol and higher) are effectively insoluble in water because of the hydrocarbon chain's dominance. All simple alcohols are miscible in organic solvents.
Because of hydrogen bonding, alcohols tend to have higher boiling points than comparable hydrocarbons and ethers. The boiling point of the alcohol ethanol is 78.29 °C, compared to 69 °C for the hydrocarbon Hexane (a common constituent of gasoline), and 34.6 °C for Diethyl ether.
Alcohols, like water, can show either acidic or basic properties at the O-H group. With a pKa of around 16-19, they are, in general, slightly weaker acids than water, but they are still able to react with strong bases such as sodium hydride or reactive metals such as sodium. The salts that result are called alkoxides, with the general formula RO- M+.
Meanwhile, the oxygen atom has lone pairs of nonbonded electrons that render it weakly basic in the presence of strong acids such as sulfuric acid. For example, with methanol:
Alcohols can also undergo oxidation to give aldehydes, ketones, or carboxylic acids, or they can be dehydrated to alkenes. They can react to form ester compounds, and they can (if activated first) undergo nucleophilic substitution reactions. The lone pairs of electrons on the oxygen of the hydroxyl group also makes alcohols nucleophiles. For more details, see the reactions of alcohols section below.
As one moves from primary to secondary to tertiary alcohols with the same backbone, the hydrogen bond strength, the boiling point, and the acidity typically decrease.
Some alcohols, mainly ethanol and methanol, can be used as an alcohol fuel. Fuel performance can be increased in forced induction internal combustion engines by injecting alcohol into the air intake after the turbocharger or supercharger has pressurized the air. This cools the pressurized air, providing a denser air charge, which allows for more fuel, and therefore more power.
Alcohols have applications in industry and science as reagents or solvents. Because of its low toxicity and ability to dissolve non-polar substances, ethanol can be used as a solvent in medical drugs, perfumes, and vegetable essences such as vanilla. In organic synthesis, alcohols serve as versatile intermediates.
Ethanol can be used as an antiseptic to disinfect the skin before injections are given, often along with iodine. Ethanol-based soaps are becoming common in restaurants and are convenient because they do not require drying due to the volatility of the compound. Alcohol is also used as a preservative for specimens.
Alcohol gels have become common as hand sanitizers.
==Laboratory synthesis== Several methods exist for the preparation of alcohols in the laboratory.
The formation of a secondary alcohol via reduction and hydration is shown: :
==Reactions==
: 2 R-OH + 2 NaH → 2 R-O-Na+ + 2H2↑
: 2 R-OH + 2 Na → 2 R-O−Na+ + H2
: 2 CH3CH2-OH + 2 Na → 2 CH3-CH2-O−+ + H2↑
Water is similar in pKa to many alcohols, so with sodium hydroxide there is an equilibrium set-up, which usually lies to the left:
: R-OH + NaOH ⇌ R-O-Na+ + H2O (equilibrium to the left)
It should be noted, however, that the bases used to deprotonate alcohols are strong themselves. The bases used and the alkoxides created are both highly moisture-sensitive chemical reagents.
The acidity of alcohols is also affected by the overall stability of the alkoxide ion. Electron-withdrawing groups attached to the carbon containing the hydroxyl group will serve to stabilize the alkoxide when formed, thus resulting in greater acidity. On the other hand, the presence of electron-donating group will result in a less stable alkoxide ion formed. This will result in a scenario whereby the unstable alkoxide ion formed will tend to accept a proton to reform the original alcohol.
With alkyl halides alkoxides give rise to ethers in the Williamson ether synthesis.
Alcohols may, likewise, be converted to alkyl bromides using hydrobromic acid or phosphorus tribromide, for example:
: 3 R-OH + PBr3 → 3 RBr + H3PO3
In the Barton-McCombie deoxygenation an alcohol is deoxygenated to an alkane with tributyltin hydride or a trimethylborane-water complex in a radical substitution reaction.
More useful is the E1 elimination reaction of alcohols to produce alkenes. The reaction, in general, obeys Zaitsev's Rule, which states that the most stable (usually the most substituted) alkene is formed. Tertiary alcohols eliminate easily at just above room temperature, but primary alcohols require a higher temperature.
This is a diagram of acid catalysed dehydration of ethanol to produce ethene:
A more controlled elimination reaction is the Chugaev elimination with carbon disulfide and iodomethane.
: R-OH + R'-COOH → R'-COOR + H2O
In order to drive the equilibrium to the right and produce a good yield of ester, water is usually removed, either by an excess of H2SO4 or by using a Dean-Stark apparatus. Esters may also be prepared by reaction of the alcohol with an acid chloride in the presence of a base such as pyridine.
Other types of ester are prepared in a similar manner — for example, tosyl (tosylate) esters are made by reaction of the alcohol with p-toluenesulfonyl chloride in pyridine.
The direct oxidation of primary alcohols to carboxylic acids normally proceeds via the corresponding aldehyde, which is transformed via an ''aldehyde hydrate'' (R-CH(OH)2) by reaction with water before it can be further oxidized to the carboxylic acid.
Reagents useful for the transformation of primary alcohols to aldehydes are normally also suitable for the oxidation of secondary alcohols to ketones. These include Collins reagent and Dess-Martin periodinane. The direct oxidation of primary alcohols to carboxylic acids can be carried out using Potassium permanganate or the Jones reagent.
Ethanol in alcoholic beverages has been consumed by humans since prehistoric times for a variety of hygienic, dietary, medicinal, religious, and recreational reasons. The consumption of large doses of ethanol causes drunkenness (intoxication), which may lead to a hangover as its effects wear off. Depending upon the dose and the regularity of its consumption, ethanol can cause acute respiratory failure or death. Because ethanol impairs judgment in humans, it can be a catalyst for reckless or irresponsible behavior. The of ethanol in rats is 10.3 g/kg.
Other alcohols are substantially more poisonous than ethanol, partly because they take much longer to be metabolized and partly because their metabolism produces substances that are even more toxic. Methanol (wood alcohol), for instance, is oxidized to formaldehyde and then to the poisonous formic acid in the liver by alcohol dehydrogenase and formaldehyde dehydrogenase enzymes, respectively; accumulation of formic acid can lead to blindness or death. Likewise, poisoning due to other alcohols such as ethylene glycol or diethylene glycol are due to their metabolites, which are also produced by alcohol dehydrogenase. An effective treatment to prevent toxicity after methanol or ethylene glycol ingestion is to administer ethanol. Alcohol dehydrogenase has a higher affinity for ethanol, thus preventing methanol from binding and acting as a substrate. Any remaining methanol will then have time to be excreted through the kidneys.
Methanol itself, while poisonous, has a much weaker sedative effect than ethanol. Some longer-chain alcohols such as n-propanol, isopropanol, n-butanol, t-butanol, and 2-methyl-2-butanol do, however, have stronger sedative effects, but also have higher toxicity than ethanol. These longer chain alcohols are found as contaminants in some alcoholic beverages and are known as fusel alcohols, and are reputed to cause severe hangovers although it is unclear if the fusel alcohols are actually responsible. Many longer chain alcohols are used in industry as solvents and are occasionally abused by alcoholics, leading to a range of adverse health effects.
* Category:Antiseptics Category:Arabic loanwords Category:Functional groups Category:Iranian inventions
af:Alkohol ar:كحول an:Alcohol ast:Alcohol bn:অ্যালকোহল be:Спірты be-x-old:Сьпірт bs:Alkohol bg:Алкохол ca:Alcohol cs:Alkoholy cy:Alcohol da:Alkohol (stofklasse) de:Alkohole et:Alkoholid el:Αλκοόλες es:Alcohol eo:Alkoholo eu:Alkohol fa:الکل fo:Alkohol fr:Alcool (chimie) gd:Alcol gl:Alcohol ko:알코올 hi:एल्कोहॉल hr:Alkoholi io:Alkoholo id:Alkohol ia:Alcohol is:Alkóhól it:Alcoli he:כוהל jv:Alkohol kk:Алкогольдер sw:Alkoholi ht:Alkòl ku:Alkol la:Alcohol lv:Spirti lt:Alkoholis ln:Lotoko lmo:Alcol hu:Alkoholok mk:Алкохол ml:ചാരായം (രസതന്ത്രം) ms:Alkohol nl:Alcohol (stofklasse) ja:アルコール no:Alkoholer nn:Alkohol oc:Alcòl pnb:الکحل nds:Alkohol pl:Alkohole pt:Álcool ro:Alcool qu:Alkul ru:Спирты sq:Alkoholet scn:Alcool simple:Alcohol sk:Alkohol (hydroxyderivát) sl:Alkohol ckb:ئەلکول sr:Алкохол sh:Alkoholi su:Alkohol fi:Alkoholi sv:Alkoholer tl:Alkohol ta:மதுசாரம் te:ఆల్కహాలు th:แอลกอฮอล์ chy:Manestôtse tr:Alkol uk:Спирти ur:الکحل vi:Ancol vls:Alcool war:Alkohol yi:אלקאהאל yo:Ọtí zh-yue:酒精 bat-smg:Alkuoguolis zh:醇This text is licensed under the Creative Commons CC-BY-SA License. This text was originally published on Wikipedia and was developed by the Wikipedia community.
Coordinates | 34°03′″N118°15′″N |
---|---|
name | Brad Paisley| image Paisley, Brad (2007) 2.jpg |
landscape | yes |
background | solo_singer |
birth name | Brad Douglas Paisley |
birth date | October 28, 1972 |
origin | Glen Dale, West Virginia,United States |
instrument | Vocals, guitar, mandolin |
genre | Country |
occupation | Singer-songwriter, musician |
years active | 1997–present |
spouse | Kimberly Williams-Paisley |
label | Arista Nashville |
associated acts | Alison Krauss, Dolly Parton, Carrie Underwood, Keith Urban, Martina McBride, Chely Wright |
website | BradPaisley.com |
notable instruments | Bill Crook TelecastersFender Telecasters }} |
Paisley was the 2008 CMA and ACM Male Vocalist of the Year winner. Starting with the release of his 1999 album ''Who Needs Pictures'', Paisley has recorded seven studio albums and a Christmas compilation on the Arista Nashville label, with all of his albums certified gold or higher by the RIAA. In addition, he has charted 25 singles on the U.S. ''Billboard'' Hot Country Songs chart, 16 of which have reached #1 with a record 10 consecutive singles reaching the top spot on the chart. On November 10, 2010, Paisley won the Entertainer of the Year award at the 44th annual CMA Awards.
Paisley graduated from John Marshall High School in Glen Dale, West Virginia in 1991, studied for 2 years at West Liberty University (WV) and later was awarded a full-paid ASCAP scholarship to Belmont University, in Nashville, Tennessee (from 1993 to 1995). He interned at ASCAP, Atlantic Records, and the Fitzgerald-Hartley management firm. While in college, he met Frank Rogers, a fellow student who went on to serve as his producer. Paisley also met Kelley Lovelace, who became his songwriting partner. He also met Chris DuBois in college, and he too would write songs for him.
In 2000, Paisley's mainstream notoriety received a huge boost when he was exposed to his first national non-country music oriented audience on the TLC special, "Route 66: Main Street America." Producer, Todd Baker, tapped the young musician to appear on this show when he was a relative unknown outside the world of country music. It featured Paisley and band doing rare live and acoustic versions of Route 66. The international and home video versions of this program end with a full, un-cut acoustic rendition of the piece, which was performed live on Rainbow Bridge in Riverton, KS. The show accurately predicted that Paisley would become a legendary musician, and also featured blues artist, Buddy Guy.
Later in 2000, Paisley won the Country Music Association's (CMA) Horizon Award and the Academy of Country Music's best new male vocalist trophy. He received his first Grammy Award nomination a year later for Best New Artist. On February 17, 2001, Paisley was inducted into the Grand Ole Opry He was 28 when he accepted the invitation, and was the youngest member ever to join. PBS did a 75th anniversary concert special, which saw Paisley pair up with Chely Wright and sing a song called ''Hard to Be a Husband, Hard to Be a Wife'', and would be included on the album ''Backstage at the Opry'', It would get a CMA nomination for Vocal Event of the Year.
In addition, the ninth track from ''Mud on the Tires'', "Whiskey Lullaby", a duet with Alison Krauss reached #3 on the Billboard Hot Country Singles & Tracks (now Hot Country Songs) charts, and #41 on the Billboard Hot 100. The music video for ''Whiskey Lullaby'' also won several awards and was rated #2 on the 100 Greatest Music Videos by CMT in 2008. The album would be certified double platinum. "Online" featured the Brentwood High School marching band playing toward the end of the song, a cameo by Jason Alexander, and again featured a cameo by William Shatner. ''Throttleneck'' would also reach number one, which would get Paisley his first Grammy.
The fifth single from ''5th Gear'' actually came from a reissued version of the album – a new recording of "Waitin' on a Woman", a track cut from ''Time Well Wasted.'' The reissued version received unsolicited airplay in late 2006, and features less prominent string guitar and violin parts and a more "muted" musical tone. For the chart week of September 20, 2008, the song became Paisley's twelfth number-one single and his eighth straight number-one hit, making him the artist with the most consecutive Number One country hits since the inception of Nielsen SoundScan in 1990.
In July 2006, producer Todd Baker tapped Brad for a television appearance as an animated character in The Wonder Pets, Daddy Armadillo. The yet-to-be-broadcast episode features Brad's wife, Kimberly Williams, as Mama Armadillo.
Paisley toured April 26, 2007 through February 24, 2008 in support of ''5th Gear'' on the Bonfires & Amplifiers Tour. The tour visited 94 cities over a 10 month period and played for over 1,000,000 fans. The tour was so successful that it was extended past its original end date to February 2008. Some of the opening acts who appeared during the tour were Taylor Swift, Kellie Pickler, Jack Ingram, Rodney Atkins and Chuck Wicks.
Paisley was nominated for three 2008 Grammy Awards related to ''5th Gear'': Best Country Album (for ''5th Gear''), Best Country Collaboration (for "Oh Love" with Carrie Underwood), and Best Country Instrumental (for "Throttleneck"). On February 10, 2008, he won his first Grammy award for Best Country Instrumental for "Throttleneck".
In March 2008, Brad Paisley announced his next tour, "The Paisley Party," a 42-date tour sponsored by Hershey's. The tour kicked off on June 11, 2008, in Albuquerque, New Mexico with Chuck Wicks, Julianne Hough and Jewel as the opening acts. Brad Paisley and Keith Urban released to country radio their first duet together on September 8, 2008, "Start a Band." It was the first and only single from ''Play,'' and it went on to become Paisley's thirteenth number one hit and his ninth in a row. The album also features collaborations with James Burton, Little Jimmy Dickens, Vince Gill, John Jorgenson, B.B. King, Albert Lee, Brent Mason, Buck Owens, Redd Volkaert and Steve Wariner. Paisley and Urban both received Entertainer of the Year nominations from the CMA on September 10, 2008. On November 12, 2008 Brad Paisley won Male Vocalist of the Year and Music Video of the Year for "Waitin' on a Woman" during the CMA's.
On May 6, 2009, Paisley gave an exclusive performance to a small group of members from his fan club in Studio A of the Grand Ole Opry in Nashville, TN as he and his band taped an episode of CMT Invitation Only. The show gives fans a chance to see their favorite artists in a more intimate setting up close and personal. There was a Q & A session and interaction between Paisley and his fans. The show aired on Monday, August 3 at 9:00 p.m. on CMT.
On July 21, 2009, Paisley performed at the White House in celebration of country music. "Country Music at the White House " was streamed live on the White House web-site as well as a special on Great American Country.
On November 11, 2009, Paisley co-hosted the CMA Awards for the second straight year. He also performed "Welcome to the Future", and won both Male Vocalist of the Year and Musical Event of the Year for Start a Band with Keith Urban.
On March 1, 2010, Paisley was the first musical performance with "American Saturday Night" for the second tenure of the Tonight Show with Jay Leno.
On Friday March 5, 2010, Paisley slipped and fell performing his last song of the set, "Alcohol," at a concert at the North Charleston Coliseum in Charleston, South Carolina, on the final date of the American Saturday Night Tour. Fearing a broken rib, he was held overnight at an area hospital, but was released when a CT scan was negative.
On July 31, 2010 Brad performed alongside Carrie Underwood at the inaugural Greenbrier Classic PGA Tour Event in Lewisburg, W.Va. An estimated 60,000 people attended the out door event to watch Carrie and Brad perform in the pouring rain.
On August 4, 2010, it was announced on his official website that Paisley would release his first official greatest hits package, entitled ''Hits Alive''. Released on November 2, 2010, ''Hits Alive'' is a double-disc collection, with one disc containing studio versions of Paisley's hit singles, while the companion disc features previously unreleased live versions of his songs.
Brad Paisley cohosted the 44th Annual CMA Awards on November 10, 2010, where he was also awarded the CMA's top award, Entertainer of the Year. During his acceptance speech, Paisley emotionally honored his grandfather, who inspired him to play the guitar.
On March 22, 2011, Paisley's website announced a new beta game titled "Brad Paisley World." The game is modeled after other Facebook games such as Farmville or Mafia Wars and features original animation. The game provides a new way for fans to interact with each other and view exclusive material that would otherwise be unavailable.
On May 12, 2011, Paisley's website announced that he would release two songs on the soundtrack for the film ''Cars 2''. One of them would be a collaboration with British pop singer Robbie Williams.
In 2001, Paisley began dating Kimberly Williams. Williams appeared in a video for the song, "I'm Gonna Miss Her (The Fishin' Song)," in 2002, the last release from his ''Part II'' album. The two married on March 15, 2003, at Stauffer Chapel on the campus of Pepperdine University after a nine month engagement.
They live in Franklin, Tennessee, and have another home in Malibu.
Their first son, William Huckleberry, or "Huck", was born on February 22, 2007, in Nashville, Tennessee. Their second son, Jasper Warren (named after his grandfather who bought Brad his first guitar), was born on April 17, 2009.
Paisley is a member of the Southern Jurisdiction of the Scottish Rite of Freemasonry, and a Noble of the AAONMS, also known as Shriners. He was accompanied by his father, Doug Paisley (32º), for the ceremony on October 28, 2006.
He is also a lifelong fan of the Cleveland Browns. Paisley sang the national anthem before a game during the 1999 season, and stated in an interview, with ESPN his dream job would be to play football for them. He also invited former Browns Quarterback Brady Quinn to a concert at the Blossom Music Center, in 2008.
Paisley is also a fan of West Virginia University athletics and the Boston Red Sox.
In fall of 2009, it was announced in ''Variety'' that Paisley would enter the world of scripted television as an executive producer of a new hour-long drama series for The CW network called, appropriately, ''Nashville''. The plot was written and created by Neal Dodson and Matt Bomer (an actor on the USA Network series, ''White Collar''). The creator of the series ''One Tree Hill'', Mark Schwahn will direct the pilot and oversee the series. ''Star Trek'' and ''Heroes'' actor Zachary Quinto is also an executive producer on the series, along with Dodson, Bomer, and Corey Moosa.
As of July 2010, the series is not on the CW's fall schedule or mid-season schedule for 2010–2011 and the status of the project is unknown.
In 2010, Paisley was named a "Citizen of the Next Century" by Future-ish for his song "Welcome to the Future".
;Compilations
Category:1972 births Category:American guitarists Category:American songwriters Category:American country guitarists Category:American country singers Category:American singer-songwriters Category:American country songwriters Category:American male singer-songwriters Category:American country singer-songwriters Category:American male singers Category:American people of Scottish descent Category:Arista Records artists Category:Belmont University alumni Category:Grammy Award winners Category:Grand Ole Opry members Category:Living people Category:Lead guitarists Category:People from Marshall County, West Virginia Category:Musicians from West Virginia
de:Brad Paisley fr:Brad Paisley it:Brad Paisley nl:Brad Paisley ja:ブラッド・ペイズリー pl:Brad Paisley pt:Brad Paisley ru:Пейсли, Брэд simple:Brad Paisley sv:Brad Paisley tr:Brad Paisley vi:Brad PaisleyThis text is licensed under the Creative Commons CC-BY-SA License. This text was originally published on Wikipedia and was developed by the Wikipedia community.
Coordinates | 34°03′″N118°15′″N |
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name | Jim Breuer |
birth name | Jim Breuer |
birth date | June 21, 1967 |
birth place | Valley Stream, Long Island, New York |
medium | Stand-up, television, film, radio |
nationality | American |
active | 1988–present |
genre | Observational comedy, improvisational comedy, character comedy |
subject | Everyday life, marriage, parenting, self-deprecation |
influences | George Carlin, Sam Kinison, Steve Martin, Bill Cosby, Richard Pryor |
spouse | Dee Breuer (1993–present; 3 children) |
notable work | ''Saturday Night Live''''Half Baked''''Premium Blends'' ''Web Junk 20''''Fridays with Not funny'' |
website | jimbreuer.com |
footnotes | }} |
Among his impersonations was that of actor Joe Pesci, who hosted his own talk show, often accompanied by Colin Quinn playing fellow actor Robert De Niro. In a 1997 episode of the program, both Pesci and De Niro made surprise appearances to "confront" Breuer.
Jim Breuer has also hosted several "Premium Blends" on Comedy Central as well as several appearances on other comedy shows.
Jim Breuer hosted the third season of the VH1 show ''Web Junk 20''. The season began on November 17, 2006. He replaced Patrice Oneal, who hosted the first two seasons of the show.
In 2002, Jim Breuer's first one-hour Comedy Central special, "Hardcore," premiered. The same year, he released a comedy album titled ''Smoke 'n' Breu''.
On July 25, 2009, Jim Breuer's second one-hour Comedy Central special, "Let's Clear the Air," premiered and came in as one of the highest rated comedy specials in Comedy Central's history.
Jim Breuer currently appears in Pizza Hut commercials, advertising the cheese crust-filled pizzas using the catch phrase, "Jackpot!"
Also, Breuer starred in the VH1 documentary "When Metallica Ruled the World" where he commented on the songs by Metallica through the years.
Breuer is the host of ''Fridays with Jim Breuer,'' (previously known as ''Breuer Unleashed'') which can be heard each Friday afternoon from 4-6PM (EST) on the Sirius Satellite Radio channel "Raw Dog Comedy." He credits Joe Pesci with jump starting his career as he mentions in his comedy concert "Hardcore". One show, while Breuer was singing the classic Judas Priest song "Devil's Child," Rob Halford "The Metal God," singer of Judas Priest, entered the studio still with his coat on and sang with him.
He appeared on The Howard Stern show on August 19, 2010 as Joe Pesci for the entirety of the show with the exception of the news.
On October 5, 2010 he published a book called ''"I'm Not High (But I've Got a Lot of Crazy Stories about Life as a Goat Boy, a Dad, and a Spiritual Warrior)".''
In January 2011, Jim launched a podcast called "The Podcast Masters" with fellow comedian Pete Correale.
This text is licensed under the Creative Commons CC-BY-SA License. This text was originally published on Wikipedia and was developed by the Wikipedia community.
Coordinates | 34°03′″N118°15′″N |
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Name | Jamie Foxx |
Birth name | Eric Marlon Bishop |
Birth date | December 13, 1967 |
Birth place | Terrell, Texas, United States |
Medium | Stand up, Film, Television, Radio, Music |
Nationality | American |
Active | 1989–present |
Associated acts | Kanye West, T.I., Keyshia Cole |
Genre | Musical comedy, Political satire, Observational comedy, Character comedy, Black comedy |
Subject | Race relations, Racism, African-American culture, Celebrities, Human sexuality, American politics, Current events, Self-deprecation |
Occupation | Singer, Actor, Rapper, Comedian |
Notable work | Law Abiding CitizenJamie King on The Jamie Foxx ShowRay Charles in RayNico in Rio |
Working with | Flo Rida, Kanye West, A-Trak, KiD CuDi |
Website | Official site }} |
Born in Terrell, Texas, Foxx was raised by his mother's adoptive parents. He performed in high school and was awarded with a scholarship to United States International University. In his twenties, Foxx began performing stand-up at comedy clubs, and eventually joined the cast of ''In Living Color'' in 1991; this exposure helped him land film roles and star in his own sitcom, ''The Jamie Foxx Show''. He released his debut album, ''Peep This'', in 1994, but he did not gain significant musical success until 2004 when he was featured in Twista's song "Slow Jamz". Also in 2004, Foxx played critically acclaimed roles in the films ''Collateral'' and ''Ray''. He released his second album, ''Unpredictable'', in 2005, which was helped by his collaboration on Kanye West's number-one single "Gold Digger". His third album ''Intuition'' was released in 2008 and was anchored by the single "Blame It". Foxx released his fourth studio album, ''Best Night of My Life'', in 2010.
Foxx attended Terrell High School, where he received top grades, played basketball and football as quarterback, and had an ambition to play for the Dallas Cowboys. He was the first player in the school's history to pass for more than 1,000 yards. He also sang in a band called Leather and Lace. After completing high school, Foxx received a scholarship to United States International University, where he studied classical music and composition. He has often acknowledged his grandmother's influence in his life as one of the greatest reasons for his success.
Foxx is the second male in history to receive two acting Oscar nominations in the same year for two different movies, ''Collateral'' and ''Ray''. The only other male actor to achieve this was Al Pacino. In 2005, Foxx was invited to join the Academy of Motion Picture Arts and Sciences.
Following these successes, Foxx appeared in ''Jarhead'', ''Miami Vice'', and ''Dreamgirls'', which were box-office hits, and lifted his profile even higher as a bankable star in Hollywood. 2007 brought him the lead role in the film ''The Kingdom'' opposite Chris Cooper, Jason Bateman, Jennifer Garner and Ashraf Barhom.
In September 2007, Foxx was awarded a star on the Hollywood Walk of Fame. He said, upon receiving the honor, "[it was] one of the most amazing days of my life."
In April 2009, Foxx played the lead role in the dramatic film ''The Soloist''. A few months later in October 2009, He played a starring role along side Gerard Butler in the thriller Law Abiding Citizen. In April 2011, Foxx voiced Nico, a canary in the movie ''Rio''.
In 2011, Foxx was officially cast in the title role of, Django Unchained. It will be written and directed by Quentin Tarantino, and he will star alongside Christoph Waltz, Leonardo DiCaprio, Samuel L. Jackson, and Kevin Costner.
Foxx released his second studio album, ''Unpredictable'', in December 2005. It debuted at number two, selling 598,000 copies in its first week. The following week, the album rose to number one, selling an additional 200,000 copies. To date, the album has sold 1.98 million copies in the United States, and was certified double Platinum by the RIAA. The album also charted on the UK Albums Chart, where it peaked at number nine. Foxx became the fourth artist to have won an Academy Award for an acting role and to have achieved a number-one record album in the US. (The other three to accomplish this feat were Frank Sinatra, Bing Crosby, and Barbra Streisand.) Foxx's first single from the album, the title track "Unpredictable" (featuring Ludacris), samples "Wildflower" by New Birth. The song peaked inside the top 10 of the Billboard Hot 100 and also made the UK top 20 singles chart. The second US single from the album was "DJ Play a Love Song," which reunited Foxx with Twista. In the UK, however, the second single was "Extravaganza," which saw Foxx once again collaborate with Kanye West. He was not, however, featured in the song's music video.
At the 2006 Black Entertainment Television (BET) Awards, Foxx won Best Duet/Collaboration with Kanye West for "Gold Digger" and tied with Mary J. Blige's "Be Without You" for Video of the year. On December 8, 2006, Foxx received four Grammy nominations, which included Best R&B; Performance by a Duo or Group with Vocals for ''Love Changes'' featuring Mary J. Blige, Best R&B; Album for ''Unpredictable'', Best Rap Performance by a Duo or Group for ''Georgia'' by Ludacris & Field Mob featuring Jamie Foxx, and Best Rap/Sung Collaboration for ''Unpredictable'' featuring Ludacris.
On January 22, 2007, Foxx was on Sirius Satellite Radio, announcing his new channel The Foxxhole. The channel features talk-radio programs, stand-up comedy albums, and music primarily by African-American performers, and features much of Foxx's own material as well. ''The Jamie Foxx Show'', Foxx's own talk-radio variety program, airs Friday evenings on The Foxxhole, and features Johnny Mack, Speedy, The Poetess, Lewis Dix, and T.D.P., as his co-hosts. Guests include popular musicians, actors, and fellow comedians.
He recorded a song with country superstars Rascal Flatts entitled "She Goes All the Way" for their album, ''Still Feels Good''. Foxx also performed background vocals for artist/songwriter Tank. He and The-Dream are featured on Plies' "Please Excuse My Hands." He also appeared on the remix of Ne-Yo's "Miss Independent" entitled "She Got Her Own." The track also features Fabolous. Foxx then collaborated with rapper The Game on the track "Around The World."
Foxx released his third album titled ''Intuition'' in 2008, featuring such artists as Kanye West, T.I., Lil Wayne, and T-Pain. The album's first single, "Just Like Me" featuring T.I., was promoted by a video directed by Brett Ratner and featuring an appearance by Taraji P. Henson. The second single "Blame It" featured T-Pain and became a top 5 single on the Billboard Hot 100 and a number-one single on the Billboard Hot R&B;/Hip-Hop Songs chart. The "Blame It" music video, directed by Hype Williams, features cameo appearances by Forest Whitaker, Samuel L. Jackson, Ron Howard, Quincy Jones, and Jake Gyllenhaal, among others. Foxx was also featured on T.I.'s single "Live in the Sky" from the album ''King''.
On April 6, 2009 Foxx performed the George Strait song "You Look So Good in Love" at the George Strait Artist of the Decade All-Star Concert. Foxx has been a fan of country music for many years.
Jamie Foxx hosted the 2009 BET Awards ceremony on June 28, 2009, which featured several tributes to pop star Michael Jackson, who had died three days prior to the show. Aside from performing "Blame It" with T-Pain and "She Got Her Own" with Ne-Yo and Fabolous, Foxx opened the show with a rendition of Jackson's "Beat It" dance routine and closed the show with a cover of The Jackson 5's "I'll Be There" with Ne-Yo. Foxx stated during the ceremony, "We want to celebrate this black man. He belongs to us and we shared him with everybody else."
Foxx released his fourth album, ''Best Night of My Life'', on December 21, 2010. The first single is "Winner", featuring Justin Timberlake and T.I.. The second single is "Living Better Now" featuring rapper Rick Ross and the third single is "Fall For Your Type" featuring rapper Drake.
Foxx has a daughter, Corinne Bishop, who was born in 1994. Former ''Jamie Foxx Show'' co-star Garcelle Beauvais-Nilon made a public announcement on ''The Wendy Williams Show'' stating that Foxx has a second child. Foxx was spotted with the baby in Miami for New Year's Eve 2010, and it was revealed to be a girl.
Foxx performed a public service announcement for Do Something to promote food drives in local communities.
In April 2003, Foxx was involved in an incident with two police officers who were attempting to escort him and his sister out of Harrah's casino in New Orleans. Employees claimed they had failed to show identification upon entry. Originally charged with trespassing, disturbing the peace, battery on police officers and resisting arrest, Foxx pleaded no contest to disturbing the peace in exchange for the other charges being dropped, and was sentenced to a six month suspended jail term with two years probation and a $1500 fine.
Category:1967 births Category:Actors from Texas Category:African American film actors Category:African American comedians Category:American adoptees Category:American male singers Category:American stand-up comedians Category:American comedy musicians Category:American television actors Category:American voice actors Category:BAFTA winners (people) Category:Best Actor BAFTA Award winners Category:Best Actor Academy Award winners Category:Best Musical or Comedy Actor Golden Globe (film) winners Category:Living people Category:People from Linden, Texas Category:People from the Dallas – Fort Worth Metroplex Category:African American television actors Category:Grammy Award winners Category:United States International University alumni
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