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- Published: 12 Apr 2011
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Name | Coal |
---|---|
Type | Sedimentary |
Composition | carbon |
Composition secondary | sulfur,hydrogen,oxygen,nitrogen |
The wide shallow seas of the Carboniferous period provided ideal conditions for coal formation, although coal is known from most geological periods. The exception is the Coal gap in the Lower Triassic, where coal is incredibly rare: presumably a result of the mass extinction which prefaced this era. Coal is even known from Precambrian strata, which predate land plants: this coal is presumed to have originated from algal residues.
Coal, a fossil fuel, is the largest source of energy for the generation of electricity worldwide, as well as one of the largest worldwide anthropogenic sources of carbon dioxide releases. Gross carbon dioxide emissions from coal usage are slightly more than those from petroleum and about double the amount from natural gas. Coal is extracted from the ground by mining, either underground by shaft mining through the seams or in open pits.
As geological processes apply pressure to dead biotic material over time, under suitable conditions it is transformed successively into:
The classification of coal is generally based on the content of volatiles. However, the exact classification varies between countries. According to the German classification, coal is classified as follows: The middle six grades in the table represent a progressive transition from the English-language sub-bituminous to bituminous coal, while the last class is an approximate equivalent to anthracite, but more inclusive (the U.S. anthracite has < 6% volatiles).
Cannel coal (sometimes called "candle coal"), is a variety of fine-grained, high-rank coal with significant hydrogen content. It consists primarily of "exinite" macerals, now termed "liptinite".
Outcrop coal was used in Britain during the Bronze Age (3000–2000 BC), where it has been detected as forming part of the composition of funeral pyres. In Roman Britain, with the exception of two modern fields, "the Romans were exploiting coals in all the major coalfields in England and Wales by the end of the second century AD". Evidence of trade in coal (dated to about AD 200) has been found at the inland port of Heronbridge, near Chester, and in the Fenlands of East Anglia, where coal from the Midlands was transported via the Car Dyke for use in drying grain. Coal cinders have been found in the hearths of villas and military forts, particularly in Northumberland, dated to around AD 400. In the west of England contemporary writers described the wonder of a permanent brazier of coal on the altar of Minerva at Aquae Sulis (modern day Bath) although in fact easily accessible surface coal from what became the Somerset coalfield was in common use in quite lowly dwellings locally. Evidence of coal's use for iron-working in the city during the Roman period has been found. In Eschweiler, Rhineland, deposits of bituminous coal were used by the Romans for the smelting of iron ore. Mineral coal came to be referred to as "seacoal" in the 13th century; the wharf where the material arrived in London was known as Seacoal Lane, so identified in a charter of King Henry III granted in 1253. Initially the name was given because much coal was found on the shore, having fallen from the exposed coal seams on cliffs above or washed out of underwater coal outcrops, In 1257–59, coal from Newcastle was shipped to London for the smiths and lime-burners building Westminster Abbey. (See Industrial processes below for modern uses of the term.)
These easily accessible sources had largely become exhausted (or could not meet the growing demand) by the 13th century, when underground mining from shafts or adits was developed. In 1947, there were some 750,000 miners, but by 2004 this had shrunk to some 5,000 miners working in around 20 collieries.
In ancient China, coal was used as fuel by the 4th century AD, but there was little extensive use until the 11th century.
When coal is used for electricity generation, it is usually pulverized and then combusted (burned) in a furnace with a boiler. The furnace heat converts boiler water to steam, which is then used to spin turbines which turn generators and create electricity. The thermodynamic efficiency of this process has been improved over time. Simple cycle steam turbines have topped out with some of the most advanced reaching about 35% thermodynamic efficiency for the entire process. Increasing the combustion temperature can boost this efficiency even further. Old coal power plants, especially "grandfathered" plants, are significantly less efficient and produce higher levels of waste heat. At least 40% of the world's electricity comes from coal, and in 2008 approximately 49% of the United States' electricity came from coal. The emergence of the supercritical turbine concept envisions running a boiler at extremely high temperatures and pressures with projected efficiencies of 46%, with further theorized increases in temperature and pressure perhaps resulting in even higher efficiencies.
Other ways to use coal are combined heat and power cogeneration and an MHD topping cycle.
More than 40% of the world electricity production uses coal. The total known deposits recoverable by current technologies, including highly polluting, low energy content types of coal (i.e., lignite, bituminous), is sufficient for many years. However, consumption is increasing and maximal production could be reached within decades (see World Coal Reserves, below).
An experimental way of coal combustion is in a form of coal-water slurry fuel (CWS, which was well-developed in Russia (since the Soviet Union time). CWS significantly reduces emissions saving the heating value of coal.
The coke must be strong enough to resist the weight of overburden in the blast furnace, which is why coking coal is so important in making steel by the conventional route. However, the alternative route to is direct reduced iron, where any carbonaceous fuel can be used to make sponge or pelletised iron. Coke from coal is grey, hard, and porous and has a heating value of 24.8 million Btu/ton (29.6 MJ/kg). Some cokemaking processes produce valuable by-products that include coal tar, ammonia, light oils, and "coal gas".
Petroleum coke is the solid residue obtained in oil refining, which resembles coke but contains too many impurities to be useful in metallurgical applications.
During gasification, the coal is mixed with oxygen and steam (water vapor) while also being heated and pressurized. During the reaction, oxygen and water molecules oxidize the coal into carbon monoxide (CO) while also releasing hydrogen (H2) gas. This process has been conducted in both underground coal mines and in coal refineries.
: (Coal) + O2 + H2O → H2 + CO
If the refiner wants to produce gasoline, the syngas is collected at this state and routed into a Fischer-Tropsch reaction. If hydrogen is the desired end-product, however, the syngas is fed into the water gas shift reaction where more hydrogen is liberated.
: CO + H2O → CO2 + H2
High prices of oil and natural gas are leading to increased interest in "BTU Conversion" technologies such as gasification, methanation and liquefaction. The Synthetic Fuels Corporation was a U.S. government-funded corporation established in 1980 to create a market for alternatives to imported fossil fuels (such as coal gasification). The corporation was discontinued in 1985.
In the past, coal was converted to make coal gas, which was piped to customers to burn for illumination, heating, and cooking. At present, the safer natural gas is used instead.
Coal can also be converted into liquid fuels such as gasoline or diesel by several different processes. In the direct liquefaction processes, the coal is either hydrogenated or carbonized. Hydrogenation processes are the Bergius process, the SRC-I and SRC-II (Solvent Refined Coal) processes and the NUS Corporation hydrogenation process. In the process of low-temperature carbonization, coal is coked at temperatures between 360 °C (680 °F) and 750 °C (1,380 °F). These temperatures optimize the production of coal tars richer in lighter hydrocarbons than normal coal tar. The coal tar is then further processed into fuels. Alternatively, coal can be converted into a gas first, and then into a liquid, by using the Fischer-Tropsch process. An overview of coal liquefaction and its future potential is available.
Coal liquefaction methods involve carbon dioxide (CO2) emissions in the conversion process. If coal liquefaction is done without employing either carbon capture and storage technologies or biomass blending, the result is lifecycle greenhouse gas footprints that are generally greater than those released in the extraction and refinement of liquid fuel production from crude oil. If CCS technologies are employed, reductions of 5-12% can be achieved in CTL plants and up to a 75% reduction is achievable when co-gasifying coal with commercially demonstrated levels of biomass (30% biomass by weight) in CBTL plants. For most future synthetic fuel projects, Carbon dioxide sequestration is proposed to avoid releasing it into the atmosphere. Sequestration will, however, add to the cost of production. Currently all US and at least one Chinese synthetic fuel projects, include sequestration in their process designs.
Coal liquefaction features intense research work, particularly in China, Germany, South Africa and the USA. Every year, the World CTL Award rewards an individual who has contributed substantially in the understanding and development of Coal and Biomass Conversion. In 2011, the World CTL Award was granted to Rudi Heydenrich, executive manager of Sasol Technology.
Some cultures uphold that children who misbehave will receive only a lump of coal from Santa Claus for Christmas in their stockings instead of presents.
It is also customary and lucky in Scotland and the North of England to give coal as a gift on New Year's Day. It happens as part of First-Footing and represents warmth for the year to come.
In addition to the NYMEX contract, the IntercontinentalExchange (ICE) has European (Rotterdam) and South African (Richards Bay) coal futures available for trading. The trading unit for these contracts is , and are also quoted in U.S. dollars and cents per ton.
The price of coal increased from around $30.00 per short ton in 2000 to around $150.00 per short ton as of September 2008. As of October 2008, the price per short ton had declined to $111.50. Prices further declined to $71.25 as of October 2010.
Coal-fired power plants shorten nearly 24,000 lives a year in the United States, including 2,800 from lung cancer
In China, due to an increasing need for liquid energy in the transportation sector, coal liquefaction projects were given high priority even during periods of oil prices below $40 per barrel. This is probably because China prefers not to be dependent on foreign oil, instead utilizing its enormous domestic coal reserves. As oil prices were increasing during the first half of 2009, the coal liquefaction projects in China were again boosted, and these projects are profitable with an oil barrel price of $40.
China is by far the largest producer of coal in the world. It has now become the world's largest energy consumer but relies on coal to supply about 70% of its energy needs. An estimated 5 million people work in China's coal-mining industry.
Among commercially mature technologies, advantages for indirect coal liquefaction over direct coal liquefaction are reported by Williams and Larson (2003).
The energy density of coal can also be expressed in kilowatt-hours, the units that electricity is most commonly sold in, per units of mass to estimate how much coal is required to power electrical appliances. One kilowatt-hour is 3.6 MJ, so the energy density of coal is 6.67 kW·h/kg. The typical thermodynamic efficiency of coal power plants is about 30%, so of the 6.67 kW·h of energy per kilogram of coal, 30% of that—2.0 kW·h/kg—can successfully be turned into electricity; the rest is waste heat. So coal power plants obtain approximately 2.0 kW·h per kilogram of burned coal.
As an example, running one 100-watt lightbulb for one year requires 876 kW·h (100 W × 24 h/day × 365 day/year = 876000 W·h = 876 kW·h). Converting this power usage into physical coal consumption: :
It takes 325 kg (714 lb) of coal to power a 100 W lightbulb for one year. One should also take into account transmission and distribution losses caused by resistance and heating in the power lines, which is in the order of 5–10%, depending on distance from the power station and other factors.
Carbon combines with oxygen in the atmosphere during combustion, producing carbon dioxide, with an atomic weight of (12 + 16 × 2 = 44 kg/kmol). The CO2 released to air for each kilogram of incinerated coal is therefore :.
This can be used to calculate an emission factor for CO2 from the use of coal power. Since the useful energy output of coal is about 30% of the 6.67 kWh/kg(coal), the burning of 1 kg of coal produces about 2 kWh of electrical energy. Since 1 kg coal emits 2.93 kg CO2, the direct CO2 emissions from coal power are 1.47 kg/kWh, or about 0.407 kg/MJ.
The U.S. Energy Information Agency's 1999 report on CO2 emissions for energy generation, quotes a lower emission factor of 0.963 kg CO2/kWh for coal power. The same source gives a factor for oil power in the U.S. of 0.881 kg CO2/kWh, while natural gas has 0.569 kg CO2/kWh. Estimates for specific emission from nuclear power, hydro, and wind energy vary, but are about 100 times lower.
At Kuh i Malik in Yagnob Valley, Tajikistan, coal deposits have been burning for thousands of years, creating vast underground labyrinths full of unique minerals, some of them very beautiful. Local people once used this method to mine ammoniac. This place has been well-known since the time of Herodotus, but European geographers misinterpreted the Ancient Greek descriptions as the evidence of active volcanism in Turkestan (up to the 19th century, when the Russian army invaded the area).
The reddish siltstone rock that caps many ridges and buttes in the Powder River Basin (Wyoming), and in western North Dakota is called porcelanite, which also may resemble the coal burning waste "clinker" or volcanic "scoria". Clinker is rock that has been fused by the natural burning of coal. In the Powder River Basin approximately 27 to 54 billion tons of coal burned within the past three million years. Wild coal fires in the area were reported by the Lewis and Clark Expedition as well as explorers and settlers in the area.
BP, in its 2007 report, estimated at 2006 end that there were 909,064 million tons of proven coal reserves worldwide, or 147 years reserves-to-production ratio. This figure only includes reserves classified as "proven"; exploration drilling programs by mining companies, particularly in under-explored areas, are continually providing new reserves. In many cases, companies are aware of coal deposits that have not been sufficiently drilled to qualify as "proven". However, some nations haven't updated their information and assume reserves remain at the same levels even with withdrawals. Collective projections generally predict that global peak coal production may occur sometime around 2025 at 30 percent above current production in the best case scenario, depending on future coal production rates.
Of the three fossil fuels, coal has the most widely distributed reserves; coal is mined in over 100 countries, and on all continents except Antarctica. The largest reserves are found in the USA, Russia, China, India and Australia. Note the table below.
{| class="wikitable sortable" align="center" style="text-align:right" |+ Proved recoverable coal reserves at end-2008 (million tons (teragrams)) |- ! width="120pt"|Country ! width="100pt"|Bituminous & Anthracite ! width="100pt"|SubBituminous ! width="100pt"|Lignite ! width="100pt"|TOTAL ! width="100pt"|Percentage of World Total |- |align="left"|||108,501||98,618||30,176||237,295||22.6 |- |align="left"|||49,088||97,472||10,450||157,010||14.4 |- |align="left"|||62,200||33,700||18,600||114,500||12.6 |- |align="left"|||37,100||2,100||37,200||76,500||8.9 |- |align="left"|||56,100||0||4,500||60,600||7.0 |- |align="left"|||99||0||40,600||40,699||4.7 |- |align="left"|||15,351||16,577||1,945||33,873||3.9 |- |align="left"|||21,500||0||12,100||33,600||3.9 |- |align="left"|||30,156||0||0||30,156||3.5 |- |align="left"|||9||361||13,400||13,770||1.6 |- |align="left"|||6,366||380||0||6,746||0.8 |- |align="left"|||3,474||872||2,236||6,528||0.8 |- |align="left"|||4,338||0||1,371||5,709||0.7 |- |align="left"|||1,520||2,904||1,105||5,529||0.6 |- |align="left"|||0||4,559||0||4,559||0.5 |- |align="left"|||0||0||3,020||3,020||0.4 |- |align="left"|||484||0||2,369||2,853||0.3 |- |align="left"|||1,170||0||1,350||2,520||0.3 |- |align="left"|||2||190||2,174||2,366||0.3 |- |align="left"|||0||166||1,904||2,070||0.3 |- |align="left"|||529||0||1,814||2,343||0.3 |- |align="left"|||47||0||1,853||1,900||0.2 |- |align="left"|||13||439||1,208||1,660||0.2 |- |align="left"|||0||0||1,239||1,239||0.1 |- |align="left"|||860||300||51||1,211||0.1 |- |align="left"|||1,203||0||0||1,203||0.1 |- |align="left"|||192||0||908||1,100||0.1 |- |align="left"|||0||0||812||812||0.1 |- |align="left"|||0||0||794||794||0.1 |- |align="left"|||300||300||0||600||0.1 |- |align="left"|||33||205||333-7,000||571-15,000||0.1 |- |align="left"|||200||300||30||530||0.1 |- |align="left"|||4||0||499||503||0.1 |- |align="left"|||502||0||0||502||0.1 |- |align="left"|||0||0||500||500||0.1 |- |align="left"|All others||3,421||1,346||846||5,613||0.7 |-class="sortbottom" !Total world ||404,762||260,789||195,387||860,938||100 |}
{| class="wikitable sortable" align="center" style="text-align:right" |+ Imports of Coal by Country and year (million short tons) |- ! width="140pt"|Country ! width="100pt"|2006 ! width="100pt"|2007 ! width="100pt"|2008 ! width="100pt"|2009 ! width="100pt"|Share |- |align="left"| | 199.7 | 209.0 | 206.0 | 182.1 | 17.5% |- |align="left"| | 42.0 | 56.2 | 44.5 | 151.9 | 14.5% |- |align="left"| | 84.1 | 94.1 | 107.1 | 109.9 | 10.6% |- |align="left"| | 52.7 | 29.6 | 70.9 | 76.7 | 7.4% |- |align="left"| | 69.1 | 72.5 | 70.9 | 64.6 | 6.2% |- |align="left"| | 50.6 | 56.2 | 55.7 | 45.9 | 4.4% |- |align="left"| | 56.8 | 48.9 | 49.2 | 42.2 | 4.1% |- |-class="sortbottom" ! Total ! 991.8 ! 1,056.5 ! 1,063.2 ! 1,039.8 ! 100% |}
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