Enriched uranium is a kind of uranium in which the percent composition of uranium-235 has been increased through the process of isotope separation. Natural uranium is 99.284% 238U isotope, with 235U only constituting about 0.711% of its weight. 235U is the only nuclide existing in nature (in any appreciable amount) that is fissile with thermal neutrons.
Enriched uranium is a critical component for both civil nuclear power generation and military nuclear weapons. The International Atomic Energy Agency attempts to monitor and control enriched uranium supplies and processes in its efforts to ensure nuclear power generation safety and curb nuclear weapons proliferation.
During the Manhattan Project enriched uranium was given the codename oralloy, a shortened version of Oak Ridge alloy, after the location of the plants where the uranium was enriched. The term oralloy is still occasionally used to refer to enriched uranium. There are about 2,000 tonnes (t, Mg) of highly enriched uranium in the world, produced mostly for nuclear weapons, naval propulsion, and smaller quantities for research reactors.
The 238U remaining after enrichment is known as depleted uranium (DU), and is considerably less radioactive than even natural uranium, though still very dense and extremely hazardous in granulated form—such granules are a natural by-product of the shearing action that makes it useful for armour-penetrating weapons, and radiation shielding. At present, 95% of the world's stocks of depleted uranium remain in secure storage.
''Slightly enriched uranium'' (SEU) has a 235U concentration of 0.9% to 2%. This new grade is being used to replace natural uranium (NU) fuel in some heavy water reactors like the CANDU. Costs are lowered because less uranium and fewer bundles are needed to fuel the reactor. This in turn reduces the quantity of used fuel and its subsequent waste management costs.
''Reprocessed uranium'' (RpU or RU) is a product of nuclear fuel cycles involving nuclear reprocessing of spent fuel. RpU recovered from light water reactor (LWR) spent fuel typically contains slightly more U-235 than natural uranium, and therefore could be used to fuel reactors that customarily use natural uranium as fuel. It also contains the undesirable isotope uranium-236 which undergoes neutron capture, wasting neutrons (and requiring higher U-235 enrichment) and creating neptunium-237 which would be one of the more mobile and troublesome radionuclides in deep geological repository disposal of nuclear waste.
Highly enriched uranium (HEU) has a greater than 20% concentration of 235U or 233U. The fissile uranium in nuclear weapons usually contains 85% or more of 235U known as weapon(s)-grade, though for a crude, inefficient weapon 20% is sufficient (called weapon(s)-usable); some argue that even less is sufficient, but then the critical mass for unmoderated fast neutrons rapidly increases, approaching infinity at 6%235U. For criticality experiments, enrichment of uranium to over 97% has been accomplished.
The very first uranium bomb, Little Boy in 1945, used 64 kilograms of 80% enriched uranium. Wrapping the weapon's fissile core in a neutron reflector (which is standard on all nuclear explosives) can dramatically reduce the critical mass. Because the core was surrounded by a good neutron reflector, at explosion it comprised almost 2.5 critical masses. Neutron reflectors and compressing the fissile core via implosion allow nuclear weapon designs that use less than what would be one bare-sphere critical mass at normal density. The presence of too much of the 238U isotope inhibits the runaway nuclear chain reaction that is responsible for the weapon's power. The critical mass for 85% highly enriched uranium is about , which at normal density would be a sphere about in diameter.
Later US nuclear weapons usually use plutonium-239 in the primary stage, but the secondary stage which is compressed by the primary nuclear explosion often uses HEU with enrichment between 40% and 80% along with the fusion fuel lithium deuteride. For the secondary of a large nuclear weapon, the higher critical mass of less-enriched uranium can be an advantage as it allows the core at explosion time to contain a larger amount of fuel. The 238U is not fissile but still fissionable by fusion neutrons.
HEU is also used in fast neutron reactors, whose cores require about 20% or more of fissile material, as well as in naval reactors, where it often contains at least 50% 235U, but typically does not exceed 90%. The Fermi-1 commercial fast reactor prototype used HEU with 26.5% 235U. Significant quantities of HEU are used in the production of medical isotopes, for example molybdenum-99 for technetium-99m generators.
There are currently two generic commercial methods employed internationally for enrichment: gaseous diffusion (referred to as ''first'' generation) and gas centrifuge (''second'' generation) which consumes only 6% as much energy as gaseous diffusion. Later generation methods will become established because they will be more efficient in terms of the energy input for the same degree of enrichment and the next method of enrichment to be commercialized will be referred to as ''third'' generation. Some work is being done that would use nuclear resonance; however there is no reliable evidence that any nuclear resonance processes have been scaled up to production.
Gaseous diffusion is a technology used to produce enriched uranium by forcing gaseous uranium hexafluoride (''hex'') through semi-permeable membranes. This produces a slight separation between the molecules containing 235U and 238U. Throughout the Cold War, gaseous diffusion played a major role as a uranium enrichment technique, and as of 2008 accounted for about 33% of enriched uranium production, but is now an obsolete technology that is steadily being replaced by the later generations of technology as the diffusion plants reach their ends-of-life.
The gas centrifuge process uses a large number of rotating cylinders in series and parallel formations. Each cylinder's rotation creates a strong centrifugal force so that the heavier gas molecules containing 238U move toward the outside of the cylinder and the lighter gas molecules rich in 235U collect closer to the center. It requires much less energy to achieve the same separation than the older gaseous diffusion process, which it has largely replaced and so is the current method of choice and is termed ''second generation''. It has a separation factor per stage of 1.3 relative to gaseous diffusion of 1.005, which translates to about one-fiftieth of the energy requirements. Gas centrifuge techniques produce about 54% of the world's enriched uranium.
The Zippe centrifuge is an improvement on the standard gas centrifuge, the primary difference being the use of heat. The bottom of the rotating cylinder is heated, producing convection currents that move the 235U up the cylinder, where it can be collected by scoops. This improved centrifuge design is used commercially by Urenco to produce nuclear fuel and was used by Pakistan in their nuclear weapons program.
Aerodynamic enrichment processes include the Becker jet nozzle techniques developed by E. W. Becker and associates using the LIGA process and the vortex tube separation process. These aerodynamic separation processes depend upon diffusion driven by pressure gradients, as does the gas centrifuge. In effect, aerodynamic processes can be considered as non-rotating centrifuges. Enhancement of the centrifugal forces is achieved by dilution of UF6 with hydrogen or helium as a carrier gas achieving a much higher flow velocity for the gas than could be obtained using pure uranium hexafluoride. The Uranium Enrichment Corporation of South Africa (UCOR) developed and deployed the Helikon vortex separation process based on the vortex tube and a demonstration plant was built in Brazil by NUCLEI, a consortium led by Industrias Nucleares do Brasil that used the separation nozzle process. However both methods have high energy consumption and substantial requirements for removal of waste heat; neither is currently in use.
In the electromagnetic isotope separation process (EMIS), metallic uranium is first vaporized, and then ionized to positively charged ions. The cations are then accelerated and subsequently deflected by magnetic fields onto their respective collection targets. A production-scale mass spectrometer named the Calutron was developed during World War II that provided some of the 235U used for the Little Boy nuclear bomb, which was dropped over Hiroshima in 1945. Properly the term 'Calutron' applies to a multistage device arranged in a large oval around a powerful electromagnet. Electromagnetic isotope separation has been largely abandoned in favour of more effective methods.
The work necessary to separate a mass of feed of assay into a mass of product assay , and tails of mass and assay is given by the expression
:
where is the value function, defined as
:
The feed to product ratio is given by the expression
:
whereas the tails to product ratio is given by the expression
:
For example, beginning with of NU, it takes about 61 SWU to produce of LEU in 235U content to 4.5%, at a tails assay of 0.3%.
The number of separative work units provided by an enrichment facility is directly related to the amount of energy that the facility consumes. Modern gaseous diffusion plants typically require 2,400 to 2,500 kilowatt-hours (kW·h), or 8.6–9 gigajoules, (GJ) of electricity per SWU while gas centrifuge plants require just 50 to 60 kW·h (180–220 MJ) of electricity per SWU.
''Example:''
A large nuclear power station with a net electrical capacity of 1300 MW requires about 25 tonnes per year (25 t/a) of LEU with a 235U concentration of 3.75%. This quantity is produced from about 210 t of NU using about 120 kSWU. An enrichment plant with a capacity of 1000 kSWU/a is, therefore, able to enrich the uranium needed to fuel about eight large nuclear power stations.
Cost issues
In addition to the separative work units provided by an enrichment facility, the other important parameter to be considered is the mass of natural uranium (NU) that is needed to yield a desired mass of enriched uranium. As with the number of SWUs, the amount of feed material required will also depend on the level of enrichment desired and upon the amount of 235U that ends up in the depleted uranium. However, unlike the number of SWUs required during enrichment which increases with decreasing levels of 235U in the depleted stream, the amount of NU needed will decrease with decreasing levels of 235U that end up in the DU.
For example, in the enrichment of LEU for use in a light water reactor it is typical for the enriched stream to contain 3.6% 235U (as compared to 0.7% in NU) while the depleted stream contains 0.2% to 0.3% 235U. In order to produce one kilogram of this LEU it would require approximately 8 kilograms of NU and 4.5 SWU if the DU stream was allowed to have 0.3% 235U. On the other hand, if the depleted stream had only 0.2% 235U, then it would require just 6.7 kilograms of NU, but nearly 5.7 SWU of enrichment. Because the amount of NU required and the number of SWUs required during enrichment change in opposite directions, if NU is cheap and enrichment services are more expensive, then the operators will typically choose to allow more 235U to be left in the DU stream whereas if NU is more expensive and enrichment is less so, then they would choose the opposite.
==Downblending== The opposite of enriching is downblending; surplus HEU can be downblended to LEU to make it suitable for use in commercial nuclear fuel.
The HEU feedstock can contain unwanted uranium isotopes: 234U is a minor isotope contained in natural uranium; during the enrichment process, its concentration increases but remains well below 1%. High concentrations of 236U are a byproduct from irradiation in a reactor and may be contained in the HEU, depending on its manufacturing history. HEU reprocessed from nuclear weapons material production reactors (with an 235U assay of approx. 50%) may contain 236U concentrations as high as 25%, resulting in concentrations of approximately 1.5% in the blended LEU product. 236U is a neutron poison; therefore the actual 235U concentration in the LEU product must be raised accordingly to compensate for the presence of 236U.
The blendstock can be NU, or DU, however depending on feedstock quality, SEU at typically 1.5 wt% 235U may used as a blendstock to dilute the unwanted byproducts that may contained in the HEU feed. Concentrations of these isotopes in the LEU product in some cases could exceed ASTM specifications for nuclear fuel, if NU, or DU were used. So, the HEU downblending generally cannot contribute to the waste management problem posed by the existing large stockpiles of depleted uranium.
A major downblending undertaking called the Megatons to Megawatts Program converts ex-Soviet weapons-grade HEU to fuel for U.S. commercial power reactors. From 1995 through mid-2005, 250 tonnes of high-enriched uranium (enough for 10,000 warheads) was recycled into low-enriched-uranium. The goal is to recycle 500 tonnes by 2013. The decommissioning programme of Russian nuclear warheads accounted for about 13% of total world requirement for enriched uranium leading up to 2008.
The United States Enrichment Corporation has been involved in the disposition of a portion of the 174.3 tonnes of highly enriched uranium (HEU) that the U.S. government declared as surplus military material in 1996. Through the U.S. HEU Downblending Program, this HEU material, taken primarily from dismantled U.S. nuclear warheads, was recycled into low-enriched uranium (LEU) fuel, used by nuclear power plants to generate electricity.
Category:Isotope separation Category:Nuclear fuels Uranium, Enriched Category:Uranium
af:Uraanverryking ar:يورانيوم مخصب ca:Urani enriquit de:Uran-Anreicherung es:Enriquecimiento de uranio fa:غنیسازی اورانیوم fr:Enrichissement de l'uranium ko:농축 우라늄 hi:संवर्धित यूरेनियम is:Auðgað úran it:Uranio arricchito he:אורניום מועשר hu:Dúsított urán ml:സമ്പുഷ്ട യുറേനിയം nl:Verrijkt uranium ja:濃縮ウラン pl:Uran wzbogacony pt:Urânio enriquecido ru:Обогащение урана sv:Urananrikning th:ยูเรเนียมเสริมสมรรถนะ tr:Zenginleştirilmiş uranyum zh:濃縮鈾This text is licensed under the Creative Commons CC-BY-SA License. This text was originally published on Wikipedia and was developed by the Wikipedia community.
Name | Sam Cooke |
---|---|
Background | solo_singer |
Birth name | Samuel Cook |
Alias | Dale Cook |
Born | January 22, 1931Clarksdale, Mississippi, U.S. |
Origin | Chicago, Illinois, U.S. |
Died | December 11, 1964Los Angeles, California, U.S.
Interred: Forest Lawn Memorial Park, Glendale, California |
Genre | R&B;, soul, gospel, pop |
Occupation | Singer-songwriter, entrepreneur |
Instrument | Vocals, piano, guitar |
Years active | 1950–1964 |
Label | Specialty, Keen, RCA |
Associated acts | The Soul StirrersBobby WomackJohnnie Taylor }} |
Cooke had 29 top-40 hits in the U.S. between 1957 and 1964. Major hits like "You Send Me", "A Change Is Gonna Come", "Cupid", "Chain Gang", "Wonderful World", and "Bring It on Home to Me" are some of his most popular songs. Cooke was also among the first modern black performers and composers to attend to the business side of his musical career. He founded both a record label and a publishing company as an extension of his careers as a singer and composer. He also took an active part in the American Civil Rights Movement.
On December 11, 1964, Cooke was fatally shot by the manager of the Hacienda Motel in Los Angeles, California, at the age of 33. At the time, the courts ruled that Cooke was drunk and distressed, and that the manager had killed Cooke in what was later ruled a justifiable homicide. Since that time, the circumstances of his death have been widely questioned.
Cooke began his career singing gospel with his siblings in a group called ''The Singing Children''. He first became known as lead singer with the Highway QC's as a teenager. In 1950, Cooke replaced gospel tenor R.H. Harris as lead singer of the landmark gospel group The Soul Stirrers. Under Cooke's leadership, the group signed with Specialty Records and recorded the hits "Peace in the Valley", "How Far Am I From Canaan?", "Jesus Paid the Debt", and "One More River", among many other gospel songs.
In 1957, Cooke appeared on ABC's ''The Guy Mitchell Show''. That same year, he signed with Keen Records. His first release "You Send Me", (the B-side of a reworking of George Gershwin's "Summertime") spent six weeks at #1 on the Billboard R&B; chart. The song also had mainstream success, spending three weeks at #1 on the Billboard pop chart.
In 1961, Cooke started his own record label, SAR Records, with J.W. Alexander and his manager, Roy Crain. The label soon included The Simms Twins, The Valentinos, Bobby Womack, and Johnnie Taylor. Cooke then created a publishing imprint and management firm, then left Keen to sign with RCA Victor. One of his first RCA singles was the hit "Chain Gang". It reached #2 on the Billboard pop chart and was followed by more hits, including "Sad Mood", "Bring it on Home to Me" (with Lou Rawls on backing vocals), "Another Saturday Night" and "Twistin' the Night Away".
Like most R&B; artists of his time, Cooke focused on singles; in all he had twenty-nine top-40 hits on the pop charts, and more on the R&B; charts. In spite of this, he released a well received blues-inflected LP in 1963, ''Night Beat'', and his most critically acclaimed studio album ''Ain't That Good News'', which featured five singles, in 1964.
Some posthumous releases followed, many of which became hits, including "A Change Is Gonna Come", an early protest song that is generally regarded as his greatest composition. After Cooke's death, his widow, Barbara, married Bobby Womack. Cooke's daughter, Linda, later married Bobby's brother, Cecil.
According to Franklin and the motel's owner, Evelyn Carr (whose last name is identified by some sources as ''Card'', rather than ''Carr''), they had been on the telephone together at the time of the incident. Thus, Carr claimed to have overheard Cooke's intrusion and the ensuing conflict and gunshots. Carr called the police to request that they go to the motel, informing them that she believed a shooting had occurred.
A coroner's inquest was convened to investigate the incident. The woman who had accompanied Cooke to the motel was identified as Elisa Boyer, who had also called the police that night shortly before Carr. Boyer had called the police from a telephone booth near the motel, telling them she had just escaped being kidnapped.
Boyer told the police that she had first met Cooke earlier that night and had spent the evening in his company. She claimed that after they left a local nightclub together, she had repeatedly requested that he take her home, but he instead took her against her will to the Hacienda Motel. She claimed that once in one of the motel's rooms, Cooke physically forced her onto the bed and that she was certain he was going to rape her. According to Boyer, when Cooke stepped into the bathroom for a moment, she quickly grabbed her clothes and ran from the room. She claimed that in her haste, she had also scooped up most of Cooke's clothing by mistake. She said that she ran first to the manager's office and knocked on the door seeking help. However, she said that the manager took too long in responding, so, fearing Cooke would soon be coming after her, she fled the motel altogether before the manager ever opened the door. She claimed she then put her own clothing back on, hid Cooke's clothing, and went to the telephone booth from which she called police.
Boyer's story is the only account of what happened between the two that night; however, her story has long been called into question. Inconsistencies between her version of events and details reported by other witnesses, as well as circumstantial evidence (e.g., thousands in cash that Cooke was reportedly carrying was never recovered, and Boyer was soon after arrested for prostitution), invited speculation that Boyer may have gone willingly to the motel with Cooke, then slipped out of the room with Cooke's clothing in order to rob him, rather than to escape an attempted rape.
Such questions were ultimately deemed beyond the scope of the inquest, whose purpose was to establish the circumstances of Franklin's role in the shooting, not to determine precisely what had transpired between Cooke and Boyer preceding the event. Boyer's leaving the motel room with almost all of Cooke's clothing, regardless of exactly why she did so, combined with the fact that tests showed Cooke was inebriated at the time, provided what inquest jurors deemed a plausible explanation for Cooke's bizarre behavior and state of dress, as reported by Franklin and Carr. This explanation, in conjunction with the fact that Carr's testimony corroborated Franklin's version of events, and the fact that police officials testified that both Boyer and Franklin had passed lie detector tests, was enough to convince the coroner's jury to accept Franklin's explanation, and return a verdict of justifiable homicide. With that verdict, authorities officially closed the case on Cooke's death.
Some of Cooke's family and supporters, however, have rejected Boyer's version of events, as well as those given by Franklin and Carr. They believe that there was a conspiracy to murder Cooke and that the murder took place in some manner entirely different from the three official accounts. In her autobiography, ''Rage to Survive'', singer Etta James claimed that she viewed Cooke's body in the funeral home and that the injuries she observed were well beyond what could be explained by the official account of Franklin alone having fought with Cooke. James described Cooke as having been so badly beaten that his head was nearly separated from his shoulders, his hands were broken and crushed, and his nose mangled.
No concrete evidence supporting a conspiracy theory has been presented to date.
Rapper Tupac Shakur references Cooke in a line of the song "Thugz Mansion", and Nas references him in the song "We Major" with Kanye West. The Roots' song "Stay Cool" suggests, "I got the soul of a young Sam Cooke." The Irish rock-group Jetplane Landing have a song named "Sam Cooke". Canadian punk band The Riptides pay homage to Cooke in "Change Gonna Come". Steve Perry makes reference to Cooke's tragic death in "Captured by the Moment".
The Night Beats, a band from Seattle Washington, claim to have borrowed their name from Cooke's album ''Night Beat''.
He is once again mentioned by Nas on the song "Blunt Ashes". The rapper talks about the marriage between Bobby Womack and Sam Cooke's widow, suggesting Cooke’s discontent with the affair in the afterlife.
Rock star Rod Stewart once revealed to VH-1 that as a teen in the UK, he would lock himself in his room and spend hours studying Cooke's vocal phrasings.
A fictional version of Cooke (portrayed by Paul Mooney) appeared briefly in the 1978 film, ''The Buddy Holly Story'', leaving the stage at the Apollo Theater before Buddy and The Crickets went on. After being featured prominently in the 1985 film ''Witness'', the song "Wonderful World" gained further exposure. "Wonderful World" was featured in one of two concurrently running Levi's Jeans commercials in 1985 and became a hit in the United Kingdom because of this, reaching #2 in re-release. Two of Cooke's songs, "Cupid" and "Twistin' the Night Away" were also prominently featured in the 1987 movie, ''Innerspace''. Other movies that featured his music are ''Animal House'' ("Wonderful World" and "Twistin' the Night Away"), ''An American Werewolf in London'', and ''Cadence'' ("Chain Gang").
Cooke's songs "Bring It on Home to Me" and "A Change is Gonna Come" were both featured in the 2001 film ''Ali''. The opening scene of the movie consisted of a live reenactment of "Bring It on Home to Me". Al Green's cover of "A Change Is Gonna Come" is featured during the death scene of Malcolm X.
Alternative rock band The Wallflowers song "Sleepwalker" from their 2000 album (Breach) featured the lyric "Cupid don't draw back your bow/Sam Cooke didn't know what I know." The words are a reference to Cooke's song, "Cupid".
John Cougar Mellencamp's song "Ain't Even Done With the Night" contains the line "You got your hands in my back pockets, and Sam Cooke's singin' on the radio."
R. Kelly performed "A Change Gonna Come", during the Ladies Make Some Noise Tour in September 2009 in New York City.
Colin Meloy of The Decemberists released a tour-only EP entitled ''Colin Meloy Sings Sam Cooke''. The album was released to accompany his 2008 solo tour, and features five cover songs. "Cupid", "Summertime", "Thats Where Its At", "Good Times", and "Bring it on Home to Me".
The song was featured in Tyler Perry's 2007 film Daddy's Little Girls.
Matt Embree frequently covers "Bring It On Home" at RX Bandits live shows.
Category:1931 births Category:1964 deaths Category:1964 crimes in the United States Category:African American singers Category:American gospel singers Category:American male singers Category:American soul musicians Category:Specialty Records artists Category:RCA Victor artists Category:African Americans' rights activists Category:Burials at Forest Lawn Memorial Park (Glendale) Category:Musicians from Chicago, Illinois Category:Deaths by firearm in California Category:Grammy Lifetime Achievement Award winners Category:Musicians from Mississippi Category:Murdered African-American people Category:Murdered musicians Category:People from Clarksdale, Mississippi Category:People from Chicago, Illinois Category:Rock and Roll Hall of Fame inductees Category:Songwriters Hall of Fame inductees
bg:Сам Кук cy:Sam Cooke da:Sam Cooke de:Sam Cooke es:Sam Cooke fr:Sam Cooke it:Sam Cooke he:סם קוק hu:Sam Cooke nl:Sam Cooke ja:サム・クック no:Sam Cooke pl:Sam Cooke pt:Sam Cooke ro:Sam Cooke ru:Кук, Сэм simple:Sam Cooke fi:Sam Cooke sv:Sam Cooke th:แซม คุก tr:Sam Cooke uk:Сем Кук vi:Sam Cooke yo:Sam CookeThis text is licensed under the Creative Commons CC-BY-SA License. This text was originally published on Wikipedia and was developed by the Wikipedia community.
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