Paint is any liquid, liquefiable, or mastic composition which after application to a substrate in a thin layer is converted to an opaque solid film. One may also consider the digital mimicry thereof. It is most commonly used to protect, color or provide texture to objects.
Ancient colored walls at Dendera, Egypt, which were exposed for years to the elements, still possess their brilliant color, as vivid as when they were painted about 2,000 years ago. The Egyptians mixed their colors with a gummy substance, and applied them separate from each other without any blending or mixture. They appeared to have used six colors: white, black, blue, red, yellow, and green. They first covered the area entirely with white then traced the design in black, leaving out the lights of the ground color. They used minium for red, and generally of a dark tinge.
Pliny mentions some painted ceilings in his day in the town of Ardea, which had been done prior to the foundation of Rome. He expresses great surprise and admiration at their freshness, after the lapse of so many centuries.
Paint was made with the yolk of eggs and therefore, the substance would harden and stick onto the surface it is applied to. Pigments were made from plants, sands, and different soil types.
Pigments are granular solids incorporated into the paint to contribute color, toughness, texture, give the paint some special properties or simply to reduce the cost of the paint. Alternatively, some paints contain dyes instead of or in combination with pigments.
Pigments can be classified as either natural or synthetic types. Natural pigments include various clays, calcium carbonate, mica, silicas, and talcs. Synthetics would include engineered molecules, calcined clays, blanc fixe, precipitated calcium carbonate, and synthetic pyrogenic silicas.
Hiding pigments, in making paint opaque, also protect the substrate from the harmful effects of ultraviolet light. Hiding pigments include titanium dioxide, phthalo blue, red iron oxide, and many others.
Fillers are a special type of pigment that serve to thicken the film, support its structure and simply increase the volume of the paint. Fillers are usually made of cheap and inert materials, such as diatomaceous earth, talc, lime, barytes, clay, etc. Floor paints that will be subjected to abrasion may even contain fine quartz sand as a filler. Not all paints include fillers. On the other hand some paints contain very large proportions of pigment/filler and binder.
Some pigments are toxic, such as the lead pigments that are used in lead paint. Paint manufacturers began replacing white lead pigments with the less toxic substitute, titanium white (titanium dioxide), even before lead was functionally banned in paint for residential use in 1978 by the U.S. Consumer Product Safety Commission. The titanium dioxide used in most paints today is often coated with silica/alumina/zirconium for various reasons such as better exterior durability, or better hiding performance (opacity) via better efficiency promoted by more optimal spacing within the paint film.
The binder imparts adhesion, binds the pigments together, and strongly influences such properties as gloss potential, exterior durability, flexibility, and toughness.
Binders include synthetic or natural resins such as cement, alkyds, acrylics, vinyl-acrylics, vinyl acetate/ethylene (VAE), polyurethanes, polyesters, melamine resins, epoxy, or oils.
Binders can be categorized according to drying, or curing mechanism. The four most common are simple solvent evaporation, oxidative crosslinking, catalyzed/cross linked polymerization, and coalescence. There are others.
Note that drying and curing are two different processes. Drying generally refers to evaporation of the solvent or thinner, whereas curing refers to polymerization of the binder. (The term "vehicle" is industrial jargon which is used inconsistently, sometimes to refer to the solvent and sometimes to refer to the binder.) Depending on chemistry and composition, any particular paint may undergo either, or both processes. Thus, there are paints that dry only, those that dry then cure, and those that do not depend on drying for curing.
Paints that dry by simple solvent evaporation and contain a solid binder dissolved in a solvent are known as lacquers. A solid film forms when the solvent evaporates, and because the film can re-dissolve in solvent, lacquers are not suitable for applications where chemical resistance is important. Classic nitrocellulose lacquers fall into this category, as do non-grain raising stains composed of dyes dissolved in solvent and more modern acrylic based coatings such as 5-ball Krylon aerosol. Performance varies by formulation, but lacquers generally tend to have better UV resistance and lower corrosion resistance than comparable systems that cure by polymerization or coalescence.
Latex paint is a water-borne dispersion of sub-micrometre polymer particles. The term "latex" in the context of paint simply means an aqueous dispersion; latex rubber (the sap of the rubber tree that has historically been called latex) is not an ingredient. These dispersions are prepared by emulsion polymerization. Latex paints cure by a process called coalescence where first the water, and then the trace, or coalescing, solvent, evaporate and draw together and soften the latex binder particles and fuse them together into irreversibly bound networked structures, so that the paint will not redissolve in the solvent/water that originally carried it. The residual surfactants in paint as well as hydrolytic effects with some polymers cause the paint to remain susceptible to softening and, over time, degradation by water.
Paints that cure by oxidative crosslinking are generally single package coatings. When applied, the exposure to oxygen in the air starts a process that crosslinks and polymerizes the binder component. Classic alkyd enamels would fall into this category. Oxidative cure coatings are catalyzed by metal complex driers such as cobalt naphthenate.
Paints that cure by "catalyzed" polymerization are generally two package coatings that polymerize by way of a chemical reaction initiated by mixing resin and curing agent/hardener, and which cure by forming a hard plastic structure. Depending on composition they may need to dry first, by evaporation of solvent. Classic two package epoxies or polyurethanes would fall into this category. The word catalyst is a misnomer as catalyst should not be part of the polymer. Cobalt driers are catalysts, iso cyanates and epoxy adducts are not.
There are paints called plastisols/organosols, which are made by blending PVC granules with a plasticiser. These are stoved and the mix coalesceses.
Still other films are formed by cooling of the binder. For example, encaustic or wax paints are liquid when warm, and harden upon cooling. In many cases, they will resoften or liquify if reheated.
Recent environmental requirements restrict the use of volatile organic compounds (VOCs), and alternative means of curing have been developed, particularly for industrial purposes. In UV curing paints, the solvent is evaporated first, and hardening is then initiated by ultraviolet light. In powder coatings there is little or no solvent, and flow and cure are produced by heating of the substrate after electrostatic application of the dry powder.
Winnik and co-workers have developed environmentally friendly, smart, pH responsive nanoparticles that help particle coalescence, thus increasing open time of latex paints. Ammonia-neutralized nanoparticles undergo a sequence of pH dependent structural changes that lead to the build up of films with useful mechanical properties.
This component is optional: some paints have no diluent.
Water is the main diluent for water-borne paints, even the co-solvent types.
Solvent-borne, also called oil-based, paints can have various combinations of solvents as the diluent, including aliphatics, aromatics, alcohols, ketones and white spirit. These include organic solvents such as petroleum distillate, esters, glycol ethers, and the like. Sometimes volatile low-molecular weight synthetic resins also serve as diluents. Such solvents are used when water resistance, grease resistance, or similar properties are desired.
Additives normally do not significantly alter the percentages of individual components in a formulation.
Electrochromic paints change color in response to an applied electric current. Car manufacturer Nissan has been reportedly working on an electrochromic paint for use in its vehicles, based on particles of paramagnetic iron oxide. When subjected to an electromagnetic field the paramagnetic particles change spacing, modifying their color and reflective properties. The electromagnetic field would be formed using the conductive metal of the car body. Electrochromic paints can be applied to plastic substrates as well, using a different coating chemistry. The technology involves using special dyes that change conformation when an electric current is applied across the film itself. Recently, this new technology has been used to achieve glare protection at the touch of a button in passenger airplane windows.
Since the time of the Renaissance, siccative (drying) oil paints, primarily linseed oil, have been the most commonly used kind of paints in fine art applications; oil paint is still common today. However, in the 20th century, water-based paints, including watercolors and acrylic paints, became very popular with the development of acrylic and other latex paints. Milk paints (also called casein), where the medium is derived from the natural emulsion that is milk, were popular in the 19th century and are still available today. Egg tempera (where the medium is an emulsion of egg yolk mixed with oil) is still in use as well, as are encaustic wax-based paints. Gouache is a variety of opaque watercolor which was also used in the Middle Ages and Renaissance for manuscript illuminations. The pigment was often made from ground semiprecious stones such as lapis lazuli and the binder made from either gum arabic or egg white. Gouache, also known as 'designer color' or 'body color' is commercially available today.
Poster paint has been used primarily in the creation of student works, or by children.
As a solid (usually used in industrial and automotive applications), the paint is applied as a very fine powder, then baked at high temperature. This melts the powder and causes it to adhere (stick) to the surface. The reasons for doing this involve the chemistries of the paint, the surface itself, and perhaps even the chemistry of the substrate (the overall object being painted). This is commonly referred to as "powder coating" an object.
As a gas or as a gaseous suspension, the paint is suspended in solid or liquid form in a gas that is sprayed on an object. The paint sticks to the object. This is commonly referred to as "spray painting" an object. The reasons for doing this include:
In the liquid application, paint can be applied by direct application using brushes, paint rollers, blades, other instruments, or body parts such as fingers.
Rollers generally have a handle that allows for different lengths of poles which can be attached to allow for painting at different heights. Generally, roller application takes two coats for even color. A roller with a thicker nap is used to apply paint on uneven surfaces. Edges are often finished with an angled brush.
After liquid paint is applied, there is an interval during which it can be blended with additional painted regions (at the "wet edge") called "open time." The open time of an oil or alkyd-based emulsion paint can be extended by adding white spirit, similar glycols such as Dowanol (propylene glycol ether) or commercial open time prolongers. This can also facilitate the mixing of different wet paint layers for aesthetic effect. Latex and acrylic emulsions require the use of drying retardants suitable for water-based coatings.
Paint application by spray is the most popular method in industry. In this, paint is atomized by the force of compressed air or by the action of high pressure compression of the paint itself, which results in the paint being turned into small droplets which travel to the article which is to be painted. Alternate methods are airless spray, hot spray, hot airless spray, and any of these with an electrostatic spray included. There are numerous electrostatic methods available.
Dipping used to be the norm for objects such as filing cabinets, but this has been replaced by high speed air turbine driven bells with electrostatic spray. Car bodies are primed using cathodic elephoretic primer, which is applied by charging the body depositing a layer of primer. The unchanged residue is rinsed off and the primer stoved.
Many paints tends to separate when stored, the heavier components settling to the bottom and require mixing before use. Some paint outlets have machines for mixing the paint by shaking it vigorously in the can for a few minutes.
The opacity and the film thickness of paint may be measured using a drawdown card.
Water-based paints tend to be the easiest to clean up after using—the brushes and rollers can be cleaned with soap and water.
Proper disposal of left over paint is a challenge. Sometimes it can be recycled: Old paint may be usable for a primer coat or an intermediate coat, and paints of similar chemistry can be mixed to make a larger amount of a uniform color.
To dispose of paint it can be dried and disposed of in the domestic waste stream provided that it contains no prohibited substances (see container). Disposal of liquid paint usually requires special handling and should be treated as hazardous waste, and disposed of according to local regulations.
Application Defects can be attributed to:
In the United States, environmental regulations, consumer demand, and advances in technology led to the development of low-VOC and zero-VOC paints and finishes. These new paints are widely available and meet or exceed the old high-VOC products in performance and cost-effectiveness while having significantly less impact on human and environmental health.
Category:Coatings Category:Matter Category:Soft matter
ar:طلاء zh-min-nan:Thô͘-liāu bg:Боя ca:Pintura (material) cs:Barva (materiál) da:Maling de:Anstrichmittel et:Värv es:Pintura (material) eo:Farbo fa:رنگ نقاشی fr:Peinture (matière) ko:도료 hi:पेंट hr:Nalič io:Farbo ilo:Pintor id:Cat is:Málning it:Vernice he:צבע (חומר) jv:Cèt kk:Автомобиль косметикасы la:Pigmentum (pictura) lt:Dažas nl:Verf ja:塗料 no:Maling nn:Måling nrm:Peintuthe pl:Farba pt:Tinta ro:Vopsea ru:Краски simple:Paint fi:Maali sv:Målarfärg ta:வண்ணப்பூச்சு tr:Boya uk:Фарба yo:Ọ̀dà zh:涂料This text is licensed under the Creative Commons CC-BY-SA License. This text was originally published on Wikipedia and was developed by the Wikipedia community.
Coordinates | 35°27′″N139°38′″N |
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bgcolour | #6495ED |
name | David Kassan |
birth place | Little Rock, Arkansas |
nationality | American |
field | Realism |
awards | }} |
Kassan currently lives and works in Brooklyn, New York, and teaches painting classes and workshops at various institutions around the world.
He has also won the Newington-Cropsy Foundation’s Travel Grant, which allowed him to travel, study and sketch in Italy in the summer of 2003. There he conducted sketch studies of various masterworks, which are source of inspiration to his own work.
Kassan also cites a number of other varied influences, including the “sheer conceptual and executed realism” of Caravaggio and American realists, in particular John Sloan of the Ashcan School.
In addition to work in traditional drawing and painting media, Kassan is also exploring the use of digital media, including the use of the iPad as a portable drawing tablet, used for study sketches and impromptu demonstrations. His YouTube demonstration "Finger Painting on the Apple iPad from the live model" achieved over 1 million views within 6 months of posting. This also resulted in considerable news-media coverage in the printed press and on television
A DVD on his drawing technique in charcoal and chalk is available from his website, and he has posted demonstrations online at YouTube and ustream
This text is licensed under the Creative Commons CC-BY-SA License. This text was originally published on Wikipedia and was developed by the Wikipedia community.
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