Elemental sodium was first isolated by Humphry Davy in 1807 by passing an electric current through molten sodium hydroxide. Elemental sodium does not occur naturally on Earth, because it quickly oxidizes in air and is violently reactive with water, so it must be stored in a non-oxidizing medium, such as a liquid hydrocarbon. The free metal is used for some chemical synthesis, analysis, and heat transfer applications.
Sodium ion is soluble in water, and is thus present in great quantities in the Earth's oceans and other stagnant bodies of water. In these bodies it is mostly counterbalanced by the chloride ion, causing evaporated ocean water solids to consist mostly of sodium chloride, or common table salt. Sodium ion is also a component of many minerals.
Sodium is an essential element for all animal life (including human) and for some plant species. In animals, sodium ions are used in opposition to potassium ions, to allow the organism to build up an electrostatic charge on cell membranes, and thus allow transmission of nerve impulses when the charge is allowed to dissipate by a moving wave of voltage change. Sodium is thus classified as a "dietary inorganic macro-mineral" for animals. Sodium's relative rarity on land is due to its solubility in water, thus causing it to be leached into bodies of long-standing water by rainfall. Such is its relatively large requirement in animals, in contrast to its relative scarcity in many inland soils, that herbivorous land animals have developed a special taste receptor for the sodium ion.
Sodium changes color at high pressures, turning black at 1.5 megabar, becoming a red transparent substance at 1.9 megabar, and is predicted to become clearly transparent at 3 megabar. The high pressure allotropes are insulators and take the form of sodium electride.
Sodium reacts exothermically with water: small pea-sized pieces will bounce across the surface of the water until they are consumed by it, whereas large pieces will explode. While sodium reacts with water at room temperature, the sodium piece melts with the heat of the reaction to form a sphere, if the reacting sodium piece is large enough. The reaction with water produces very caustic sodium hydroxide (lye) and highly flammable hydrogen gas. These are extreme hazards. When burned in air, sodium forms sodium peroxide Na2O2, or with limited oxygen, sodium oxide Na2O (unlike lithium, the nitride is not formed). If burned in oxygen under pressure, sodium superoxide NaO2 is produced.
Sodium compounds are important to the chemical, glass, metal, paper, petroleum, pyrotechnic, soap, and textile industries. Hard soaps are generally sodium salt of certain fatty acids (potassium produces softer or liquid soaps).
The sodium compounds that are the most important to industries are common salt (NaCl), soda ash (Na2CO3), baking soda (NaHCO3), caustic soda (NaOH), sodium nitrate (NaNO3), di- and tri-sodium phosphates, sodium thiosulfate (Na2S2O3 · 5H2O), and borax (Na2B4O7·10H2O).
Sodium tends to form water-soluble compounds, such as halides, sulfate, nitrate, carboxylates and carbonates. There are only isolated examples of sodium compounds precipitating from water solution. However, nature provides examples of many insoluble sodium compounds such as the cryolite and the feldspars (aluminium silicates of sodium, potassium and calcium). There are other insoluble sodium salts such as sodium bismuthate NaBiO3, sodium octamolybdate Na2Mo8O25·4H2O, sodium thioplatinate Na4Pt3S6, sodium uranate Na2UO4. Sodium meta-antimonate's 2NaSbO3·7H2O solubility is 0.3 g/L as is the pyro form Na2H2Sb2O7·H2O of this salt. Sodium metaphosphate NaPO3 has a soluble and an insoluble form.
When sodium or its compounds are introduced into a flame, they turn the flame a bright yellow color.
One atomic spectral line of sodium vapor is the so-called D-line, which may be observed directly as the sodium flame-test line and also the major light output of low-pressure sodium lamps (these produce an unnatural yellow, rather than the peach-colored glow of high pressure lamps). The D-line is one of the classified Fraunhofer lines observed in the visible spectrum of the Sun's electromagnetic radiation. Sodium vapor in the upper layers of the Sun creates a dark line in the emitted spectrum of electromagnetic radiation by absorbing visible light in a band of wavelengths around 589.5 nm. This wavelength corresponds to transitions in atomic sodium in which the valence-electron transitions from a 3p to 3s electronic state. Closer examination of the visible spectrum of atomic sodium reveals that the D-line actually consists of two lines called the D1 and D2 lines at 589.6 nm and 589.0 nm, respectively. This fine structure results from a spin-orbit interaction of the valence electron in the 3p electronic state. The spin-orbit interaction couples the spin angular momentum and orbital angular momentum of a 3p electron to form two states that are respectively notated as 3p(2P) and 3p(2P) in the LS coupling scheme. The 3s state of the electron gives rise to a single state which is notated as 3s(2S1/2) in the LS coupling scheme. The D1-line results from an electronic transition between 3s(2S1/2) lower state and 3p(2P) upper state. The D2-line results from an electronic transition between 3s(2S1/2) lower state and 3p(2P) upper state. Even closer examination of the visible spectrum of atomic sodium would reveal that the D-line actually consists of a lot more than two lines. These lines are associated with hyperfine structure of the 3p upper states and 3s lower states. Many different transitions involving visible light near 589.5 nm may occur between the different upper and lower hyperfine levels.
A practical use for lasers which work at the sodium D-line transition is to create artificial laser guide stars (artificial star-like images from sodium in the upper atmosphere) which assist in the adaptive optics for large land-based visible light telescopes.
Acute neutron radiation exposure (e.g., from a nuclear criticality accident) converts some of the stable 23Na in human blood plasma to 24Na. By measuring the concentration of this isotope, the neutron radiation dosage to the victim can be computed.
Salt has been an important commodity in human activities, as testified by the English word salary, referring to salarium, the wafers of salt sometimes given to Roman soldiers along with their other wages.
In medieval Europe a compound of sodium with the Latin name of sodanum was used as a headache remedy. The name sodium probably originates from the Arabic word suda meaning headache as the headache-alleviating properties of sodium carbonate or soda were well known in early times.
Sodium's chemical abbreviation Na was first published by Jöns Jakob Berzelius in his system of atomic symbols (Thomas Thomson, Annals of Philosophy) and is a contraction of the element's new Latin name natrium which refers to the Egyptian natron, the word for a natural mineral salt whose primary ingredient is hydrated sodium carbonate. Hydrated sodium carbonate historically had several important industrial and household uses later eclipsed by soda ash, baking soda and other sodium compounds.
Although sodium (sometimes called "soda" in English) has long been recognized in compounds, it was not isolated until 1807 by Humphry Davy through the electrolysis of caustic soda.
Sodium imparts an intense yellow color to flames. As early as 1860, Kirchhoff and Bunsen noted the high sensitivity that a flame test for sodium could give. They state in Annalen der Physik und Chemie in the paper "Chemical Analysis by Observation of Spectra":
Sodium is relatively abundant in stars and the D spectral lines of this element are among the most prominent in star light. Though elemental sodium has a rather high vaporization temperature, its relatively high abundance and very intense spectral lines have allowed its presence to be detected by ground telescopes and confirmed by spacecraft (Mariner 10 and MESSENGER) in the thin atmosphere of the planet Mercury.
A process based on the reduction of sodium hydroxide was developed in 1886.
Sodium is now produced commercially through the electrolysis of liquid sodium chloride, based on a process patented in 1924. This is done in a Downs Cell in which the NaCl is mixed with calcium chloride to lower the melting point below 700 °C. As calcium is less electropositive than sodium, no calcium will be formed at the anode. This method is less expensive than the previous Castner process of electrolyzing sodium hydroxide.
Very pure sodium can be isolated by the thermal decomposition of sodium azide.
Sodium metal in reagent-grade sold for about $1.50/pound ($3.30/kg) in 2009 when purchased in tonne quantities. Lower purity metal sells for considerably less. The market in this metal is volatile due to the difficulty in its storage and shipping. It must be stored under a dry inert gas atmosphere or anhydrous mineral oil to prevent the formation of a surface layer of sodium oxide or sodium superoxide. These oxides can react violently in the presence of organic materials. Sodium will also burn violently when heated in air.
Smaller quantities of sodium, such as a kilogram, cost far more, in the range of $165/kg. This is partially due to the cost of shipping hazardous material.
Sodium leaks and fires were a significant operational problem in the first large sodium-cooled fast reactors, causing extended shutdowns at the Monju Nuclear Power Plant and Beloyarsk Nuclear Power Plant.
Where reactors need to be frequently shut down, as is the case with some research reactors, the alloy of sodium and potassium called NaK is used. It melts at −11 °C, so cooling pipes will not freeze at room temperature. Extra precautions against coolant leaks need to be taken in case of NaK, because molten potassium will spontaneously catch fire when exposed to air.
The phase diagram with potassium shows that the mixtures with potassium are liquid at room temperature in a wide concentration range. A compound Na2K melts at 7 °C. The eutectic mixture with a potassium content of 77 % gives a melting point at −12.6 °C.
Increasing soil salinity, osmotic stress and sodium toxicity in plants, especially in agricultural crops, have become worldwide phenomena. High levels of sodium in the soil solution limit the plants' ability to uptake water due to decreased soil water potential and, therefore, may result in wilting of the plant. In addition, excess sodium within the cytoplasm of plant cells can lead to enzyme inhibition, which may result in symptoms such as necrosis, chlorosis, and possible plant death. To avoid such symptoms, plants have developed methods to combat high sodium levels, such as: mechanisms limiting sodium uptake by roots, compartmentalization of sodium in cell vacuoles, and control of sodium in long distance transport. Many plants store excess sodium in old plant tissue, limiting damage to new growth.
The serum sodium and urine sodium play important roles in medicine, both in the maintenance of sodium and total body fluid homeostasis, and in the diagnosis of disorders causing homeostatic disruption of salt/sodium and water balance.
In mammals, decreases in blood pressure and decreases in sodium concentration sensed within the kidney result in the production of renin, a hormone which acts in a number of ways, one of them being to act indirectly to cause the generation of aldosterone, a hormone which decreases the excretion of sodium in the urine. As the body of the mammal retains more sodium, other osmoregulation systems which sense osmotic pressure in part from the concentration of sodium and water in the blood, act to generate antidiuretic hormone. This, in turn, causes the body to retain water, thus helping to restore the body's total amount of fluid.
There is also a counterbalancing system, which senses volume. As fluid is retained, receptors in the heart and vessels which sense distension and pressure, cause production of atrial natriuretic peptide, which is named in part for the Latin word for sodium. This hormone acts in various ways to cause the body to lose sodium in the urine. This causes the body's osmotic balance to drop (as low concentration of sodium is sensed directly), which in turn causes the osmoregulation system to excrete the "excess" water. The net effect is to return the body's total fluid levels back toward normal.
Persons suffering from severe dehydration caused by diarrhea, such as that by cholera, can be treated with oral rehydration therapy, in which they drink a solution of sodium chloride, potassium chloride and glucose. This simple, effective therapy saves the lives of millions of children annually in the developing world.
According to the USDA, consumption of sodium in the US is disproportionately greater than the recommended intake, and AHA estimates the daily intake of sodium as 3.4 g/day. NHANES reported that in 2005–2006 the lowest consumption was by 2–5 years old females (~2.1 g/day) and the highest was for 30–39 years old males (~4.7 g/day); males consumed more than 2.3 g/day regardless of age and more than females of the same age group.
==Precautions== Extreme care is required in handling elemental/metallic sodium. Sodium is potentially explosive in water (depending on quantity), and it is rapidly converted to sodium hydroxide on contact with moisture and sodium hydroxide is a corrosive substance. The powdered form may combust spontaneously in air or oxygen. Sodium must be stored either in an inert (oxygen and moisture free) atmosphere (such as nitrogen or argon), or under a liquid hydrocarbon such as mineral oil or kerosene.
The reaction of sodium and water is a familiar one in chemistry labs, and is reasonably safe if amounts of sodium smaller than a pencil eraser are used and the reaction is done behind a plastic shield by people wearing eye protection. However, the sodium-water reaction does not scale up well, and is treacherous when larger amounts of sodium are used. Larger pieces of sodium melt under the heat of the reaction, and the molten ball of metal is buoyed up by hydrogen and may appear to be stably reacting with water, until splashing covers more of the reaction mass, causing thermal runaway and an explosion which scatters molten sodium, lye solution, and sometimes flame. (18.5 g explosion ) This behavior is unpredictable, and among the alkali metals it is usually sodium which invites this surprise phenomenon, because lithium is not reactive enough to do it, and potassium is so reactive that chemistry students are not tempted to try the reaction with larger potassium pieces.
Sodium is much more reactive than magnesium; a reactivity which can be further enhanced due to sodium's much lower melting point. When sodium catches fire in air (as opposed to just the hydrogen gas generated from water by means of its reaction with sodium) it more easily produces temperatures high enough to melt the sodium, exposing more of its surface to the air and spreading the fire.
Few common fire extinguishers work on sodium fires. Water, of course, exacerbates sodium fires, as do water-based foams. CO2 and Halon are often ineffective on sodium fires, which reignite when the extinguisher dissipates. Among the very few materials effective on a sodium fire are Pyromet and Met-L-X. Pyromet is a NaCl/(NH4)2HPO4 mix, with flow/anti-clump agents. It smothers the fire, drains away heat, and melts to form an impermeable crust. This is the standard dry-powder canister fire extinguisher for all classes of fires. Met-L-X is mostly sodium chloride, NaCl, with approximately 5% Saran plastic as a crust-former, and flow/anti-clumping agents. It is most commonly hand-applied, with a scoop. Other extreme fire extinguishing materials include Lith+, a graphite based dry powder with an organophosphate flame retardant; and Na+, a Na2CO3-based material. Alternatively, plain dry sand can effectively slow down the oxygen and humidity flow to the sodium.
Because of the reaction scale problems discussed above, disposing of large quantities of sodium (more than 10 to 100 grams) must be done through a licensed hazardous materials disposer. Smaller quantities may be broken up and neutralized carefully with ethanol (which has a much slower reaction than water), or even methanol (where the reaction is more rapid than ethanol's but still less than in water), but care should nevertheless be taken, as the caustic products from the ethanol or methanol reaction are just as hazardous to eyes and skin as those from water. After the alcohol reaction appears complete, and all pieces of reaction debris have been broken up or dissolved, a mixture of alcohol and water, then pure water, may then be carefully used for a final cleaning. This should be allowed to stand a few minutes until the reaction products are diluted more thoroughly and flushed down the drain. The purpose of the final water soaking and washing of any reaction mass or container which may contain sodium, is to ensure that alcohol does not carry unreacted sodium into the sink trap, where a water reaction may generate hydrogen in the trap space which can then be potentially ignited, causing a confined sink trap explosion.
Category:Desiccants Category:Dietary minerals Category:Reducing agents Category:Chemical elements Category:Alkali metals Category:Biology and pharmacology of chemical elements Category:Nuclear reactor coolants
af:Natrium ar:صوديوم an:Sodio ast:Sodiu az:Natrium bn:সোডিয়াম zh-min-nan:Na (goân-sò͘) be:Натрый bs:Natrijum bg:Натрий ca:Sodi cv:Натри cs:Sodík co:Sodiu cy:Sodiwm da:Natrium de:Natrium dv:ސޯޑިއަމް nv:Soodin et:Naatrium el:Νάτριο es:Sodio eo:Natrio eu:Sodio fa:سدیم hif:Sodium fr:Sodium fy:Natrium fur:Sodi ga:Sóidiam gv:Sodjum gd:Sodium gl:Sodio gu:સોડિયમ hak:Na̍p xal:Натрион ko:나트륨 haw:Sodiuma hy:Նատրիում hi:सोडियम hr:Natrij io:Natro id:Natrium is:Natrín it:Sodio he:נתרן jv:Natrium kn:ಸೋಡಿಯಮ್ ka:ნატრიუმი sw:Natiri kv:Натрий ht:Sodyòm ku:Natriyûm la:Natrium lv:Nātrijs lb:Natrium lt:Natris lij:Sodio ln:Sodu jbo:sodna hu:Nátrium mk:Натриум ml:സോഡിയം mi:Konutai mr:सोडियम ms:Natrium my:ဆိုဒီယမ် mrj:Натрий nl:Natrium ja:ナトリウム frr:Natrium no:Natrium nn:Natrium nrm:Sôdgium nov:Natrium oc:Sòdi uz:Natriy pa:ਸੋਡੀਅਮ pnb:سوڈیم nds:Natrium pl:Sód pnt:Νάτριον pt:Sódio ro:Sodiu qu:Natriyu ru:Натрий sah:Натриум stq:Natrium sq:Natriumi scn:Sodiu si:සෝඩියම් simple:Sodium sk:Sodík sl:Natrij sr:Натријум sh:Natrij fi:Natrium sv:Natrium tl:Sodyo ta:சோடியம் tt:Натрий te:సోడియమ్ th:โซเดียม tg:Натрий tr:Sodyum uk:Натрій ug:ناترىي vi:Natri wa:Sodiom zh-classical:鈉 war:Sodyo yi:נאטריום yo:Sodium zh-yue:鈉 zh:钠This text is licensed under the Creative Commons CC-BY-SA License. This text was originally published on Wikipedia and was developed by the Wikipedia community.
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